• 제목/요약/키워드: Decomposition prevention

검색결과 51건 처리시간 0.032초

무기성 순환자원의 수소 활성화 및 이산화탄소 분해 (Hydrogen Activation and Carbon Dioxide Decomposition Using An Inorganic Recycling Resource)

  • 박영구;고재철;전제열;박준석
    • 한국응용과학기술학회지
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    • 제26권4호
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    • pp.483-490
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    • 2009
  • This research was conducted to estimate the characteristics of carbon dioxide decomposition using an inorganic sludge. The inorganic sludge was composed of high amount (66.8%) of $Fe_2O_3$. Hydrogen could be reduced with 0.247, 0.433, 0.644, and 0.749 at 350, 400, 450, and $500^{\circ}C$, respectively. The carbon dioxide decomposition rates at 250, 300, 350, 400, 450, and $500^{\circ}C$ were 32, 52, 35, 62, 75, and 84%, respectively. High temperature led to high reduction of hydrogen and better decomposition of carbon dioxide. The specific surface area of the sludge after hydrogen reduction was higher than that after carbon dioxide decomposition. The specific surface area of the sludge was more decreased with increasing of temperature.

Decomposition Characteristics of Benzene by Microwave

  • Kim, Dong-Sik;Kim, Jeong-Young;Lee, Dong-Kyu
    • Carbon letters
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    • 제1권3_4호
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    • pp.143-147
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    • 2001
  • Under the irradiation of radiofrequency wave, the dipole materials vibrate as microwave phase changes. This causes friction between adjacent molecules and enables an unique characteristics of interior heating of the materials. Using this principle, when harmful material pass through anthracite- bed which play a role as a absorber of radiofrequency wave, the material can be easily decomposed by the microwave energy. To remove benzene vapour and other solvents in the process of industry, we examined decomposition of benzene in this manner. It was found that benzene was decomposed to the methane, ethane, propane and butane, etc. during passing through the carbon-bed under the microwave impingement and distribution of methane in the products reached about 85 vol.%. The decomposition rate of benzene was high within 5 minutes from start of reaction. For a lower concentration of benzene gas, general cases in the field of industry, almost complete decomposition of benzene is believed possible and this method is surely expected to be useful for the prevention of air pollution and improvement of ambient condition.

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Estimating global solar radiation using wavelet and data driven techniques

  • Kim, Sungwon;Seo, Youngmin
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 2015년도 학술발표회
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    • pp.475-478
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    • 2015
  • The objective of this study is to apply a hybrid model for estimating solar radiation and investigate their accuracy. A hybrid model is wavelet-based support vector machines (WSVMs). Wavelet decomposition is employed to decompose the solar radiation time series into approximation and detail components. These decomposed time series are then used as inputs of support vector machines (SVMs) modules in the WSVMs model. Results obtained indicate that WSVMs can successfully be used for the estimation of daily global solar radiation at Champaign and Springfield stations in Illinois.

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CaO를 첨가한 폐PVC전선의 열적분해 특성에 관한 연구 (A Study on the Thermal Decomposition Characteristics of Waste PVC Wire Added with CaO)

  • ;박호;권우택;이해평;오세천
    • 한국응용과학기술학회지
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    • 제29권2호
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    • pp.268-277
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    • 2012
  • 폐 PVC전선의 열적분해 특성에 관한 연구를 TGA 및 고정층 반응기를 이용하여 연구하였다. 본 연구에서는 분해온도, 공기유량 및 CaO/ PVC의 비를 실험조건으로 고려하였으며, PVC전선의 열적분해과정에서 발생되는 염화수소 및 독성가스의 제거를 위한 CaO의 첨가에 대한 효과를 검증하기 위하여 PVC 전선의 열적분해 과정에서 생성되는 기상 생성물을 GC/MS를 이용하여 분석하였다. 또한 CaO의 첨가효과를 고찰하고자 액성 생성물에 대한 GC/MS을 함께 수행하였으며, 분해온도, 공기유량 및 CaO/PVC의 비에 따른 액상, 기상 및 고상 잔류물의 수율 변화를 함께 고찰하였다. 본 연구로부터 CaO의 첨가량이 증가할수록 PVC의 열적분해 과정에서 발생되는 염화수소의 제거량이 증가함을 확인하였다.

철도차량용 폐 복합소재에서의 탄소섬유 회수 (The Recovery of Carbon Fiber from Carbon Fiber Reinforced Epoxy Composites for Train Body)

  • 이석호;이철규;김용기;김정석;주창식
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2008년도 추계학술대회 논문집
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    • pp.406-415
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    • 2008
  • Recently, the amount of thermosetting plastic wastes have increased with the production of reinforced plastic composites and causes serious environmental problems. The epoxy composites, one of the versatile thermosetting plastics with excellent properties, cannot be melted down and remolded as what is done in the thermoplastic industry. In this research, a series of experiments that recovers carbon fibers from carbon fiber reinforced epoxy composites for train body was performed. We experimentally examined various decomposition processes and compared their decomposition efficiencies and mechanical property of recovered carbon fibers. For the prevention of tangle of recovered carbon fibers, each composites specimen was fixed with a Teflon supporter and no mechanical mixing was applied. Decomposition products were analyzed by scanning electron microscope (SEM), gas chromatography mass spectrometer (GC-MS), and universal testing machine (UTM). Carbon fibers could be completely recovered from decomposition process using nitric acid aqueous solution, liquid-phase thermal cracking and pyrolysis. The tensile strength losses of the recovered carbon fibers were less than 4%.

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FERRATE(VI) FOR WASTE WATER TREATMENT : OXIDATION OF CYANIDE IN AQUEOUS MEDIUM

  • Tiwari, Diwakar;Kim, Hyoung-Uk;Lee, Seung-Mok;Yang, Jae-Kyu;Kim, Hyun-Ook
    • Environmental Engineering Research
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    • 제11권6호
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    • pp.318-324
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    • 2006
  • The higher valence state of iron i.e., Fe(VI) was employed for the oxidation of one of an important toxic ion, cyanide in the aqueous medium. Cyanide was oxidized into cyanate, which is 1,000 times less toxic to cyanide and often accepted for its ultimate disposal. It was to be noted that Fe(VI) is a very powerful oxidizing agent and can oxidize most of the cyanide within few minutes i.e., ca 5 mins of contact. The data was obtained by the UV-Visible measurements for the Fe(VI) decomposition. The UV-Visible data was used to evaluate the overall rate constant for second order redox reaction between ferrate(VI) and cyanide. Also the pseudo first order rate constant was calculated as keeping the cyanide concentration in excess.

철도차량용 폐 복합소재로부터 탄소섬유 회수 (The Recovery of Carbon Fiber from Carbon Fiber Reinforced Epoxy Composites Applied to Railway Vehicles)

  • 이석호;김정석;이철규;김용기;주창식
    • 한국철도학회논문집
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    • 제12권6호
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    • pp.1059-1066
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    • 2009
  • 근래에 와서 강화 플라스틱 복합재료의 생산과 함께 열경화성 수지 폐기물들의 양이 급격하게 증가하여 심각한 환경문제를 야기하고 있다. 우수한 기계적 물성을 지닌 유용한 열경화성 수지의 하나인 에폭시 수지는 열가소성 수지처럼 용융되거나 재 성형되지 않는다. 본 연구에서는 철도 차량용 탄소섬유 강화 에폭시 수지 복합재로부터 에폭시 수지를 분해하여 탄소섬유를 회수하는 일련의 실험을 수행하였다. 여러 분해공정들을 실험적으로 조사하여, 분해 효율과 회수되는 탄소섬유의 기계적 물성을 비교 검토하였다. 회수되는 탄소섬유가 서로 엉키는 것을 방지하기 위해서 각 복합재료 시편은 테플론 지지대로 고정시키고, 기계적인 교반을 가하지 않았다. 분해 생성물은 전자현미경(SEM), 기체 크로마토그라피 질량분석기(GC-MS) 및 만능재료시험기를 사용하여 분석하였다. 질산 수용액을 사용하는 분해 공정과 액상 및 기상 열분해 공정에서는 탄소섬유가 완전하게 회수되었다. 회수된 탄소섬유의 인장강도 감소율은 4% 미만으로 미미하였다.

지구자의 Glutathione S-transferase 활성과 알코올 분해효과 (Activity of Glutathione S-transferase and Effect of Alcohol Decomposition on the Fruit of Hovenia dulcis Thunb)

  • 차배천;이은희;이은;박행호
    • 약학회지
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    • 제48권3호
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    • pp.213-217
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    • 2004
  • For the determination of glutathione S-transferase activity, a new method was established by using HPLC system. Moreover, amount of enzyme for a optimum reaction was determined by a comparative study with a variety concentration of enzyme. Using a established method, activity of glutathione S-transferase that is alcohol metabolizing enzyme was investigated on the fruit of Hovenia dulcis Thunb. As the result of experiment, EtOH and $H_2O$ extracts of the fruit of Hovenia dulcis Thunb showed visible a synergistic effect of glutathione S-transferase activity. On a continuous experiment, EtOH and $H_2O$ extracts of the fruit of Hovenia dulcis Thunb showed alcohol decomposition activity on the in vivo test using rat. These results suggest that the fruit of Hovenia dulcis Thunb may be useful in the prevention of hangover.

원료의약품 분진의 폭발 위험성 평가 (Hazard Assesment of Dust Explosion Pharmaceutical Raw Material Powders)

  • 김원성;이근원;우인성;전상용
    • 한국안전학회지
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    • 제33권2호
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    • pp.39-44
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    • 2018
  • Dust explosions are occurring in a variety of industries. A dust explosion caused by a specific energy generates huge amount of energy in the ignition and releases decomposition gas. Damages can be increased since this released decomposition gas can cause second and subsequent explosions. In this study, the goal was to obtain practical information on what could affect the explosion by comparing the characteristics of two kinds of dusts with completely different chemical properties. Three kinds of dusts were measured and evaluated for explosion pressure, dust explosion index, explosion limit and minimum ignition energy. It is possible to grasp the characteristics of each dust and use it as useful accident prevention data in the production of raw material powder.

Network intrusion detection method based on matrix factorization of their time and frequency representations

  • Chountasis, Spiros;Pappas, Dimitrios;Sklavounos, Dimitris
    • ETRI Journal
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    • 제43권1호
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    • pp.152-162
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    • 2021
  • In the last few years, detection has become a powerful methodology for network protection and security. This paper presents a new detection scheme for data recorded over a computer network. This approach is applicable to the broad scientific field of information security, including intrusion detection and prevention. The proposed method employs bidimensional (time-frequency) data representations of the forms of the short-time Fourier transform, as well as the Wigner distribution. Moreover, the method applies matrix factorization using singular value decomposition and principal component analysis of the two-dimensional data representation matrices to detect intrusions. The current scheme was evaluated using numerous tests on network activities, which were recorded and presented in the KDD-NSL and UNSW-NB15 datasets. The efficiency and robustness of the technique have been experimentally proved.