• Kyungpook Mathematical Journal
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• v.50 no.3
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• pp.389-397
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• 2010

In this paper we introduce the new generalized difference sequence space $\ell_\infty$($\Delta_v^n$, M,p,q,s), $\bar{c}$($\Delta_v^n$,M,p,q,s), $\bar{c_0}$($\Delta_v^n$,M,p,q,s), m($\Delta_v^n$,M,p,q,s) and $m_0$($\Delta_v^n$,M,p,q,s) defined over a seminormed sequence space (X,q). We study some of it properties, like completeness, solidity, symmetricity etc. We obtain some relations between these spaces as well as prove some inclusion result.

• Journal of the Korean Chemical Society
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• v.30 no.3
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• pp.301-306
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• 1986

The rate constants for the solvolysis reactions of p-methoxybenzylchloride in ethanol-water mixtures were determined at 2$^{\circ}$ and 10$^{\circ}C$ up to 1600bar. Rates of reaction were increased with increasing temperature and pressure, and decreased with increasing solvent composition of ethanol mole fraction. From the rate constants, the values of the activation parameters (${{\Delta}V_o}^{\neq},\;{\Delta}{\beta}^{\neq},\;{\Delta}H^{\neq},\;and\;{\Delta}S^{\neq}$) were evaluated. The values of ${{\Delta}V_o}^{\neq}$ and ${\Delta}{\beta}^{\neq}$ exhibit the extremum behavior at about 0.30 mole fraction of ethanol. This behavior is discussed in terms of solvent structure variation. From these results, it could be postulated that the reaction proceeds through $S_N1$ mechanism.

• Journal of the Korean Society of Marine Environment & Safety
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• v.21 no.2
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• pp.179-187
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• 2015

The purpose of this study is to identify the aspect that the traffic distribution function changes, according to the direction of the datum line and the horizontal and vertical positions of the datum point applied when it is calculated. Targeting routes at the entrance of Mokpo Harbor, this study tested using AIS survey data of January 2013 the effects of the three variables-direction of the datum line(${\theta}$), horizontal position($\mathfrak{L}_H$) and vertical position($\mathfrak{L}_V$) on mean ($\bar{x}$) and standard deviation (${\delta}$). The test result showed that $\bar{x}$ and ${\delta}$ were changed according to the change of ${\theta}$, because the extracted sample data were changed according to ${\theta}$; and the changes of $\bar{x}$ and ${\delta}$ according to ${\theta}$ were drawn as the relation of the sine function' sum. In addition, it was found that setting up ${\theta}$ that the change value of ${\delta}$ becomes the least as the direction of the datum line was valid, to determine the optimum passage distribution function on complex waters with multiple branches of route. The result of this study is expected to be used as basic data to understand maritime traffic flow based on more quantified data of normal distribution and make decisions related to maritime traffic safety management.

• Journal of the Korean Chemical Society
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• v.30 no.1
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• pp.40-46
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• 1986

Rate constants for the solvolysis of o-methylbenzyl chloride were determined at 30$^{\circ}$ and 40$^{\circ}$C in aqueous ethanol mixtures under various pressures up to 1600 bar. From the rate constants, the activation parameters ${\Delta}V^{\neq}$, ${\Delta}{\beta}^{\neq}$, ${\Delta}H^{\neq}$, ${\Delta}S^{\neq}$ and${\Delta}G^{\neq}$ were evaluated. The values exhibit the extremum behavior at about 0.30 mole fraction of ethanol. This behavior is discussed in terms of electrostriction. To examine the reaction mechanism by Laidler and Eyring equation, we compared the rate constants with the dielectric constants of aqueous ethanol and the number of water molecule participated in the transition state. It was concluded that solvolytic reaction proceeds via $S_N$1 mechanism.

• Journal of the Korean Chemical Society
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• v.37 no.6
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• pp.555-561
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• 1993

Ultraviolet spectrophotometric investigation has been carried out on the system of iododestannylation iodine and tetramethyltin in methanol. The transient CT absorption spectrum can be observed and the subsequent disappearance of CT absorption spectrum was accompained by the cleavage of tetramethyltin with iodine. From there, the rate constants for the iododestannylation were determined at 10, 25 and 35$^{\circ}C$ up to 1600 bar and the reaction rates were increased with increasing temperature and pressure. From these rate constants, the values of the activation parameters (${\Delta}V^\neq,\;{\Delta}{\beta}^{\neq},\;{\Delta}H^{\neq},\;{\Delta}S^{\neq}\;and\;{\Delta}G^{\neq}$) were obtained. The activation volumes and activation compressibility coefficients were both negativity. The activation enthalpies were positive and activation entropies had large negative values. From these values discussed in terms of solvent structure variation of transition state and mechanism. From these results, it was found that the reaction is followed with $S_E2$ mechaenism and weakened $S_E2$ mechanism nature by increasing pressure.

• Journal of the Korean Chemical Society
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• v.29 no.3
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• pp.239-246
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• 1985

The equilibria of chemical reaction between [Cu(dl-trans-[14]-diene)]$^{2+}$ and L$^{n-}$(S$_2$O$_3^{2-}$, SCN$^-$, I$^-$, NO$_2^-$) ions were studied by the spectrophotometric method in the range of 15 to 35$^{\circ}C$ and 1 to 1500bar. The equilibrium constants(K) for L$^{n-}$ = S$_2$O$_3^{2-}$, SCN$^-$, I$^-$ and NO$_2^-$ ions at 25$^{\circ}C$ and 1500bar were 3.0, 1.9, 0.6 and 0.5, respectively. The values of K decreased with increasing pressure and temperature. From the temperature effect on equlibrium constant, the thermodynamic parameters(${\Delta}G^{\circ}$, ${\Delta}H^{\circ}$, ${\Delta}S^{\circ}$) of reaction were evaluated and the reactions of [Cu(dl-trans-[14]-diene)]2+ ion with S$_2$O$_3^{2-}$, SCN$^-$ and I$^-$ except NO$_2^-$ ion were exothermic. The volume changes of reaction(${\Delta}$V) had positive values for all the used anions. The values of ${\Delta}$V in cm$^3$/mole for S$_2$O$_3^{2-}$ ion at 1,500, 1,000 and 1,500bar were 26, 22, 19 and 16, and those for S$_2$O$_3^{2-}$, SCN$^-$, I$^-$ and NO$_2^-$ ions at atmospheric pressure 26, 30, 64 and 45, respectively. Bonding character between Cu(Ⅱ)-complex ion and L$^{n-}$ was discussed by comparing both the equlibrium constants experimentally determined and those calculated according to Fuoss's ion-pair equation in case of S$_2$O$_3^{2-}$ ion.

• Journal of Institute of Control, Robotics and Systems
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• v.6 no.6
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• pp.441-446
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• 2000

This paper presents an approach for the prediction of optimal heating load using a diagonal recurrent neural networks(DRNN) and data base system of outdoor temperature. In the DRNN, a dynamic backpropagation(DBP) with delta-bar-delta teaming method is used to train an optimal heating load identifier. And the data base system is utilized for outdoor temperature prediction. Compared to other kinds of methods, the proposed method gives better prediction performance of heating load. Also a hardware for the controller is developed using a microprocessor. The experimental results show that prediction enhancement for heating load can be achieved with the proposed method regardless of the its inherent nonlinearity and large time constant.

• Proceedings of the Korean Institute of Intelligent Systems Conference
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• 2005.04a
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• pp.335-339
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• 2005

본 논문에서는 퍼지 RBF 네트워크의 학습 성능을 개선하기 위하여 Delta-bar-Delta 알고리즘을 적용하여 학습률을 동적으로 조정하는 개선된 퍼지 RBF 네트워크를 제안한다. 제안된 학습 알고리즘은 일반화된 델타 학습 방법에 퍼지 C-Means 알고리즘을 결합한 방법으로, 중간층의 노드를 자가 생성하고 중간층과 출력충의 학습에는 일반화된 델타 학습 방법에 Delta-bar-Delta 알고리즘을 적용하여 학습률을 동적으로 조정하여 학습 성능을 개선한다. 제안된 RBF 네트워크의 학습 성능을 평가하기 위하여 컨테이너 영상에서 추출한 40개의 식별자를 학습 데이터로 적용한 결과, 기존의 ART2 기반 RBF 네트워크와 기존의 퍼지 RBF 네트워크 보다 학습 시간이 적게 소요되고, 학습의 수렴성이 개선된 것을 확인하였다.

• Proceedings of the Korea Inteligent Information System Society Conference
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• 2004.11a
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• pp.195-202
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• 2004

일반적으로 운송 컨테이너의 식별자들은 크기나 위치가 정형화되어 있지 않고 외부 잡음으로 인하여 식별자의 형태가 변형될 수 있기 때문에 일정한 규칙으로 찾기는 힘들다. 본 논문에서는 이러한 특성을 고려하여 컨테이너 영상에 대해 Canny 마스크를 이용하여 에지를 검출하고, 검출된 에지 정보에서 영상획득 시 외부 광원에 의해 수직으로 길게 발생하는 잡음들을 퍼지추론 방법을 적용하여 제거한 후에 수직 블록과 수평 블록을 검출하여 컨테이너의 식별자 영역을 추출하고 이진화 한다. 이진화된 식별자 영역에 대해 검정색의 빈도수를 이용하여 흰바탕과 민바탕을 구분하고 윤곽선 추적 알고리즘을 적용하여 개별 식별자를 추출한다. 추출된 개별 식별자의 인식은 개선된 퍼지 RBF 네트워크를 제안하여 적용한다. 제안된 퍼지 RBF 네트워크는 퍼지 C-Means 알고리즘을 중간층으로 적용하고 중간층과 출력층 간의 학습에는 일반화된 델타 학습 방법과 Delta-bar-Delta 알고리즘을 적용하여 학습 성능을 개선한다. 실제 컨테이너 영상을 대상으로 실험한 결과, 기존의 식별자 추출 방법보다 제안된 식별자 추출 방법이 개선되었고 기존의 퍼지 RBF 네트워크 보다 제안된 퍼지 RBF 네트워크가 컨테이너 식별자의 학습 및 인식에 우수함을 확인하였다.

• Proceedings of the KAIS Fall Conference
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• 2003.11a
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• pp.84-87
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• 2003

This paper proposes the enhanced REF network, which arbitrates learning rate and momentum dynamically by using the fuzzy system, to arbitrate the connected weight effectively between the middle layer of REF network and the output layer of REF network. ART2 is applied to as the learning structure between the input layer and the middle layer and the proposed auto-turning method of arbitrating the learning rate as the method of arbitrating the connected weight between the middle layer and the output layer. The enhancement of proposed method in terms of learning speed and convergence is verified as a result of comparing it with the conventional delta-bar-delta algorithm and the REF network on the basis of the ART2 to evaluate the efficiency of learning of the proposed method.