• Title/Summary/Keyword: Decomposition of Efficiency

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Decomposition of CFC-12($CCl_2F_2$) by Discharge Plasma (방전 플라스마에 의한 CFC-12($CCl_2F_2$)의 분해)

  • 강현춘;우인성;황명환;안형환;이한섭;조정국;강안수
    • Journal of the Korean Society of Safety
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    • v.14 no.3
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    • pp.93-100
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    • 1999
  • Decomposition efficiency, power consumption, and applied voltage of CFC(Chlorofluorocatbon) were investigated by SPCP(surface induced discharge plasma chemical processing) reactor to obtain optimum process variables and maximum decomposition efficiencies. Decomposition efficiency of CFC-12 with various electric frequencies(5~50kHz). flow rates (100~1,000mL/min), initial concentrations(100~1,000ppm), electrode materials(W, Cu, Al). electrode thickness(1, 2, 3mm) and reference gases($N_2$, $O_2$, air) were measured and the products were analyzed with FT-IR. Experimental results showed that at the frequency of 10kHz, the highest decomposition efficiency of 92.7% for CFC-12 were observed at the power consumptions of 29.6W. respectively, and that decomposition efficiency decreased with increasing frequency above 20kHz and decomposition efficiency per unit power were 3.13%/W for CFC-12. Decomposition efficiency was increased with increasing residence times and with decreasing initial concentration of pollutants. Decomposition efficiency was increased with increasing thickness of discharge electrode and the highest decomposition efficiency was obtained for the electrode diameter of 3m. As the electrode material, decomposition efficiency was in order that tungsten(W), copper(Cu), aluminum (Al). Decomposition of CFC-12 in the reference gas of $N_2$ showed the highest efficiency among three reference gases, and then the effect of reference gas on the decomposition efficiency decreased in order of air and $O_2$. The optimum power for the maximum decomposition efficiency was 25.3W for CFC.

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EFFICIENCY ANALYSIS OF A DOMAIN DECOMPOSITION METHOD FOR THE TWO-DIMENSIONAL TELEGRAPH EQUATIONS

  • Jun, Younbae
    • East Asian mathematical journal
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    • v.37 no.3
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    • pp.295-305
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    • 2021
  • In this paper, we analyze the efficiency of a domain decomposition method for the two-dimensional telegraph equations. We formulate the theoretical spectral radius of the iteration matrix generated by the domain decomposition method, because the rate of convergence of an iterative algorithm depends on the spectral radius of the iteration matrix. The theoretical spectral radius is confirmed by the experimental one using MATLAB. Speedup and operation ratio of the domain decomposition method are also compared as the two measurements of the efficiency of the method. Numerical results support the high efficiency of the domain decomposition method.

Effect of Electrode Process Variables in case of Decomposition of $NO_{x}$ by SPCP (연면방전에 의한 질소산화물의 분해시 전극 공정변수에 대한 영향)

  • 안형환;강현춘
    • Journal of the Korea Safety Management & Science
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    • v.1 no.1
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    • pp.241-258
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    • 1999
  • For hazardous air pollutants(HAP) such as NO and $NO_{2}$ decomposition efficiency, power consumption, and applied voltage were investigated by SPCP(surface induced discharge plasma chemical processing) reactor to obtain optimum process variables and maximum decomposition efficiencies. Decomposition efficiency of HAP with various electric frequencies(5~50 kHz), flow rates(100~1,000 mL/min), initial concentrations(100~1,000 ppm), electrode materials(W, Cu, Al), electrode thickness(1, 2, 3 mm) and number of electrode windings(7, 9, 11) were measured. Experimental results showed that for the frequency of 10 kHz, the highest decomposition efficiency of 94.3 % for NO and 84.7 % for $NO_{2}$ were observed at the power consumptions of 19.8 and 20W respectively and that decomposition efficiency decreased with increasing frequency above 20 kHz. Decomposition efficiency was increased with increasing residence times and with decreasing initial concentration of pollutants. Decomposition efficiency was increased with increasing thickness of discharge electrode and the highest decomposition efficiency was obtained for the electrode diameter of 3 mm in this experiment. As the electrode material, decomposition efficiency was in order : tungsten(W), copper(Cu), aluminum(Al).

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A study of decomposition of sulfur oxides(harmful gas) using calcium dihydroxide catalyst by plasma reactions (Ca(OH)2촉매를 이용한 플라즈마 반응에 의한 황산화물(유해가스)의 제거에 관한 연구)

  • Kim, Dayoung;Hwang, Myungwhan;Woo, Insung
    • Journal of the Korea Safety Management & Science
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    • v.16 no.2
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    • pp.237-246
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    • 2014
  • Researches on the elimination of sulfur and nitrogen oxides with catalysts and absorbents reported many problems related with elimination efficiency and complex devices. In this study, decomposition efficiency of harmful gases was investigated. It was found that the efficiency rate can be increased by moving the harmful gases together with SPCP reactor and the catalysis reactor. Calcium hydroxide($Ca(OH)_2$), CaO, and $TiO_2$ were used as catalysts. Harmful air polluting gases such as $SO_2$ were measured for the analysis of decomposition efficiency, power consumption, and voltage according to changes to the process variables including frequency, concentration, electrode material, thickness of electrode, number of electrode winding, and additives to obtain optimal process conditions and the highest decomposition efficiency. The standard sample was sulfur oxide($SO_2$). Harmful gases were eliminated by moving them through the plasma generated in the SPCP reactor and the $Ca(OH)_2$ catalysis reactor. The elimination rate and products were analyzed with the gas analyzer (Ecom-AC,Germany), FT-IR(Nicolet, Magna-IR560), and GC-(Shimazu). The results of the experiment conducted to decompose and eliminate the harmful gas $SO_2$ with the $Ca(OH)_2$ catalysis reactor and SPCP reactor show 96% decomposition efficiency at the frequency of 10 kHz. The conductivity of the standard gas increased at the frequencies higher than 20 kHz. There was a partial flow of current along the surface. As a result, the decomposition efficiency decreased. The decomposition efficiency of harmful gas $SO_2$ by the $Ca(OH)_2$ catalysis reactor and SPCP reactor was 96.0% under 300 ppm concentration, 10 kHz frequency, and decomposition power of 20 W. It was 4% higher than the application of the SPCP reactor alone. The highest decomposition efficiency, 98.0% was achieved at the concentration of 100 ppm.

Effect of CH4 Addition in Case of Decomposition of NOx, SOx by Discharge Plasma (방전플라스마에 의한 NOx, SOx 분해시 메탄첨가의 영향)

  • Kang, Hyun-Choon;Woo, In-Sung;Kang, An-Soo
    • Journal of the Korean Society of Safety
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    • v.15 no.2
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    • pp.70-77
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    • 2000
  • For hazardous air pollutants(HAP) such as NO, $NO_2$ and $SO_2$ decomposition efficiency, power consumption, and applied voltage were investigated by SPCP(Surface induced discharge Plasma Chemical Processing) reactor to obtain optimum process variables and maximum decomposition efficiencies. Decomposition efficiency of HAP with various electric frequencies(5~50 kHz), flow rates(100~1,000 mL/min), initial concentrations(100~1,000 ppm) and additive($CH_4$) were measured and the products were analyzed with FT-IR. Experimental results showed that for the frequency of 10 kHz, the highest decomposition efficiency of 94.3 % for NO, 84.7 % for $NO_2$ and 99 % far $SO_2$ were observed at the power consumptions of 19.8, 20 and 19W, respectively, and that decomposition efficiency decreased with increasing frequency above 20 kHz. And decomposition efficiency per unit power were 5.21 %/W for $SO_2$, 4.76 %/W for NO and 4.24 %/W for $NO_2$ and the highest decomposition efficiency was observed with $SO_2$. Decomposition efficiency was increased with increasing residence times and with decreasing initial concentration of pollutants. When the additive of $CH_4$ was used, decomposition efficiency was increased with increasing $CH_4$ content, and NO, $NO_2$ and $SO_2$ were almost completely decomposed with the efficiency of 99 %, 98 % and 99 %, respectively and therefore $CH_4$ was a good additive material. The optimum power for the maximum decomposition efficiency were 7.5 W for $SO_2$, 9.5 W for NO and 15.5 W for $NO_2$, respectively. Optimum power with the maximum decomposition efficiency were 9.5 W at 1,000 ppm of NO, 7~8 W at 100~500 ppm of NO and 15.5 W at all concentration range of $NO_2$ and 11.5 W at 1,000 ppm, 4.9 W at 500 ppm, 3.7 W at 100~300 ppm of $SO_2$ and power efficiency was best in these case.

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Structural Properties of Dielectric Barrier Reactor with Hole (DBH) for CF4 Decomposition

  • Jung Jung Gun;Kim Jong Suk;Park Jae Yoon;Kim Kwang Soo;Rim Geun Hie
    • Transactions on Electrical and Electronic Materials
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    • v.4 no.4
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    • pp.30-35
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    • 2003
  • In this paper, the $CF_4$ decomposition efficiency is investigated for three simulated plasma reactors that are needle plate reactor, metal particle reactor, and dielectric barrier reactor with hole (DBH). The$CF_4$ decomposition efficiency by DBH is much better than that by needle plate reactor or metal particle reactor. When applied voltage is increased up to the critical voltage for spark formation in the all reactors, the $CF_4$ decomposition efficiency is increased. The $CF_4$ decomposition efficiency in needle plate reactor and metal particle reactor is about $12\%$ and $22\%$ respectively at applied voltage of 23 kV (consumption power: 110 W) and $CF_4$ concentration of 500 ppm, however, the $CF_4$ decomposition efficiency is more than $95\%$ in case of DBH. DBH should be much better than two reactors investigated for $CF_4$ decomposition.

Enhanced data-driven simulation of non-stationary winds using DPOD based coherence matrix decomposition

  • Liyuan Cao;Jiahao Lu;Chunxiang Li
    • Wind and Structures
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    • v.39 no.2
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    • pp.125-140
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    • 2024
  • The simulation of non-stationary wind velocity is particularly crucial for the wind resistant design of slender structures. Recently, some data-driven simulation methods have received much attention due to their straightforwardness. However, as the number of simulation points increases, it will face efficiency issues. Under such a background, in this paper, a time-varying coherence matrix decomposition method based on Diagonal Proper Orthogonal Decomposition (DPOD) interpolation is proposed for the data-driven simulation of non-stationary wind velocity based on S-transform (ST). Its core idea is to use coherence matrix decomposition instead of the decomposition of the measured time-frequency power spectrum matrix based on ST. The decomposition result of the time-varying coherence matrix is relatively smooth, so DPOD interpolation can be introduced to accelerate its decomposition, and the DPOD interpolation technology is extended to the simulation based on measured wind velocity. The numerical experiment has shown that the reconstruction results of coherence matrix interpolation are consistent with the target values, and the interpolation calculation efficiency is higher than that of the coherence matrix time-frequency interpolation method and the coherence matrix POD interpolation method. Compared to existing data-driven simulation methods, it addresses the efficiency issue in simulations where the number of Cholesky decompositions increases with the increase of simulation points, significantly enhancing the efficiency of simulating multivariate non-stationary wind velocities. Meanwhile, the simulation data preserved the time-frequency characteristics of the measured wind velocity well.

The characteristic of $CF_{4}$ decomposition for High density streamer (고밀도스트리머를 이용한 $CF_{4}$ 분해특성)

  • Song, W.S.;Park, J.Y.;Jung, J.G.;Kim, J.S.;Kim, T.Y.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.08a
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    • pp.133-137
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    • 2002
  • In this paper, the $CF_{4}$ decomposition rate are investigated for a simulated three plasma reactors which are metal particle reactor, spiral wire reactor and reactor with porous dielectric as applied voltage. The $CF_{4}$ decomposition rate by plasma reactor with porous dielectric had a gain of 20~25[%] over that by plasma reactor with spiral wire or metal particle electrode. The $CF_{4}$ decomposition efficiency increases with increasing applied voltage up to the critical voltage for spark formation. The $CF_{4}$ decomposition efficiency of metal particle reactor was about 80[%] at AC 24[kV]. However, decomposition efficiency is more than 90% in case of the reactor with porous dielectric. we think, the reactor with porous dielectric should be much better than other reactors for $CF_{4}$ decomposition.

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Treatment of Odorous air pollutants by Plasma and Photocatalytic Process. (플라즈마 광촉매 복합 긍정을 이용한 악취물질 중 TEA, MEK의 분해처리)

  • 최금찬;정창훈
    • Journal of Environmental Science International
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    • v.12 no.12
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    • pp.1255-1260
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    • 2003
  • Plasma-photocatalytic oxidation process was applied in the decomposition of Triethylamine(TEA) and Methyl ethyl ketone(MEK). Plasma reactor was made entirely of pyrex glass and consists of 24mm inner diameter, 1,800mm length and discharge electrode of 0.4mm stainless steel. And initial concentrations of TEA and MEK for plasma-photocatalytic oxidation are 100 ppm. Odor gas samples were taken by gas-tight syringe from a glass sampling bulb which was located at reactor inlet and outlet, and TEA and MEK were determined by GC-FID. For plasma process, the decomposition efficiency of TEA and MEK were evaluated by varying different flowrates and decomposition efficiency of TEA and MEK increased considerably with decreasing treatment flowrates. For photocatalytic oxidation process, also the decomposition efficiency of TEA and MEK increased considerably with decreasing treatment flowrates. The decomposition efficiency of MEK was 57.8%, 34.2%, 18.8% respectively and the decomposition efficiency of TEA was reached all 100%. This result is higher than that of plasma process only, From this study, the results indicate that plasma-photocatalytic oxidation process is ideal for treatment of TEA and MEK.

Removal Characteristics of Benzene in Dielectric Barrier Discharge Process

  • Chung, Jae-Woo
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.E1
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    • pp.13-20
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    • 2002
  • The electrical and chemical properties of the dielectric barrier discharge (DBD) process for the benzene removal were investigated. The benzene removal was initiated with the applied voltage higher than the discharge onset value. The removal efficiency over 95 % was obtained at approximately 1.6 kJ lite $r^{r-1}$ of the electrical energy density. The increase of the inlet concentration decreased the removal efficiency. However, the benzene decomposition rate increased with the inlet concentration . While the increase of the gas retention time enhanced the removal efficiency, the decomposition rate decreased. Identification of the optimum condition between the decomposition rate and the removal efficiency is required for field applications of the DBD process.s.