• Title/Summary/Keyword: Decomposition prevention

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A Kinetic Study of Thermal-Oxidative Decomposition of Waste Polyurethane (폐폴리우레탄의 열적 산화분해에 대한 속도론적 연구)

  • Jun, Hyun Chul;Oh, Sea Cheon;Lee, Hae Pyeong;Kim, Hee Taik
    • Applied Chemistry for Engineering
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    • v.17 no.3
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    • pp.296-302
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    • 2006
  • The kinetics of the thermal-oxidative decomposition of waste polyurethane (PU) according to oxygen concentration has been studied using a non-isothermal thermogravimetric technique at several heating rates from 10 to $50^{\circ}C/min$. A kinetic model accounting for the effects of the oxygen concentration by the differential and integral method based on Arrhenius equation was proposed to describe the thermal-oxidative decomposition of waste PU. To obtain the information on the kinetic parameters such as activation energy, reaction order, and pre-exponential factor, the thermogravimetric analysis curves and its derivatives have been analyzed using the kinetic analysis method proposed in this work. From this work, it was found that reaction orders for oxygen concentration had a negative sign, and activation energy decreased as the oxygen concentration increased. It was also found that the kinetic parameters obtained from the integral method using the single heating rate experiments varied with heating rates. Therefore, it is thought that the differential method using the multiple heating rate experiments more effectively represents the thermal-oxidative decomposition of waste polyurethane.

Microscopic Study of Decomposition-Inhibition Effect in Grapefruit-seed Extract in Rat Kidney (자몽추출물의 콩팥조직 부패억제 효과에 관한 현미경적 연구)

  • Hwang, Kyu-Sung; Choi, Ki-Ju;Nam, Yong-Seok;Lim, Do-Seon
    • Applied Microscopy
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    • v.39 no.4
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    • pp.325-332
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    • 2009
  • It has been well known that grapefruit seed extract (GSE) have effects on the deodorization and a wide range disinfectant. But anybody do not research about the decomposition-inhibition effect of GSE. The present study was performed to investigate the decomposition-inhibition effect of GSE by measuring the microscope and electroscope observation with passage of time. A total of 30 healthy Sprague-Dawley (SD) rats weighting from 230 gm to 250 gm were used as experimental animals. One group that do not treated by GSE named control group and the other group that treated by 55% GSE named Experimental group. Under ether anesthesia, right kidney was obtained. Put each sample in $37^{\circ}C$ and humidity $80{\pm}5%$ incubator, we obtained each sample after 0 day, 1 day, 2 days, 3 days, 4 days and 5 days. 4 ${\mu}m$ of paraffin sections were obtained, stained H-E stain and observed by use of a microscope. Morphological change in tissue was similar to control 1 day group and experimental 3 days group. Therefore, decomposition-inhibition effect of GSE continued about 2 days and it protected necrosis. According to above results, the author suggest that 55% GSE is an effective decomposition inhibitor until 2 days on $37^{\circ}C$ and humidity $80{\pm}5%$ conditions.

Histogram-Based Singular Value Decomposition for Object Identification and Tracking (객체 식별 및 추적을 위한 히스토그램 기반 특이값 분해)

  • Ye-yeon Kang;Jeong-Min Park;HoonJoon Kouh;Kyungyong Chung
    • Journal of Internet Computing and Services
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    • v.24 no.5
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    • pp.29-35
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    • 2023
  • CCTV is used for various purposes such as crime prevention, public safety reinforcement, and traffic management. However, as the range and resolution of the camera improve, there is a risk of exposing personal information in the video. Therefore, there is a need for new technologies that can identify individuals while protecting personal information in images. In this paper, we propose histogram-based singular value decomposition for object identification and tracking. The proposed method distinguishes different objects present in the image using color information of the object. For object recognition, YOLO and DeepSORT are used to detect and extract people present in the image. Color values are extracted with a black-and-white histogram using location information of the detected person. Singular value decomposition is used to extract and use only meaningful information among the extracted color values. When using singular value decomposition, the accuracy of object color extraction is increased by using the average of the upper singular value in the result. Color information extracted using singular value decomposition is compared with colors present in other images, and the same person present in different images is detected. Euclidean distance is used for color information comparison, and Top-N is used for accuracy evaluation. As a result of the evaluation, when detecting the same person using a black-and-white histogram and singular value decomposition, it recorded a maximum of 100% to a minimum of 74%.

A Study on the Decomposition Characteristics of PVC and PS Mixtures with ZnO in Air Atmosphere (공기분위기에서 ZnO를 첨가한 PVC와 PS 혼합물의 분해특성에 관한 연구)

  • Oh, Sea Cheon;Jung, Myung Uk;Jun, Hyun-Chul;Kim, Hee Taik;Lee, Hae Pyeong
    • Applied Chemistry for Engineering
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    • v.17 no.2
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    • pp.229-234
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    • 2006
  • The effect of ZnO in the decomposition of poly(vinyl chloride) (PVC) and polystyrene (PS) mixtures in air atmosphere has been studied by thermogravimetry (TG) and gas chromatograph-mass spectrometry (GC-MS) under various mixing ratios and reaction temperatures. From this work, it can be seen that the yields of a liquid product were increased with the increase of PS in mixtures, whereas those of gaseous products were decreased. And the yields of a gaseous product and HCl were decreased with the increase of ZnO in mixtures. It was also found that HCl was rarely produced at ZnO/Mixture = 0.5 by the effect of ZnO in dehydrochlorination of PVC.

Mixed Structure Effect of Fuel and Air on Rotary Kiln Burner Flame (연료 및 공기의 혼합구조가 로타리 킬른 용 버너 화염에 미치는 영향)

  • Kim, Youngho;Lee, Cheolwoo;Kim, Insu;Lim, Youngbin
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.339-342
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    • 2014
  • Rotary kiln produces lime from limestone through thermal decomposition. Ring formation in kiln internal wall is known issue that decreases productivity. The cause of ring formation is temperature imbalance as flame leans toward upper wall. Therefore, burner nozzle geometry was changed to improve air-fuel mixing state which leads to prevention of ring formation. CFD simulation and experimental test were performed in this study to investigate the effect of air-fuel mixing on flame structure, temperature and $NO_X$ concentration. It is shown that combustion efficiency has been enhanced and $NO_X$ concentration has been decreased by using swirl flow for secondary combustion air. It's also shown that flame has been straightened by using straight flow for secondary combustion air.

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Developing decomposition of heavy metals in mining ground waste water (광산폐수의 중금속처리기술의 개발)

  • 이영신;오대민
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.12 no.2
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    • pp.96-100
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    • 2002
  • This study is aimed at prevention and countermeasurements of the mine wastewater pollution caused by a mineralized area using heavy metals. Objective of this study is selected to a high positive ion methathesis capacity of the environmental integrity character materials, as well as applied to the mine wastewater treatments. Also, the environmental integrity character materials is selected Kaolin. Silica, Zeolite, Fly ash. Thus, this environmental integrity character matters will be proved in the reduced heavy metals level and fine water quality of effluent.

High-speed Trains Driving Functions Analysis Using Systems Engineering

  • Noh, Hee-Min
    • International Journal of Railway
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    • v.3 no.3
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    • pp.90-94
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    • 2010
  • In this paper, driving functions of the Korea High-speed Trains were decomposed based on systems engineering architecture. In order to analyze the driving function, various systems engineering tools and methods were used. Moreover, interfaces of decomposed driving functions were analyzed to figure out purposes of the driving functions. Through activity modeling of driving function of the Korea High-Speed Trains, main functions were derived when starting, speeding and stopping. When the high speed train is speeding, pre-departure checks and wheel slide prevention are essential driving activities for the safety and when the high speed train runs high speed, maintaining driving stability by monitoring bogie hunting and monitoring drivers' safe operation by vigilance systems is important. Furthermore, when the train is braking, the driver should checks brake and suspensions as safety actions.

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River Stage Forecasting Model Combining Wavelet Packet Transform and Artificial Neural Network (웨이블릿 패킷변환과 신경망을 결합한 하천수위 예측모델)

  • Seo, Youngmin
    • Journal of Environmental Science International
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    • v.24 no.8
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    • pp.1023-1036
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    • 2015
  • A reliable streamflow forecasting is essential for flood disaster prevention, reservoir operation, water supply and water resources management. This study proposes a hybrid model for river stage forecasting and investigates its accuracy. The proposed model is the wavelet packet-based artificial neural network(WPANN). Wavelet packet transform(WPT) module in WPANN model is employed to decompose an input time series into approximation and detail components. The decomposed time series are then used as inputs of artificial neural network(ANN) module in WPANN model. Based on model performance indexes, WPANN models are found to produce better efficiency than ANN model. WPANN-sym10 model yields the best performance among all other models. It is found that WPT improves the accuracy of ANN model. The results obtained from this study indicate that the conjunction of WPT and ANN can improve the efficiency of ANN model and can be a potential tool for forecasting river stage more accurately.

LSTM-based Early Fire Detection System using Small Amount Data

  • Seonhwa Kim;Kwangjae Lee
    • Journal of the Semiconductor & Display Technology
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    • v.23 no.1
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    • pp.110-116
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    • 2024
  • Despite the continuous advancement of science and technology, fire accidents continue to occur without decreasing over time, so there is a constant need for a system that can accurately detect fires at an early stage. However, because most existing fire detection systems detect fire in the early stage of combustion when smoke is generated, rapid fire prevention actions may be delayed. Therefore we propose an early fire detection system that can perform early fire detection at a reasonable cost using LSTM, a deep learning model based on multi-gas sensors with high selectivity in the early stage of decomposition rather than the smoke generation stage. This system combines multiple gas sensors to achieve faster detection speeds than traditional sensors. In addition, through window sliding techniques and model light-weighting, the false alarm rate is low while maintaining the same high accuracy as existing deep learning. This shows that the proposed fire early detection system is a meaningful research in the disaster and engineering fields.

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Cultivation of Nostoc flagelliforme on Solid Medium

  • Su Jianyu;Jia Shiru;Qiao Changsheng;Kim Jung-Gyu;Hong Wan-Hae;Cho Ki-An;Choi DuBok
    • Korean Journal of Environmental Biology
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    • v.23 no.2 s.58
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    • pp.135-140
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    • 2005
  • In order to construct an artificial cultivation of Nostoc flagelliforme on solid medium, we attempted to assess the viability of approaches, which utilized either BG-11 agar or sand medium using both sterile and non-sterile algal segments. In the trial in which the BG -11 agar medium was inoculated with the non-sterile algal segments, the algae exhibited the rapid growth in the initial 4 days of cultivation. However, after 4 days of cultivation, the growth rate of the algae slowed, and the algal growth was completely stopped by 7 days of cultivation. When the BG -11 medium was inoculated with the sterile algal segments, the algae exhibited the rapid growth for a longer period of 8 days, reaching a length of 24.9 mm. The growth rate during this period was measured to be $24.5\%$. After the 8 days of cultivation, the algal growth rate began to slow and had almost stopped by the 13 days of cultivation. On the other hand, when the sterile algal segments were inoculated onto a sand plate, the algal segments decomposed, reaching total decomposition after 11 days of cultivation. By way of contrast, the desiccation treatment samples continued to grow for 14 days of cultivation. After 14 days of cultivation, the algae achieved a length of 26.1 mm, with a growth rate of $30.6\%$. Our results indicate that periodic desiccation may constitute an effective strategy for the prevention of algal decomposition.