• 제목/요약/키워드: Degradation mechanism

검색결과 980건 처리시간 0.029초

X-ray Photoelectron Spectroscopy(XPS) 분석법을 이용한 FKM 오링의 노화 메카니즘 분석 연구 (Study on the Degradation Mechanism of FKM O-ring by X-ray Photoelectron Spectroscopy)

  • 이진혁;배종우;윤유미;최명찬;조남주
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2017년도 제48회 춘계학술대회논문집
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    • pp.168-171
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    • 2017
  • X-ray photoelectron spectroscopy(XPS) 분석법을 이용하여 FKM O-ring의 대기중에서의 노화 메카니즘을 관찰하였다. FKM O-ring은 선경 3.53mm, 내경 91.67mm인 오링을 시편으로 사용하였다. 노화 후 FKM O-ring의 oxygen 원소의 농도가 20.39%로 증가하였으며, fluorine 원소는 각각 8.29%로 감소하는 경향을 나타내었다. 이를 통하여 산소에 의한 산화 반응이 FKM O-ring의 주요 노화 반응으로 나타났다. C1s와 F1s 피크 분석 결과, FKM O-ring의 주쇄중 C-F 결합에서 산화 반응이 주로 진행되는 것으로 나타났다. 또한 O1s 피크 분석 결과, 산화 반응을 통하여 C-OH, C=O, 그리고 O=C-O 구조를 형성하며, 주로 카르복실기가 생성되는 것으로 나타났다.

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OLED degradation mechanism study using impedance spectroscopy

  • Kim, Hyun-Jong;Yang, Ji-Hoon;Ye, Seok-Min;Jeong, Jae-Wook;Chang, Seung-Wook;Boris, Crystal;Chung, Ho-Kyoon;Lee, Chang-Hee;Hong, Yong-Taek
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.1022-1025
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    • 2008
  • To the best of our knowledge, for the first time, we applied impedance spectroscopy to analysis on OLED degradation mechanism by monitoring impedance change during constant voltage aging, and modeling OLED with lumped circuit elements. Change in each element value was used to explain charge accumulation and field redistribution in each organic layer.

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핫 캐리어에 의한 GaAs HBT의 새로운 열화 메카니즘 (New degradation mechanism of GaAs HBT induced by Hot carriers)

  • 권재훈;김도현;송정근
    • 전자공학회논문지D
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    • 제34D권11호
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    • pp.30-36
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    • 1997
  • AlGaAs/GaAs HBTs are developed well enough to be commercialized as an active device in optical transmission system, but there remains the unanswered questions about reliability. In this paper we applied the reverse constant current stress at the high voltage in avalanche region for a long time to find out a new degradation mechanism of junctrion I-V. The unction off-set voltage at which the current vanishes to zero was shifted to the negative direction of applied bias due to the increment of leakage current as the stress time increases. It was identified that the degradation was induced by the hot carriers which were generated at space charge region and trapped at the interface between GaAs base and the passivation nitride enhancing the electric field across the nesa edge.

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철도차량 추진제어장치의 스트레스 분석 및 열화 메커니즘 (Stress Analysis and Degradation Mechanism of the Drive Control system for a Railway carriage)

  • 김기준;왕종배;최영찬
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 제2회 학술대회 논문집 일렉트렛트 및 응용기술전문연구회
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    • pp.21-24
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    • 2000
  • Traction motors driven by several type inverters have been subjected to increasing demands for higher operating temperature, more demands for duty cycles, higher starting current, frequent voltage transients and finally severe environmental exposure. For applications to inverter duty, traction motors needs a special insulation system, which has characteristics of increased bond strength, lower operating temperature and higher turn-to-tum insulation. Also it needs major contributors to insulation life and reliability of motors, which more considered by temperature, voltage, frequency, rise time, pulse configuration, wire thickness and insulation materials. In this paper, to evaluate of reliability and expected life, it is analyzed the several stresses and their degradation mechanism on insulation system of AC traction motor.

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암반풍화도에 따른 지질공학적 특성 저감효과 (Effects of Rock Weathering on the Degradation of Engineering Properties)

  • 이창섭;조태진
    • 터널과지하공간
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    • 제15권6호
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    • pp.411-424
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    • 2005
  • 풍화작용은 심부에서 생성된 암석이 지표에서 파괴되고 변질되어 현재의 환경조건과 평형을 이루는 산물을 형성하는 과정이다. 본 연구에서는 국내에서 가장 분포면적이 넓은 화강암질암의 풍화단계별 시료를 채취하여 편광현미경관찰, X-선 회절분석, 전자현미경관찰, 화학분석, 물성시험등을 수행하였다. 실험결과에 의거하여 풍화에 의해 형성되는 2차광물, 특히 점토광물의 형성과정을 확인하였고, 풍화에 따른 암석의 공학적인 성질변화와 물성저하의 메카니즘을 규명하였다.

휴대전자기기용 저용량 리튬이온 배터리의 충방전 열화 기구 분석 및 모니터링 (Evaluation and monitoring of degradation mechanism of Li-ion battery for portable electronic device)

  • 변재원
    • 한국신뢰성학회지:신뢰성응용연구
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    • 제13권2호
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    • pp.129-140
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    • 2013
  • As a fundamental experimental study for reliability improvement of lithium ion secondary battery, degradation mechanism was investigated by microscopic observation and acoustic emission monitoring. Microstructural observation of the decomposed battery after cycle test revealed mechanical and chemical damages such as interface delamination, microcrack of the electrodes, and solid electrolyte interphase (SEI). Acoustic emission (AE) signal was detected during charge and discharge of lithium ion battery to investigate relationships among cumulative count, discharge capacity, and microdamages. With increasing number of cycle, discharge capacity was decreased and AE cumulative count was observed to increase. Observed damages were attributed to sources of the detected AE signals.

Physical Aging Mechanism of Epoxy Coating by Hygrothermal Cycling Test

  • Kim, Min Hong;Lee, Gun Dae;Park, Jin Hwan
    • Corrosion Science and Technology
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    • 제5권5호
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    • pp.177-180
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    • 2006
  • The anticorrosive performance of epoxy coating was examined by using the hygrothermal cyclic test and the degradation mechanism of the coating was investigated by using the AC impedance method. The relationship between the results obtained from different tests was studied. It was revealed that the hygrothermal cyclic test can be used as an effective acceleration test for the degradation of organic coating. It was also found in hygrothermal cyclic test that the epoxy coatings have the resistance to stresses at some extent. The degradation of organic coating seems to be caused by the decrease of resistance of coating and the increase of both capacitance and free volume in the organic coating.

동결융해 반복을 받는 콘크리트 포장용 GFRP 다웰바의 장기성능저하 메커니즘 (Long-Term Degradation Mechanism of GFRP Dowel Bar for Jointed Concrete Pavement under Repeated Freezing-Thawing)

  • 원종필;장창일;박찬기;이상우
    • 대한토목학회논문집
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    • 제28권3D호
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    • pp.325-330
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    • 2008
  • GFRP 다웰바의 장기 내구성능 저하 메커니즘을 규명하기 위하여 실제 콘크리트 포장에서 발생할 수 있는 수분환경과 동결융해반복 환경하의 촉진 내구성능 평가를 실시하였으며 그에 따른 미세구조 분석을 통해 성능저하 열화 진행 메커니즘을 분석하였다. GFRP 다웰바의 내구특성 평가는 촉진환경에 노출 후 전단시험을 실시하여 분석하였으며 미세구조 분석을 위하여 SEM 사진과 가스흡착에 의한 공극측정을 실시하였다. 실험결과 수분환경 및 동결 융해반복 환경에 노출된 GFRP 다웰바는 내구특성 저하가 거의 나타나지 않았다. 이와 같은 결과는 미세구조분석에서 명확히 관찰 할 수 있었다.

Aging Mechanisms of Lithium-ion Batteries

  • Jangwhan Seok;Wontae Lee;Hyunbeom Lee;Sangbin Park;Chanyou Chung;Sunhyun Hwang;Won-Sub Yoon
    • Journal of Electrochemical Science and Technology
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    • 제15권1호
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    • pp.51-66
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    • 2024
  • Modern society is making numerous efforts to reduce reliance on carbon-based energy systems. A notable solution in this transition is the adoption of lithium-ion batteries (LIBs) as potent energy sources, owing to their high energy and power densities. Driven by growing environmental challenges, the application scope of LIBs has expanded from their initial prevalence in portable electronic devices to include electric vehicles (EVs) and energy storage systems (ESSs). Accordingly, LIBs must exhibit long-lasting cyclability and high energy storage capacities to facilitate prolonged device usage, thereby offering a potential alternative to conventional sources like fossil fuels. Enhancing the durability of LIBs hinges on a comprehensive understanding of the reasons behind their performance decline. Therefore, comprehending the degradation mechanism, which includes detrimental chemical and mechanical phenomena in the components of LIBs, is an essential step in resolving cycle life issues. The LIB systems presently being commercialized and developed predominantly employ graphite anode and layered oxide cathode materials. A significant portion of the degradation process in LIB systems takes place during the electrochemical reactions involving these electrodes. In this review, we explore and organize the aging mechanisms of LIBs, especially those with graphite anodes and layered oxide cathodes.

Feeder Pipe Inspection Robot with an Inch-Worm Mechanism Using Pneumatic Actuators

  • Choi, Chang-Hwan;Jung, Seung-Ho;Kim, Seung-Ho
    • International Journal of Control, Automation, and Systems
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    • 제4권1호
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    • pp.87-95
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    • 2006
  • The outlet feeder pipe thinning in a PHWR (Pressurized Heavy Water Reactor) is caused by a high pressure steam flow inside the pipe, which is a well known degradation mechanism called a FAC (Flow Assisted Corrosion). In order to monitor the degradation, the thickness of the outlet bends close to the exit of the pressure tube should be measured and analyzed at every official overhaul. This paper describes a mobile feeder pipe inspection robot that can minimize the irradiation dose to human workers by automating the measurement process. The robot can move by itself on the feeder pipe by using an inch worm mechanism, which is constructed by two gripper bodies that can fix the robot body on to the pipe, one extendable and contractible actuator, and a rotation actuator connected to the two gripper bodies to move forward and backward, and to rotate in a circumferential direction.