• KSBB Journal
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• 제14권3호
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• pp.315-321
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• 1999

The relationships between the explosive 2,4,6-trinitrotoluene (TNT) degradation by Stenotrophomonas maltophilia and several relevant physicochemical environmental parameters were examined. At neutral pH of the cultures, the degradation of TNT proceeded to completion, whereas only about 50% of TNT was utilized when the cultures were adjusted to acidic pH. The effect of various co-substrates (e.g., glucose, fructose, acetate, citrate, succinate) on the degradation of TNT by the test culture of S. maltophilia was evaluated. The results indicated that, among the various co-substrates studies, the test culture that received 2 mM fructose degraded 100 mg/L of TNT completely within 20 days of incubation at ambient temperature, whereas partial degradation of TNT was observed in the test culture with acetate, citrate, or succinate as a co-substrate, respectively. In fact, fructose was the best co-substrate for TNT degradation in this experiment. The effect of supplemented nitrogens [e.g., (NH$_4$)$_2$,SO$_4$, NH$_4$Cl. urea] on the TNT degradation was monitored. All supplemented nitrogens in this study were inhibitory to TNT degradation. Addition of 1% Tween80 accelerated TNT degradation, and showed complete degradation of TNT within 8 days of incubation. Addition of yeast extract resulted higher growth yields, based on turbidity measurement, but it inhibited TNT degradation.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 춘계학술대회논문집A
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• pp.268-273
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• 2001

Fossil power plants operated in high temperature condition are composed of components such as turbine, boiler, and piping system. Among these components, turbine blades made with 12%Cr steel operate at a temperature above $500^{\circ}C$. Due to the long term service, turbine blades experience material degradation manifested by change in mechanical and microstructural properties. The need to make life assessment and to evaluate material degradation of turbine blade is strongly required but in reality, there is a lack of knowledge in defining failure mechanism and fundamental data for this component. Therefore, in making life assessment of turbine blade, evaluation of material degradation must be a priority. For this purpose, evaluation of toughness degradation is very important. The major cause of toughness degradation in 12Cr turbine blade is reported to be critical corrosion pitting induced by segregation of impurity elements(P etc.), coarsening of carbide, and corrosion, but the of materials for in-service application. In this study, the purpose of research is focused on evaluating toughness degradation with respect to operation time for 12%Cr steel turbine blade under high temperature steam environment and quantitatively detecting the degradation properties which is the cause of toughness degradation by means of non-destructive method, electrochemical polarization.

• 복식문화연구
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• 제20권2호
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• pp.238-250
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• 2012

This study examined the degradation behavior of SB(standard berberine) dye and SB dyed silk using HPLC-MS instrument after degradation in the hydrogen peroxide/ultraviolet ray radiation/oxygen system up to 9 days and 40 hours respectively. In the degraded samples, berberine was detected at 5.2 min in the SB dye and 5.3 min in the SB dyed silk with its molecular ion=336 and the UV spectra of quaternary alkaloid. Degradation product 3(m/z=102) newly appeared after 5 day degradation treatment with continued increase till the end of degradation treatment. The amount of berberine in the degraded dye decreased with degradation progression. In the silk dyeings, berberine was detected only up to 21 hour degradation sample. The amount of berberine decreased dramatically during the first 6 hours of degradation treatment. The CIELAB color measurement of the silk dyeings showed dramatic change in the b* value, near zero in the 40 hour degraded silk. CIELAB and Munsell color measurements were in agreement with the HPLC-MS results of the dyed silk in the change of berberine content that the degraded silk became white and lost yellow color.

• 대한기계학회논문집
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• 제17권9호
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• pp.2271-2279
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• 1993

In the case of life prediction on the structures and machines after long service, it is natural to consider a degradation problems. Most of degradation data form practical structures are isolated data obtained at the time of periodical inspection or repair. From such data, it may be difficult to obtain the degradation curve available and necessary for life prediction. In this paper, for the purpose of obtaining a degradation curves, developed the simulate degradation method and fatigue test and Charpy impact test were conducted on the degraded, simulate degraded and recovered materials. Fatigue life prediction were conducted by using the relationship between fracture transition temperature (DBTT : vTrs) obtained from the Charpy impact test through the degradation process and fatigue crack growth constants of m and C obtained from the fatigue test.

• 한국신뢰성학회지:신뢰성응용연구
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• 제18권1호
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• pp.80-86
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• 2018

Purpose: This article provides a mathematical model for the accelerated degradation test when the performance degradation characteristic follows the lognormal distribution. Method: For developing test plans, the total number of test units and the test time are determined based on the minimization of the asymptotic variance of the q-th quantile of the lifetime distribution at the use condition. Results: The mathematical model for the accelerated degradation test is provided. Conclusion: Accelerated degradation test method is widely used to evaluate the product lifetime within a resonable amount of cost and time. In this article. a mathematical model for the accelerated degradation test method is newly developed for this purposes.

• 대한화학회지
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• 제11권2호
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• pp.70-76
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• 1967

Structural changes attending polyacrylonitrile(PAN) upon heating and treating with nucleophilic reagents have been studied for some time and a few authors have studied on the thermal degradation, particularly on the characterization of degradation products in PAN. It is the purpose of this paper to report the kinetic study on the thermal degradation above $250^{\circ}C$ and make some suggestions as to the degradation process and mechanism in PAN. The degradation process in PAN is considered that three reactions are combined in two steps. Random chain scission accompanying the naphthylidine-type ring formation is the first step and the degradation of naphthylidine-type ring occurred as the next step. The reactions in the first step are competitive so that the maximum weight loss on pyrolysis of PAN, under such a condition that the degradation of naphthylidine-type ring is negligible, is depended on the relative reaction rate of these two competitive reactions.

• Preventive Nutrition and Food Science
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• 제12권2호
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• pp.115-118
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• 2007

Tocopherols are important lipid-phase antioxidants that are subject to heat degradation. Therefore, kinetic analyses for oxidative degradation of tocopherols as a function of temperatures and times were performed. Alpha-, gamma- and delta-tocopherols dissolved in glycerol were heated at 100${\sim}$250$^{\circ}C$ for 5～60 min. Oxidized tocopherols were analyzed by HPLC using a reversed phase ${\mu}$-Bondapak C$_{18}$-column with two kinds of elution solvent systems in a gradient mode. The degradation kinetics for tocopherols followed a first-order kinetic model. The rate of tocopherol degradation was dependent on heating temperatures. The degradation rate constants for ${\gamma}$- and ${\delta}$-tocopherols were higher than those for ${\alpha}$-tocopherol. The experimental activation energies of ${\alpha}$-, ${\gamma}$- and ${\delta}$- tocopherols were 2.51, 6.05 and 5.34 kcal/mole, respectively. The experimental activation energies for the oxidative degradation of ${\gamma}$- and ${\delta}$-tocopherols were higher than that of ${\alpha}$-tocopherol.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2008년도 춘계학술대회논문집
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• pp.593-598
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• 2008

In the present study, degradation characteristics of pumps in nuclear power plants were investigated to provide the information of degradation mechanism and stressors. The failure records of pumps for the periods 2000 to 2006 on INPO(Institute of Nuclear Power Operations) EPIX(Equipment Performance and Information Exchange System) DB were reviewed. The 1,834 failure records reveal that the critical areas of pump failures are bearing, mechanical seal, gasket/o-ring, shaft, impeller, coupling and packing. Based on the failure rate of critical areas, the important degradation mechanism and stressors were determined. Additionally, the relationship between degradation mechanism and stressors such as wear was examined. Finally, the monitoring parameters related to degradation and stressors were discussed for the future development of degradation evaluation and prognosis technology of pumps.

• KSBB Journal
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• 제25권1호
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• pp.103-107
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• 2010

Oil degradation agent was developed with organic sludge and modified peat moss (MPM) to recover oil contaminated soil. Waste sludge discharged from wastewater treatment plant of chemical plant in Ulsan National Industrial Park was used as organic sludge, and MPM was purchased. Organic sludge was adequate to use as growth medium for microorganism, the surface of MPM had porous structure which could enhance the cultivation condition of oil degradation microorganisms. Water contents and TPH variation with time were observed to investigate the degradation capacity of developed degradation agent. Water contents were rapidly decreased with higher contents of MPM, however, in case of TPH, high MPM content decreased the degradation capacity. Therefore, it was recommended that the content of MPM was controlled to below 10% in degradation agent as mixing organic sludge with MPM.

• 한국환경과학회지
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• 제11권10호
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• pp.1103-1108
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• 2002

In order to evaluate the degradation organophosphorus pesticide, EPN, in water environment, the effects of water temp.(10$^{circ}C,\;30^{\circ}C$), pH(3-11) and sunlight on its degradation were investigated during 10 days. The degradation rate of EPN(200 rpm) was faster at higher water temp. and higher pH, i.e., its degradation rate at pH 3, 5, 7, 9, 11 was 57, 63, 66, 69, 75%(1$0^{\circ}C$), and 70, 74, 79, 91, 97%(3$0^{\circ}C$) after 10 days, respectively. The effect of water temp. on its degradation was little in acidic condition, but was rather great in alkaline condition, with time. EPN was degraded fast at the alkaline condition by photolysis. At the condition of pH 11, EPN was degraded fast at the early stage in the first 2 days, but after that the degradation rate was weakened.