• Title/Summary/Keyword: Defense reaction

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Reaction Characteristics Study of Aluminum-Copper(II) Oxide Composites Initiated by the Electrostatic Discharge (Aluminum-Copper(II) Oxide Composite의 정전기에 의한 반응 특성 연구)

  • Kim, Minjun;Kim, Sung Ho;Kim, Jayoung;Im, Yeseul
    • Journal of the Korea Institute of Military Science and Technology
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    • v.21 no.5
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    • pp.591-598
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    • 2018
  • The reaction characteristics of aluminum-copper(II) oxide composites initiated by the electrostatic discharge were studied as changing the aluminum particle size. Three different sizes of aluminum particles with nano-size copper(II)-oxide particle were used in the study. These composites were manufactured by two methods i.e. a shock-gel method and a self-assembly method. The larger aluminum particle size was, the less sensitive and less violent these composites were based on the electrostatic test. On the analysis of high speed camera about ignition appearances and burning time, the burning speed was faster when aluminum particle size was smaller.

Rheological Properties of Rehydrated Freeze Dried Instant Rice (동결건조 즉석미반의 리올로지적 성질)

  • Kim, Kwan-Yu;Lee, Shin-Young;Joo, Hyun-Kyu
    • Applied Biological Chemistry
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    • v.32 no.4
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    • pp.332-337
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    • 1989
  • Rheological properties of rehydrated freeze dried instant rice were investigated in comparison with that of cooked rice. The time changes in reciprocal hardness of instant rice grains at various rehydration temperatures$(60{\sim}90^{\circ}C)$ could be expressed by the first order reaction rate equation regardless of rehydration temperature and reaction rate constant increased as the rehydration temperature increased. Activation energy for rehydrating instant rice was 6.1 kcal/g-mol. Analysis of compressive stress relaxation test showed that the viscoelastic properties of both rehydrated instant rice and cooked rice grains could be expressed by 6-elements generalized Maxwell model. Rehydrated instant rice revealed higher relaxation decay than that of cooked rice and showed the elastic property increased by increasing the rehydration temperature.

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A Study on the Characteristics of Amorphous TiAl by P/M Processing

  • Han, Chang-Suk;Jeon, Seung-Jin
    • Journal of the Korean Society for Heat Treatment
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    • v.29 no.2
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    • pp.51-55
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    • 2016
  • The P/M processing of titanium aluminide using amorphous TiAl is developed by which it is possible to overcome inherent fabricability problems and to obtain a fine microstructure. A high quality amorphous TiAl powder produced by reaction ball milling shows clear glass transition far below a temperature at the onset of crystallization in differential scanning calorimetry above a heating rate of 0.05 K/s. We obtained a fully dense compact of amorphous TiAl powders, encapsulated in a vacuumed can, via viscous flow by hot isostatic pressing (HIP). Isothermally annealing of HIP'ed amorphous compact under a pressure of 196 MPa shows a progressive growth of ${\gamma}-TiAl$ phase with ${\alpha}2$ ($Ti_3Al$), which is characterized by increasing sharpness of X-ray peaks with temperature. Fully dense HIP'ed compact of titanium aluminide TiAl shows a high hardness of 505 Hv, suggesting strengthening mechanisms by sub-micron sized grain of ${\gamma}-TiAl$ and particle-dispersion by second phase constituent, ${\alpha}2$.

Thermal Analysis of Nickel-Base Superalloys by Differential Scanning Calorimetry (시차주사열량측정법에 의한 니켈기 초내열 합금의 열분석)

  • Yun, Jihyeon;Oh, Junhyeob;Kim, Hongkyu;Yun, Jondo
    • Korean Journal of Materials Research
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    • v.26 no.5
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    • pp.235-240
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    • 2016
  • Appropriate thermo-mechanical properties of nickel-based superalloys are achieved by heat treatment, which induces precipitation and solid solution hardening; thus, information on the temperature ranges of precipitation and dissolution of the precipitates is essential for the determination of the heat treatment condition. In this study, thermal analyses of nickel-based superalloys were performed by differential scanning calorimetry method under conditions of various heating rates of 5, 10, 20, or 40K/min in a temperature range of 298~1573K. Precipitation and dissolution temperatures were determined by measuring peak temperatures, constructing trend lines, and extrapolating those lines to the zero heating rate to find the exact temperature under isothermal condition. Determined temperatures for the precipitation reactions were 813, 952, and 1062K. Determined onset, peak, and offset temperatures of the first dissolution reaction were 1302, 1388, and 1406K, respectively, and those values of the second dissolution reaction were 1405, 1414, and 1462K. Determined solvus temperature was 1462K. The study showed that it was possible to use a simple method to obtain accurate phase transition temperatures under isothermal condition.

Computational Analysis for Improving Internal Flow of High Pressure Methanol Steam Reformer Pressure Vessel (고압형 메탄올 수증기 개질기 압력용기의 내부 유동 개선을 위한 전산 해석)

  • YU, DONGJIN;JI, HYUNJIN;YU, SANGSEOK
    • Journal of Hydrogen and New Energy
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    • v.31 no.5
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    • pp.411-418
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    • 2020
  • A reformer is a device for producing hydrogen used in fuel cells. Among them, methanol steam reformer uses methanol as fuel, which is present as a liquid at room temperature. It has the advantage of low operating temperature, high energy density, and high hydrogen production. The purpose of this study is to improve the internal flow of the pressure vessel when a bundle of methanol steam reformer in the pressure vessel goes out to a single outlet. An analysis of equilibrium reaction to methanol steam reforming reaction was conducted using Aspen HYSYS® (Aspen Technology Inc., Bedford, USA), and based on the results, computational analysis was conducted using ANSYS Fluent® (ANSYS, Inc., Canonsburg, USA). For comparison of the results, the height of the pressure vessel, outlet diameter, and fillet was set as variables, and the optimum geometry was selected by comparing the effects of gravity and the amount of negative pressure.

Reaction of ferritin with hydrogen peroxide induces lipid peroxidation

  • Yoon, Hung-Hwan;Lee, Myeong-Seon;Kang, Jung-Hoon
    • BMB Reports
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    • v.43 no.3
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    • pp.219-224
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    • 2010
  • Lipid peroxidation is known to be an important factor in the pathologies of many diseases associated with oxidative stress. We assessed the lipid peroxidation induced by the reaction of ferritin with $H_2O_2$. When linoleic acid micelles or phosphatidyl choline liposomes were incubated with ferritin and $H_2O_2$, lipid peroxidation increased in the presence of ferritin and $H_2O_2$ in a concentration-dependent manner. The hydroxyl radical scavengers, azide and thiourea, prevented lipid peroxidation induced by the ferritin/$H_2O_2$ system. The iron specific chelator desferoxamine also prevented ferritin/$H_2O_2$ systemmediated lipid peroxidation. These results demonstrate the possible role of iron in ferritin/$H_2O_2$ system-mediated lipid peroxidation. Carnosine is involved in many cellular defense processes, including free radical detoxification. In this study, carnosine, homocarnosine, and anserine were shown to significantly prevent ferritin/$H_2O_2$ system-mediated lipid peroxidation and also inhibited the free radical-generation activity of ferritin. These results indicated that carnosine and related compounds may prevent ferritin/$H_2O_2$ system-mediated lipid peroxidation via free radical scavenging.

A Study of Aircraft Ground Motion (항공기 지상운동 특성에 관한 연구)

  • Song, Won Jong
    • Journal of Aerospace System Engineering
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    • v.11 no.6
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    • pp.17-25
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    • 2017
  • Vertical reaction force between ground and tire is an important parameter determining the ground behavior characteristics of aircraft. This parameter can be used to calculate the lateral force and friction. However, it is hard to obtain this parameter in real-time when the aircraft is taxiing. Therefore, pre-analysis of ground behavior and vertical reaction force should be conducted using ground simulation results to prevent rollover or hazardous scenarios. In this paper, a Landing Gear and Full-Aircraft model was constructed using VI-Aircraft S/W. The roll behavior of aircraft was analyzed using steering simulation results compared with taxi-test data.

Study on the Thermal Degradation Behavior of FKM O-rings

  • Lee, Jin Hyok;Bae, Jong Woo;Choi, Myoung Chan;Yoon, Yoo-Mi;Park, Sung Han;Jo, Nam-Ju
    • Elastomers and Composites
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    • v.53 no.4
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    • pp.213-219
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    • 2018
  • The degradation mechanism and physical properties of an FKM O-ring were observed with thermal aging in this experiment. From X-ray photoelectron spectroscopy (XPS) analysis, we could observe carbon (285 eV), fluoro (688 eV), and oxygen (531 eV) peaks. Before thermal aging, the concentration of fluoro atoms was 51.23%, which decreased to 8.29% after thermal aging. The concentration of oxygen atoms increased from 3.16% to 20.39%. Under thermal aging, the FKM O-ring exhibited debonding of the fluoro-bond by oxidation. Analysis of the C1s, O1s, and F1s peaks revealed that the degradation reaction usually occurred at the C-F, C-F2, and C-F3 bonds, and generated a carboxyl group (-COOH) by oxidation. Due to the debonding reaction and decreasing mobility, the glass transition temperature of the FKM O-ring increased from $-15.91^{\circ}C$ to $-13.79^{\circ}C$. From the intermittent CSR test, the initial sealing force was 2,149.6 N, which decreased to 1,156.2 N after thermal aging. Thus, under thermal aging, the sealing force decreased to 46.2%, compared with its initial state. This phenomenon was caused by the debonding reaction and decreasing mobility of the FKM O-ring. The S-S curve exhibited a 50% increase in modulus, with break at a low strain and stress state. This was also attributed to the decreasing mobility due to thermal aging degradation.

Attitude Control for Agile Spacecraft Installed with Reaction Wheels (리액션휠 기반 고기동 위성 자세제어 기법 연구)

  • Kim, Taeho;Mok, Sung-Hoon;Bang, Hyochoong;Song, Taeseong;Lee, Jongkuck;Song, Deokki;Seo, Joongbo
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.46 no.11
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    • pp.934-943
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    • 2018
  • In these days, demand for agile spacecraft is gradually increasing, due to the fact that agile spacecraft can improve mission capability. In this paper, an attitude control logic based on reaction wheels that can enhance agility of spacecraft is proposed. Three methods are suggested, and all three or part of them can be integrated to the existing attitude control system. First, a feedforward/feedback controller is introduced, and its pros and cons are provided, compared to the conventional feedback controller. Second, an attitude command generation method that fully utilizes torque/momentum capacities of reaction wheels is proposed. Third, a torque (current) control mode for internal wheel control is introduced. Numerical results verify that the settling time can be significantly reduced by employing the feedforward/feedback control method, especially for large angle maneuver.

Effects of Pyrite (FeS2) Particle Sizes on Electrochemical Characteristics of Thermal Batteries (열전지의 전기화학적 특성에 미치는 황철석(FeS2) 입자크기의 영향)

  • Choi, Yusong;Yu, Hye-Ryeon;Cheong, Haewon;Cho, Sungbaek;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.25 no.2
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    • pp.161-166
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    • 2014
  • In this study, effects of pyrite ($FeS_2$) particle sizes on the electrochemical characteristics of thermal batteries are investigated using unit cells made of pulverized pyrite by ball-milling. At $450^{\circ}C$ unit cell discharge test, the electrochemical capacity of $1.46{\mu}m$ pyrite-cell largely increases compared to $98.4{\mu}m$ pyrite-cell, and their internal resistances also decrease. These results are attributed to the increase in the active reaction area of pyrite by ball milling. However, at $500^{\circ}C$ unit cell discharge test, a $1.46{\mu}m$ pyrite cell shows lower internal resistance than that of $98.4{\mu}m$ pyrite cell only at Z-phase region ($FeS_2{\rightarrow}Li_3Fe_2S_4$). After that, a $1.46{\mu}m$ pyrite cell shows a decrease in the cell voltage and an rapid increase of the internal resistance in J-phase region ($Li_3Fe_2S_4{\rightarrow}LiFe_2S_4$) is observed compared to those of $98.4{\mu}m$ pyrite cell. It can be concluded that at the higher temperature, the thermally unstable pulverized pyrite is decomposed thermally as well as self discharged, simultaneously, which causes the higher resistance and lower capacity at $500^{\circ}C$ in J-phase than that of $98.4{\mu}m$ pyrite cell.