• Title/Summary/Keyword: Degradation rate

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Effect of thermal conductivity degradation on the behavior of high burnup $UO_2$ fuel

  • Lee, Byung-Ho;Koo, Yang-Hyun;Sohn, Dong-Seong
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05c
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    • pp.265-270
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    • 1996
  • The temperature distribution in the pellet was obtained from beginning the general heat conduction equation. The thermal conductivity of pellet used the SIMFUEL data that made clear the effect of burnup on the thermal conductivity degradation. Since the pellet rim acts as the thermal barrier to heat flow. the pellet was subdivided into several rings in which the outer ring was adjusted to play almost the same role as the rim. The local burup in each ring except the outer ring was calculated from the power depression factor based on FASER results. whereas the rim burnup at the outer ring was achieved by the pellet averaged burnup based on the empirical relation. The rim changed to the equivalent Xe film so the predicted temperature shooed the thermal jump across the rim. The observed temperature profiles depended on linear heat generation rate. fuel burnup. and power depression factor. The thermal conductivity degradation modelling can be applied to the fuel performance code to high burnup fuel,

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Strength Degradation from Contact Fatigue in Self-toughened Glass-ceramics

  • Lee, Kee Sung;Kim, Do Kyung;Woo, Sang Kuk;Han, Moon Hee
    • The Korean Journal of Ceramics
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    • v.7 no.2
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    • pp.63-69
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    • 2001
  • We investigated strength degradations from cyclic contact fatigue in self-toughened glass-ceramics. Hertzian indentation was used to induce cyclic contact load. Dynamic fatigue was also performed with changing stress rates from 0.01 to 10000 MPa/sec. After that, strength data and fracture origins were analysed. As the number of contact cycles increased or stressing rate decreased, severe strength degradation occurred by as much as 50% because of radial cracks developed from microcrack coalescence.

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Solid Oxide Fuel Cells for Power Generation and Hydrogen Production

  • Minh, Nguyen Q.
    • Journal of the Korean Ceramic Society
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    • v.47 no.1
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    • pp.1-7
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    • 2010
  • Solid oxide fuel cells (SOFCs) have been under development for a variety of power generation applications. Power system sizes considered range from small watt-size units (e.g., 50-W portable devices) to very large multi-megawatt systems (e.g., 500-MW base load power plants). Because of the reversibility of its operation, the SOFC has also been developed to operate under reverse or electrolysis mode for hydrogen production from steam (In this case, the cell is referred to as solid oxide electrolysis cell or SOEC.). Potential applications for the SOEC include on-site and large-scale hydrogen production. One critical requirement for practical uses of these systems is long-term performance stability under specified operating conditions. Intrinsic material properties and operating environments can have significant effects on cell performance stability, thus performance degradation rate. This paper discusses potential applications of the SOFC/SOEC, technological status and current research and development (R&D) direction, and certain aspects of long-term performance degradation in the operation of SOFCs/SOECs for power generation/hydrogen production.

Degration of Phenol by Using Nano-sized TiO2 Photocatalysts (나노 사이즈 TiO2 광촉매를 이용한 페놀 분해)

  • Choi, Sang-Keun;Kim, Dong-Joo;Kim, Kyo-Seon
    • Journal of Industrial Technology
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    • v.21 no.A
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    • pp.273-278
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    • 2001
  • In this study, we prepared nano-sized $TiO_2$ particles for various process variables by the diffusion flame reactor and we collected $TiO_2$ particles by thermophoresis. It is found that the size of $TiO_2$ particles increases, as the flame temperature or the inlet $TiCl_4$ concentration increase or the total gas flow rate decreases. We investigated the photo-degradation of phenol wish the prepared $TiO_2$ particles. We found the optimum amounts of $TiO_2$ photocatalysts for our experimental apparatus and investigated the photo-degradation efficiencies of phenol, changing the process variables such as size of $TiO_2$ photocatlysts, phase ratio of rutile/anatase, concentration of phenol, input ratio of $O_2$. Degradation efficiencies of phenol were almost 95% in 15 minutes for the standard conditions of our experiments.

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The Comparison of Photocatalysis and Sonophotocatalysis for Benomyl Degradation (광촉매공정과 초음파를 접목시킨 광촉매공정에 의한 Benomyl의 분해 비교)

  • An, Sang-Woo;Park, Jae-Hong;Cho, Il-Hyoung;Chang, Soon-Woong
    • Journal of Korean Society on Water Environment
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    • v.22 no.4
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    • pp.585-589
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    • 2006
  • Comparison between photocatalysis and sonophotocatalysis were performed in lab-scale experiments for the treatment of benomyl. The effect of operational parameters, i.e., initial benomyl concentration, $TiO_2$ concentration, $H_2O_2$ concentration on the degradation rate of aqueous solution of benomyl has been examined. The optimal conditions for photocatalysis and sonophotocatalysis processes were determined: initial Benomyl concentration was 3 mg/L, the concentration of $TiO_2$ was 2 g/L and $H_2O_2$concentration was 1.5 mM. Under the optimal conditions, sonophotocatalysis was effective for inducing faster degradation of the benomyl.

Photocatalytic Degradation of Atrazine and PCP using TiO2 (TiO2 광촉매를 이용한 Atrazine과 PCP의 분해)

  • Park, Jae-Hong;An, Sang-Woo;Chang, Soon-Woong
    • Journal of Korean Society on Water Environment
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    • v.20 no.6
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    • pp.577-582
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    • 2004
  • The photocatalytic degradation of atrazine and PCP, a endocrine disruptors, has been investigated over $TiO_2$ photocatalysts under ultraviolet (UV) light irradiation. The effect of operational parameters, i.e., pH, light intensity and persulphate concentration on the degradation rate of aqueous solution of atrazine and PCP has been examined. The results presented in this work demonstrate that, as pH and the light intensity increased, the photocatalytic reaction rates were enhanced. Individual use of $TiO_2$-persulphate was far more effective than using only $TiO_2$ in atrazine and PCP removal. Based on the overall experimental results, the photocatalytic oxidation of atrazine and PCP with the coated $TiO_2$ photocatalyst is found to be very effective under the operational conditions delineated in this study.

Optimal Remediation Design Considering Effects of Degradation Processes : Pumping strategy with Enhanced Natural Attenuation

  • Park Dong-Kyu;Lee Kang-Kun
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.371-374
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    • 2005
  • We accomplished optimization for pump and treat (P&T) designs in consideration of degradation processes such as retardation and biodegradation, which are significant for contaminant fate in hydrogeology. For more desirable remediation, optimal pumping duration and minimum pumping rate constraint problems are studied. After a specific P&T duration, it replaces the P&T with the enhanced natural attenuation (ENA), which induces aerobic biodegradation by maintaining oxygen concentration. The design in this strategy carries out the optimization for the number and locations of oxygen injection wells.

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Detection of Radiation Degradation of LDPE by ESR Spectroscopy (전자스핀공명을 이용한 저밀도 폴리에틸렌의 방사선 열화 검지)

  • Kim Ki-Yup;Lee Chung;Ryu Boo-Hyung
    • Journal of the Korean Society of Safety
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    • v.20 no.1 s.69
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    • pp.81-86
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    • 2005
  • This study has investigated radiation degradation of low density polyethylene(LDPE). Samples were irradiated up to 800kGy using a $Co^{60}\;\gamma-ray$ at a dose rate of 5kGy/hr in the presence of air atmosphere at room temperature. After irradiation, storing for 2 weeks, free radical measurement of LDPE has established by electron spin resonance(ESR). ESR measurement showed that free radical concentration(FRC) was increased with radiation dose and decreased with the time. The radical types showed alkyl, allyl, and peroxy radical with the irradiation, these changed to peroxy radical with the time.

The characteristic research of a Bi-2223 wires by the Various Transport Current (수송전류에 따른 Bi-2223 선재의 특성연구)

  • 오정훈;배덕권;강형구;안민철;이상진;고태국
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2003.02a
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    • pp.220-223
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    • 2003
  • High-Tc superconducting(HT S) systems are commercialized by many study on high-Tc superconductor. For the successful commercialization of superconducting systems using Bi-2223 wires, the database on the degradation of critical current is essentially needed. In this paper, critical current variation of Bi-2223 wires according to the transport time was investigated. The degradation rate of critical current was also calculated. Solenoid type specimens have the length of 190cm Bi-2223 wire and double-pancake type specimens have the length of l0m wire were tested. Tested Bi-2223 wires are commercialized products of AMSC (American Superconductor) and Innost. When the transportation current was 95% of critical current, the degradation of critical current was appeared after 5 hours of transport time.

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Degradation and hole formation of the Te-based thin films (Te을 기본으로 한 박막에서의 열화와 미세구멍형성에 관한 연구)

  • Lee, Hyun-Young;Park, Tae-Sung;Um, Jeong-Ho;Lee, Young-Jong;Chung, Hong-Bay
    • Proceedings of the KIEE Conference
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    • 1987.11a
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    • pp.207-209
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    • 1987
  • This paper reports the effect of additive elements such as Bi, Sb on degradation and hole formation of the Te-Se thin films. Changes in light transmission were used to monitor the degradation rate of thin Te films in an accelerated temperature-humidity environment. In thin accelerated temperature-humidity environment, $(Te_{86}Se_{14})_{70}Bi_{30}$ thin film was stable and $(Te_{86}Se_{14})_{50}Sb_{50}$ thin film was unstable in comparison with the other films that used in this experiment. The hole formation was carried out in the Te-based thin films.

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