• Bulletin of the Korean Chemical Society
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• v.15 no.7
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• pp.553-559
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• 1994

Dynamics of $CH_2CI$ group in ${\alpha},2,6$-trichlorotoluene dissolved in $CDCl_3$ was studied by observing various relaxation modes for $^{13}C$ under proton undecoupled condition. Partially relaxed $^{13}C$ spectra were obtained at $34^{\circ}C$ as a function of evolution time after applying various designed pulse sequences to this $AX_2$ spin system. It was found that nonlinear regression analysis of the relaxation data for these magnetization modes could provide the information about dipolar and spin-rotational auto-correlation and cross-correlation spectral densities for fluctuation of the $^{13}C-^1H$ internuclear vector in $CH_2Cl$ group. The results show that the effect of cross-correlation is comparable in magnitude to that of auto-correlation and the relaxation in this spin system is dominated by dipolar mechanism rather than spin-rotational one. From the resulting spectral density data we could calculate the bond angle ${\angle}HCH\;(105.1$^{\circ}$) and elements of the rotational diffusion tensor for $CH_2Cl$ group.

• Transactions of the Korean hydrogen and new energy society
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• v.32 no.5
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• pp.401-409
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• 2021

The combination of different concentrations of ZnSO₄ in acidic solution as electrolyte in Zn-air batteries was investigated by Zn symmetrical cell test, half-cell and full cell tests. Using 1 M ZnSO₄ + 0.05 M H₂SO₄ as electrolyte and MnO₂ as air cathode catalyst with Zn foil anode, this combination had a satisfactory performance with balance of electrochemical activity and stability. Its electrochemical activity was matched to or even better than the PtRu catalyst in different current density. And its cycle life was improved (more than 100 cycles stable) by suppressing the growth of zinc dendrites on anode obviously. This electrolyte overcame the shortcomings of alkaline electrolyte that are easy to react with CO₂ in the air, severely growth of Zn dendrites caused by uneven plating/stripping of Zn.

• Nuclear Engineering and Technology
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• v.53 no.10
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• pp.3182-3195
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• 2021

The implementation and validation of multi-dimensional (multi-D) features in thermal-hydraulic system codes aims to extend the application of these codes towards multi-scale simulations. The main goal is the simulation of large-scale three-dimensional effects inside large volumes such as piping or vessel. This novel approach becomes especially relevant during the simulation of accidents with strongly asymmetric flow conditions entailing density gradients. Under such conditions, coolant mixing is a key phenomenon on the eventual variation of the coolant temperature and/or boron concentration at the core inlet and on the extent of a local re-criticality based on the reactivity feedback effects. This approach presents several advantages compared to CFD calculations, mainly concerning the model size and computational efforts. However, the range of applicability and accuracy of the newly implemented physical models at this point is still limited and needs to be further extended. This paper aims at contributing to the validation of the multi-D features of the system code ATHLET based on the simulation of the Tests 1.1 and 2.1, conducted at the test facility ROCOM. Overall, the multi-D features of ATHLET predict reasonably well the evolution from both experiments, despite an observed overprediction of coolant mixing at the vessel during both experiments.

• Nuclear Engineering and Technology
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• v.51 no.7
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• pp.1860-1865
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• 2019

The confinement degradation of the energetic particles during RMP would be a key issue in success of realizing the successful energy production using fusion plasma, because a 3.5 MeV energetic alpha particle should be able to sustain the burning plasma after the ignition. As KSTAR recent results indicate the generation of high-performance plasma(${\beta}_p{\sim}3$), the confinement of the energetic particles is also an important key aspect in neutral beam driven plasma. In general, the measured absolute value of the neutron intensity is generally used for to estimating the confinement time of energetic particles by comparing it with the theoretical value based on transport calculations. However, the availability of, but for its calculation process, many accurate diagnostic data of plasma parameters such as thermal and incident fast ion density, are essential to the calculation process. In this paper, the time evolution of the neutron signal from an He3 counter during the beam blank has permitted to facilitate the estimation of the slowing down time of energetic particles and the method is applied to investigate the fast ion effect on ELM suppressed KSTAR plasma which is heated by high energy deuterium neutral beams.

• Journal of Powder Materials
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• v.29 no.1
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• pp.28-33
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• 2022

Aluminum-based powders have attracted attention as key materials for 3D printing owing to their low density, high specific strength, high corrosion resistance, and formability. This study describes the effects of TiC addition on the microstructure of the A6013 alloy. The alloy powder was successfully prepared by gas atomization and further densified using an extrusion process. We have carried out energy dispersive X-ray spectrometry (EDS) and electron backscatter diffraction (EBSD) using scanning electron microscopy (SEM) in order to investigate the effect of TiC addition on the microstructure and texture evolution of the A6013 alloy. The atomized A6013-xTiC alloy powder is fine and spherical, with an initial powder size distribution of approximately 73 ㎛ which decreases to 12.5, 13.9, 10.8, and 10.0 ㎛ with increments in the amount of TiC.

• Coupled systems mechanics
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• v.11 no.2
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• pp.167-198
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• 2022

In this paper we deal with classical instability problems of heterogeneous Euler beam under conservative loading. It is chosen as the model problem to systematically present several possible solution methods from simplest deterministic to more complex stochastic approach, both of which that can handle more complex engineering problems. We first present classical analytic solution along with rigorous definition of the classical Euler buckling problem starting from homogeneous beam with either simplified linearized theory or the most general geometrically exact beam theory. We then present the numerical solution to this problem by using reduced model constructed by discrete approximation based upon the weak form of the instability problem featuring von Karman (virtual) strain combined with the finite element method. We explain how such numerical approach can easily be adapted to solving instability problems much more complex than classical Euler's beam and in particular for heterogeneous beam, where analytic solution is not readily available. We finally present the stochastic approach making use of the Duffing oscillator, as the corresponding reduced model for heterogeneous Euler's beam within the dynamics framework. We show that such an approach allows computing probability density function quantifying all possible solutions to this instability problem. We conclude that increased computational cost of the stochastic framework is more than compensated by its ability to take into account beam material heterogeneities described in terms of fast oscillating stochastic process, which is typical of time evolution of internal variables describing plasticity and damage.

• Transactions of the Korean Society of Pressure Vessels and Piping
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• v.17 no.2
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• pp.109-118
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• 2021

In the periodic surveillance material test for the spacer component of fuel channel assembly in CANDU, a microstructural characterization analysis is required in addition to the mechanical property evaluation test. In this study, detailed microstructure analysis and simple mechanical property evaluation of archive spacer parts were conducted to indirectly support the surveillance test and assist in the study of spacer material degradation. We investigated the microstructural characteristics of the spacer garter spring coil through comparative analysis with the plate material. The main microstructure characteristics of the garter spring coil X-750 are represented by the fine grain size distribution, the ordering phase distribution developed inside the matrix, the high dislocation density inside the grains, and the arrangement of coarse carbides. In addition, the yield strength of the garter spring coil X-750 was indirectly evaluated to be approximately 1 GPa. We also established an analytical method to elucidate the microstructural evolution of the radioactive spacer garter spring coil X-750 based on Canadian research experiences. Finally, we confirmed the measurement technique for helium bubble formation through TEM examination on the helium implanted X-750 material.

• Progress in Superconductivity and Cryogenics
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• v.8 no.4
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• pp.12-14
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• 2006

YBCO coated conductors have been fabricated by the reel-to-reel processing using TFA-MOD method. In this work, the fluorine-free Y & Cu precursor solution was synthesized to shorten the calcining time by reducing the evolution of HF gas, thus the meter-long YBCO precursor films can be made within few hours by the continuous slot-die coating & calcination step using the F-free Y & Cu precursor solution. The annealing step was followed to make the YBCO films by the reel-to-reel method with the vertical gas flow system onto the moving tape. To increase the growth rate of the YBCO films by enhancing the removal of HF gas, the low total pressure was adopted in the annealing processing. And the water partial pressure and the oxygen partial pressure were varied to optimize the growth conditions of the MOD-YBCO films on the buffered metal tape. FE-SEM and XRD were used to investigate the surface morphologies and the texture of the meter-long YBCO films. The end-to-end critical current $(I_c)$ of 63A/cm-width and the critical current density $(J_c)$of $0.9MA/cm^2$ with the thickness of $0.7{\mu}m$ were obtained in the 0.42m long coated conductor.

• The Bulletin of The Korean Astronomical Society
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• v.46 no.2
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• pp.68.1-68.1
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• 2021

We study galaxy evolution with the large-scale environment with confirmed galaxy clusters from multi-object spectroscopy (MOS) observation. The observation was performed with Inamori Magellan Areal Camera and Spectrograph (IMACS) mounted on the 6.5 m Magellan/Baade telescope in Las Campanas Observatory. With the MOS observation, we spectroscopically confirm 34 galaxy clusters, including three galaxy clusters discovered in Kim et al. (2016) and 11 of them have halo mass of > 10^14.5 M_◉. Among the confirmed clusters, 12 galaxy clusters are part of large-scale structure at z ~ 0.9, and their size stretches to 40 Mpc co-moving scale. In this study, we checked the 'web feeding model,' which postulates that more linked (with their environment) galaxy clusters have less quenched populations by investigating the correlation between properties of confirmed galaxy clusters and the large-scale structure environment. Lastly, we found that galaxy clusters that make up the large-scale structure have larger and widely spread values of total star formation density (ΣSFR/M_halo) than typical clusters at similar redshifts.

• The Bulletin of The Korean Astronomical Society
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• v.46 no.2
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• pp.81.1-81.1
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• 2021

Stellar kinematics is a useful tool to understand the formation and evolution of young stellar systems. Here, we present a kinematic study of the HII region, NGC 821, using the Gaia Early Data Release 3. NGC 281 contains the open cluster IC 1590. This cluster has a core and a low-stellar density halo. We detect a pattern of cluster expansion from the Gaia proper motion vectors. Most stars radially escaping from the cluster are distributed in the halo. We measure the 1-dimensional velocity dispersion of stars in the core. The velocity dispersion (1 km/s) is comparable to the expected virial velocity dispersion of this cluster, and therefore the core is at a virial state. The core has an initial mass function shallower than that of the halo, which is indicative of mass segregation. However, there is no significant correlation between stellar masses and tangential velocities. This result suggests that the mass segregation has a primordial origin. On the other hand, it has been believed that the formation of young stars in NGC 281 West was triggered by feedback from massive stars in IC 1590. We investigate the ages of stars in the two regions, but the age difference between the two regions is not comparable to the timescale of the passage of an ionization front. Also, the proper motion vectors of the NGC 281 West stars relative to IC 1590 do not show any systematic receding motion from the cluster. Our results suggest that stars in NGC 281 West might have been formed spontaneously. In conclusion, the formation of NGC 281 can be understood in the context of hierarchical star formation model.