• Applied Chemistry
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• v.9 no.2
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• pp.25-28
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• 2005

To evaluate the dental restorative application of polymer composites filled with hydroxyapatite (HAP) which is an inorganic component of human bone material, dental properties of the polymer composites were investigated. A visible light system was utilized to activate the acrylate resin matrix of the composites. Maximum loading percentage of HAP in composite was 65 wt% and the depth of cure was 6.0 mm which can be applicable for dental restoration. With increasing the HAP content, degree of conversion of polymer composites was slightly decreased, however, polymerization shrinkage value was not varied. Diametral tensile strength value was enhanced with an increase of HAP content, however, there was no strict trend between flexural strength and HAP concentration. Anyhow, polymer composites prepared herein have superior mechanical properties sufficient specifications applicable to dental materials.

• Journal of the Korean Chemical Society
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• v.16 no.1
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• pp.50-55
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• 1972

The mechanical degradation of $poly(\alpha-methyl$ styrene) in several mixed solvents (chlorobenzene-n-butyl alcohol, chlorobenzene-sec-butyl alcohol, chlorobenzene-Kerosene, chlorobenzene-methylketone) was studied using the capillary flow method. The velocity constant of scission reaction (K) and the limited degree of polymerization (g) were compared at the same value of [${\eta}$], which is considered as the parameter of molecular dimension of polymers in solution. As results, (K) did not change much, even if the species and the volume fraction of poor(non-) solvents changed, while the value of (g) changed according to the species of poor (non-) solvents and the value of [${\eta}$] these results were discussed.

• Archives of Pharmacal Research
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• v.19 no.1
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• pp.18-22
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• 1996

Acrylate-terminated poly (ethylene glycol) (PEG) macromer was prepared by the reaction of PEG with acryloyl chloride. Photopolymerization of PEG macromer resulted in the formation of cross-linked PEG network. Interpenetrating polymer networks (IPNs) based on PEG and poly(acrylic acid) (PAA) was obtained via template polymerization of AA to the PEG network by UV curing. The swelling degree of the IPNs hydrogel increased with an increase of pH value due to the association-dissociation between carboxylic acid of PAA and either of PEG through hydrogen bounding. The swelling-deswelling behavior proceeded reversibly for the IPNs upon changing pH. Release of indomethacin from the IPNs demonstrated "on-off" regulation with pH fluctuation.

• Proceeding of EDISON Challenge
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• 2016.03a
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• pp.155-162
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• 2016

This study attempts to reveal structures of two-dimensional ring polymer solutions in various polymer concentrations ranging from dilute to concentrated regime. Polymer sizes, single molecule structure factors, bond correlation functions and monomer density distribution functions from center of mass are given in order to clarify the polymer structures. Our study shows that a ring in dilute solution maintain pseudo-circular structure with self-avoiding walk (SAW) statistics, and it seems to be composed of two connecting SAW linear chains. In semidilute solutions, ring polymers are not entangled with each other and adopt collapsed configurations. Such assumption of collapsed structures in the semidilute regime gives an overlap concentration of ${\varphi}^*{\sim}N^{-1/2}$ where N is degree of polymerization. By normalizing the polymer concentration by these overlap concentration, we find universal behaviors of polymer sizes and structure factors regardless of N.

• Journal of the Korean Applied Science and Technology
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• v.15 no.1
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• pp.9-15
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• 1998

Poly(p-anol-formaldehyde) cinnamates(AGEFCs) were synthesized to prepare a photo-sensitive polymer which enabled to be photodimerized via 6-center reaction. The photocharacteristics of the mixture of the AGEFCs and a sensitizer after exposure to light was tested. The yield of the residual film, which was closely related to the sensitivity of the film, was affected by the degree of polymerization of the backbone resin, sensitizers and their concentration. AGEFC-3 revealed a good photosensitive effect such as about 73% yield of residual film at 128 min. of exposed time.

• Journal of the Korean Chemical Society
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• v.15 no.3
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• pp.109-116
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• 1971

The mechanical degradation of poly (${\alpha}$-methyl styrene) in several mixed solvents (toluene-n-butyl alcohol, toluene-sec-butyl alcohol, toluene-kerosene, toluene-methyl ethyl ketone), from $1^{\circ}C to $45^{\circ}C$, was studied using the capillary flow method. The velocity constant of scission reaction (k) and the limited degree of polymerization (g) were compared at the same value of [${\eta}$] at each temperatures. As results, mechanical degradation of polymer in dilute mixed solutions is affected by composition of solvents around the polymer chains.

• Journal of Electrical Engineering and Technology
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• v.12 no.2
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• pp.840-845
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• 2017

In this paper, in order to investigate the lifetime of oil-paper insulation, specimens were artificially aged with thermal and electrical multiple stresses. Accelerated ageing factors and equivalent operating years for each aging temperatures were derived from results of tensile strengths for the aged paper specimens. Also, the evaluation for the multi-stress aged specimens were carried out through the measurement of impulse breakdown voltage at high temperature of $85^{\circ}C$. The lifetimes of the oil-paper insulations were calculated with the value of 66.7 for 1.0 mm thickness specimens and 69.7 for 1.25 mm thickness specimens throughout the analysis of impulse BD voltages using equivalent operating years, which means that dielectric strengths would not be severely decreased until the mechanical lifetime limit. Therefore, for the lifetime evaluation of the oil-paper insulation, thermal aging would be considered as a dominant factor whereas electrical degradation would be less effective.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.44 no.3
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• pp.79-85
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• 2012

In this study, purified cellulose was prepared from rice husk which is one of the major agricultural residues in Korea. The various bleaching processes such as ozone bleaching, $ClO_2$ bleaching and $H_2O_2$ bleaching were applied to remove residual lignin and impurities. In order to increase the contents of ${\alpha}$-cellulose contents, the effects of acid and alkali treatments were evaluated. Although the multi stages of the bleaching processes resulted in less than 0.5 % residual lignin contents, the application of ozone leaded to the decrease in DP(degree in Polymerization) and ${\alpha}$-cellulose contents. The alkali treatment after bleaching processes resulted in pure cellulose which showed more than 98% of ${\alpha}$-cellulose contents.

• Elastomers and Composites
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• v.25 no.4
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• pp.273-279
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• 1990

The graft polymerization of 2-hydroxyethylmethacrylate(HEMA) and vinyltriethoxysilane(VTES) onto styrene-butadiene-styrene block copolymer(SBS) was carried out in toluene, with radical initiator such as benzoyl peroxide(BPO) and 2, 2'-azo-bis-isobutyronitrile(AIBIN) under nitrogen atmosphere. The degree of grafting was increased with the increases of the reaction temperature and time. And the effeciency of BPO was superior to that of AIBN. The mechanical properties and molecular weight of graft products were measured and the applicability as adhesive of plasticized PVC leather was examined.

• Textile Coloration and Finishing
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• v.4 no.2
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• pp.69-75
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• 1992

This study was carried out to compare the effect of caustic soda with the effect of caustic potash on cotton fabric. Instead of caustic potash, sodium carbonate similar in chemical composition to caustic potash was used. The damage of cotton cellulose by repeated washing in various alkaline solutions at 8$0^{\circ}C$, 60 rpm was examined. The damage of cotton cellulose by the variation of copper number, carboxyl content, degree of polymerization and retained tensile strength was estimated. The results obtained at this study are as follows; 1. The damage of cotton by caustic soda was severer than caustic potash. The retained tensile strength at 50 washing cycle in caustic soda was 59% and in sodium carbonate was 80%. 2. By adding soap to caustic soda, the damage of cotton fabric decreased because contact area between fabric and air diminished by foam. 3. Detergency of EMPA 101 in caustic soda was lower than sodium carbonate. Consequently, using caustic soda that damage fabric severely and have lower detergency for caustic potash is unreasonable.