• Title/Summary/Keyword: Decomposition prevention

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Hydrogen Activation and Carbon Dioxide Decomposition Using An Inorganic Recycling Resource (무기성 순환자원의 수소 활성화 및 이산화탄소 분해)

  • Park, Young-Koo;Ko, Jae-Churl;Jeon, Jae-Youl;Park, Joon-Seok
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.4
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    • pp.483-490
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    • 2009
  • This research was conducted to estimate the characteristics of carbon dioxide decomposition using an inorganic sludge. The inorganic sludge was composed of high amount (66.8%) of $Fe_2O_3$. Hydrogen could be reduced with 0.247, 0.433, 0.644, and 0.749 at 350, 400, 450, and $500^{\circ}C$, respectively. The carbon dioxide decomposition rates at 250, 300, 350, 400, 450, and $500^{\circ}C$ were 32, 52, 35, 62, 75, and 84%, respectively. High temperature led to high reduction of hydrogen and better decomposition of carbon dioxide. The specific surface area of the sludge after hydrogen reduction was higher than that after carbon dioxide decomposition. The specific surface area of the sludge was more decreased with increasing of temperature.

Decomposition Characteristics of Benzene by Microwave

  • Kim, Dong-Sik;Kim, Jeong-Young;Lee, Dong-Kyu
    • Carbon letters
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    • v.1 no.3_4
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    • pp.143-147
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    • 2001
  • Under the irradiation of radiofrequency wave, the dipole materials vibrate as microwave phase changes. This causes friction between adjacent molecules and enables an unique characteristics of interior heating of the materials. Using this principle, when harmful material pass through anthracite- bed which play a role as a absorber of radiofrequency wave, the material can be easily decomposed by the microwave energy. To remove benzene vapour and other solvents in the process of industry, we examined decomposition of benzene in this manner. It was found that benzene was decomposed to the methane, ethane, propane and butane, etc. during passing through the carbon-bed under the microwave impingement and distribution of methane in the products reached about 85 vol.%. The decomposition rate of benzene was high within 5 minutes from start of reaction. For a lower concentration of benzene gas, general cases in the field of industry, almost complete decomposition of benzene is believed possible and this method is surely expected to be useful for the prevention of air pollution and improvement of ambient condition.

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Estimating global solar radiation using wavelet and data driven techniques

  • Kim, Sungwon;Seo, Youngmin
    • Proceedings of the Korea Water Resources Association Conference
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    • 2015.05a
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    • pp.475-478
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    • 2015
  • The objective of this study is to apply a hybrid model for estimating solar radiation and investigate their accuracy. A hybrid model is wavelet-based support vector machines (WSVMs). Wavelet decomposition is employed to decompose the solar radiation time series into approximation and detail components. These decomposed time series are then used as inputs of support vector machines (SVMs) modules in the WSVMs model. Results obtained indicate that WSVMs can successfully be used for the estimation of daily global solar radiation at Champaign and Springfield stations in Illinois.

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A Study on the Thermal Decomposition Characteristics of Waste PVC Wire Added with CaO (CaO를 첨가한 폐PVC전선의 열적분해 특성에 관한 연구)

  • Shah, Malesh;Park, Ho;Kwon, Woo-Teck;Lee, Hae-Pyeong;Oh, Sea-Cheon
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.2
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    • pp.268-277
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    • 2012
  • The thermal decomposition characteristic of waste PVC wires has been studied by using TGA and fixed-bed reactor. The experimental conditions of decomposition temperatures, air flow rates and weight ratio of CaO/PVC were considered in this work. To verify the effectiveness of CaO addition to remove HCl and toxic gases generated from thermal decomposition of PVC wire, the gaseous products obtained from the thermal decomposition of PVC were analyzed by GC/MS(Gas Chromatograph and Mass Spectrometry). To investigate the effect of CaO in thermal decomposition of PVC, liquid products were also analyzed by GC/MS. And the effect of decomposition temperature, air flow rate and CaO/ PVC weight ratio on the yield of liquid, gas and residue fraction have been also studied. From this work, it was found that the removal amount of HCl generated from thermal decomposition of PVC increased with increase of CaO addition.

The Recovery of Carbon Fiber from Carbon Fiber Reinforced Epoxy Composites for Train Body (철도차량용 폐 복합소재에서의 탄소섬유 회수)

  • Lee, Suk-Ho;Lee, Cheul-Kyu;Kim, Yong-Ki;Kim, Jung-Seok;Ju, Chang-Sik
    • Proceedings of the KSR Conference
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    • 2008.11b
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    • pp.406-415
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    • 2008
  • Recently, the amount of thermosetting plastic wastes have increased with the production of reinforced plastic composites and causes serious environmental problems. The epoxy composites, one of the versatile thermosetting plastics with excellent properties, cannot be melted down and remolded as what is done in the thermoplastic industry. In this research, a series of experiments that recovers carbon fibers from carbon fiber reinforced epoxy composites for train body was performed. We experimentally examined various decomposition processes and compared their decomposition efficiencies and mechanical property of recovered carbon fibers. For the prevention of tangle of recovered carbon fibers, each composites specimen was fixed with a Teflon supporter and no mechanical mixing was applied. Decomposition products were analyzed by scanning electron microscope (SEM), gas chromatography mass spectrometer (GC-MS), and universal testing machine (UTM). Carbon fibers could be completely recovered from decomposition process using nitric acid aqueous solution, liquid-phase thermal cracking and pyrolysis. The tensile strength losses of the recovered carbon fibers were less than 4%.

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FERRATE(VI) FOR WASTE WATER TREATMENT : OXIDATION OF CYANIDE IN AQUEOUS MEDIUM

  • Tiwari, Diwakar;Kim, Hyoung-Uk;Lee, Seung-Mok;Yang, Jae-Kyu;Kim, Hyun-Ook
    • Environmental Engineering Research
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    • v.11 no.6
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    • pp.318-324
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    • 2006
  • The higher valence state of iron i.e., Fe(VI) was employed for the oxidation of one of an important toxic ion, cyanide in the aqueous medium. Cyanide was oxidized into cyanate, which is 1,000 times less toxic to cyanide and often accepted for its ultimate disposal. It was to be noted that Fe(VI) is a very powerful oxidizing agent and can oxidize most of the cyanide within few minutes i.e., ca 5 mins of contact. The data was obtained by the UV-Visible measurements for the Fe(VI) decomposition. The UV-Visible data was used to evaluate the overall rate constant for second order redox reaction between ferrate(VI) and cyanide. Also the pseudo first order rate constant was calculated as keeping the cyanide concentration in excess.

The Recovery of Carbon Fiber from Carbon Fiber Reinforced Epoxy Composites Applied to Railway Vehicles (철도차량용 폐 복합소재로부터 탄소섬유 회수)

  • Lee, Suk-Ho;Kim, Jung-Seok;Lee, Cheul-Kyu;Kim, Yong-Ki;Ju, Chang-Sik
    • Journal of the Korean Society for Railway
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    • v.12 no.6
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    • pp.1059-1066
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    • 2009
  • Recently, the amount of thermosetting plastic wastes has increased with the production of reinforced plastic composites and causes serious environmental problems. The epoxy resins, one of the versatile thermosetting plastics with excellent properties, cannot be melted down and remolded as what is done in the thermoplastic industry. In this research, a series of experiments that decompose epoxy resin and recover carbon fibers from carbon fiber reinforced epoxy composites applied to railway vehicles was performed. We experimentally examined various decomposition processes and compared their decomposition efficiencies and mechanical property of recovered carbon fibers. For the prevention of tangle of recovered carbon fibers, each composites specimen was fixed with a Teflon supporter and no mechanical mixing was applied. Decomposition products were analyzed by scanning electron microscope (SEM), gas chromatography mass spectrometer (GC-MS), and universal testing machine (UTM). Carbon fibers could be completely recovered from decomposition process using nitric acid aqueous solution, liquid-phase thermal cracking and pyrolysis. The tensile strength losses of the recovered carbon fibers were less than 4%.

Activity of Glutathione S-transferase and Effect of Alcohol Decomposition on the Fruit of Hovenia dulcis Thunb (지구자의 Glutathione S-transferase 활성과 알코올 분해효과)

  • Cha, Bae-Cheon;Lee, Eun-Hee;Lee, Eun;Park, Hang-Ho
    • YAKHAK HOEJI
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    • v.48 no.3
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    • pp.213-217
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    • 2004
  • For the determination of glutathione S-transferase activity, a new method was established by using HPLC system. Moreover, amount of enzyme for a optimum reaction was determined by a comparative study with a variety concentration of enzyme. Using a established method, activity of glutathione S-transferase that is alcohol metabolizing enzyme was investigated on the fruit of Hovenia dulcis Thunb. As the result of experiment, EtOH and $H_2O$ extracts of the fruit of Hovenia dulcis Thunb showed visible a synergistic effect of glutathione S-transferase activity. On a continuous experiment, EtOH and $H_2O$ extracts of the fruit of Hovenia dulcis Thunb showed alcohol decomposition activity on the in vivo test using rat. These results suggest that the fruit of Hovenia dulcis Thunb may be useful in the prevention of hangover.

Hazard Assesment of Dust Explosion Pharmaceutical Raw Material Powders (원료의약품 분진의 폭발 위험성 평가)

  • Kim, Won Sung;Lee, Keun Won;Woo, In Sung;Jeon, Sang Yong
    • Journal of the Korean Society of Safety
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    • v.33 no.2
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    • pp.39-44
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    • 2018
  • Dust explosions are occurring in a variety of industries. A dust explosion caused by a specific energy generates huge amount of energy in the ignition and releases decomposition gas. Damages can be increased since this released decomposition gas can cause second and subsequent explosions. In this study, the goal was to obtain practical information on what could affect the explosion by comparing the characteristics of two kinds of dusts with completely different chemical properties. Three kinds of dusts were measured and evaluated for explosion pressure, dust explosion index, explosion limit and minimum ignition energy. It is possible to grasp the characteristics of each dust and use it as useful accident prevention data in the production of raw material powder.

Network intrusion detection method based on matrix factorization of their time and frequency representations

  • Chountasis, Spiros;Pappas, Dimitrios;Sklavounos, Dimitris
    • ETRI Journal
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    • v.43 no.1
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    • pp.152-162
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    • 2021
  • In the last few years, detection has become a powerful methodology for network protection and security. This paper presents a new detection scheme for data recorded over a computer network. This approach is applicable to the broad scientific field of information security, including intrusion detection and prevention. The proposed method employs bidimensional (time-frequency) data representations of the forms of the short-time Fourier transform, as well as the Wigner distribution. Moreover, the method applies matrix factorization using singular value decomposition and principal component analysis of the two-dimensional data representation matrices to detect intrusions. The current scheme was evaluated using numerous tests on network activities, which were recorded and presented in the KDD-NSL and UNSW-NB15 datasets. The efficiency and robustness of the technique have been experimentally proved.