• Title/Summary/Keyword: Decomposed component concentration

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Experimence Study of Trace Water and Oxygen Impact on SF6 Decomposition Characteristics Under Partial Discharge

  • Zeng, Fuping;Tang, Ju;Xie, Yanbin;Zhou, Qian;Zhang, Chaohai
    • Journal of Electrical Engineering and Technology
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    • v.10 no.4
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    • pp.1786-1795
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    • 2015
  • It is common practice to identify the insulation faults of GIS through monitor the contents of SF6 decomposed components. Partial discharges (PD) could lead to the decomposition of SF6 dielectric, so new reactions usually occur in the mixture of the newly decomposed components including traces of H2O and O2. The new reactions also cause the decomposed components to differ due to the different amounts of H2O and O2 even under the same strength of PD. Thus, the accuracy of assessing the insulation faults is definitely influenced when using the concentration and corresponding change of decomposed components. In the present research, a needle-plate electrode was employed to simulate the PD event of a metal protrusion insulation fault for two main characteristic components SO2F2 and SOF2, and to carry out influence analysis of trace H2O and O2 on the characteristic components. The research shows that trace H2O has the capability of catching an F atom, which inhibits low-sulfide SFx from recombining into high-sulfide SF6. Thus, the amount of SOF2 strongly correlates to the amount of trace H2O, whereas the amount of SO2F2 is weakly related to trace H2O. Furthermore, the dilution effect of trace O2 on SOF2 obviously exceeds that of SO2F2.

Rheology and morphology of concentrated immiscible polymer blends

  • Mewis, Jan;Jansseune, Thomas;Moldenaers, Paula
    • Korea-Australia Rheology Journal
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    • v.13 no.4
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    • pp.189-196
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    • 2001
  • The phase morphology is an important factor in the rheology of immiscible polymer blends. Through its size and shape, the interface between the two phases determines how the components and the interface itself will contribute to the global stresses. Rheological measurements have been used successfully in the past to probe the morphological changes in model blends, particularly for dilute systems. For more concentrated blends only a limited amount of systematic rheological data is available. Here, viscosities and first normal stress differences are presented for a system with nearly Newtonian components, the whole concentration range is covered. The constituent polymers are PDMS and PIB, their viscosity ratio can be changed by varying the temperature. The data reported here have been obtained at 287 K where the viscosities of the two components are identical. By means of relaxation experiments the measured stresses are decomposed into component and interfacial contributions. The concentration dependence is quite different for the two types of contribution. Except for the component contributions to the shear stresses there is no clear indication of the phase inversion. Plotting either the interfacial shear or normal stresses as a function of composition produces in some cases two maxima. The relaxation times of these stresses display a similar concentration dependence. Although the components have the same viscosity, the stress-component curves are not symmetrical with respect to the 50/50 blend. A slight elasticity of one of the components seems to be the cause of this effect. The data for the more concentrated blends at higher shear rates are associated with a fibrillar morphology.

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Application of Nonlinear Dynamics and Wavelet Theory for Discharge and Water Quality Data in Youngsan River Basin (영산강 유역의 유출량 및 수질자료에 대한 비선형 동역학과 웨이블렛 이론의 적용)

  • Oh, Chang-Ryeol;Jin, Young-Hoon;Park, Sung-Chun
    • Journal of Korean Society on Water Environment
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    • v.23 no.4
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    • pp.551-560
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    • 2007
  • The present study analyzed noise reduction and long/short-term components for discharge, TOC concentration, and TOC load data in order to understand the data characteristics better. For the purpose, wavelet transform which can reduce noise from raw data and has flexible resolution in time and frequency domain was applied and the theory of nonlinear dynamics was also used to determine the last decomposition level for wavelet transform. Wavelet function of 'db10' and the 7th level for the last decomposition of wavelet transform were applied for the all data in the present study. Also the results revealed that the energy ratios of approximation components with 187-hour periodicity decomposed from 7th level of wavelet transform were 94.71% (discharge), 99.00% (TOC concentration), and 93.84% (TOC load), respectively. In addition, the energy ratios of detail components showed the range between 1.00% and 6.17%, which were extremely small comparing to the energy ratios of approximation components, therefore, the first and second detail components might be considered as noise components included in the raw data.

Comparisons of the Equity of Medical Care Utilization by Sex, Age Groups, and Region (성, 연령, 지역에 따른 의료이용 형평성의 집단 간 비교)

  • Kim, Jin-Gu
    • Korean Journal of Social Welfare Studies
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    • v.43 no.2
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    • pp.319-344
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    • 2012
  • This study decomposed Concentration Index(CI) and Hiwv Index(HI) of medical care utilization by subgroups: sex, age group, and region. CI and HI were decomposed into "the between group" component, "within group" component, and a residual. The results of analysis are summarized as follows; First, there was no influence of sex on the equity of medical care utilization measured by the numbers of visiting clinic. However, "within group" component of female explained .0441 among HI, .1035. This means that poor women's underutilization of medical care is the important factor in determining its degree of equity. Second, age groups had a decisive effect on the equity of medical care utilization measured by the numbers of visiting clinic. they explained -.0085 among HI, -.0170. Third, internal equality within elderly group was the most important factor in determining HI measured by the medical care cost. Finally, "within group" component of urban area explained .0535 amomg HI, ,1035 measured by medical care cost. This indicated that the urban poor's underutilization of medical care was very important factor in explaining its degree of equity. There was the poor's underutilization of medical care within the groups as female, the elderly, and urban areas. This significantly explained the equity of medical care costs.

Reaction of the System of Coal Fly Ash-Sulfuric Acid-Calcium Hydroxide (플라이 애쉬-황산-수한화칼슘계의 반응)

  • 송종택;안민선;정문영
    • Journal of the Korean Ceramic Society
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    • v.33 no.12
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    • pp.1331-1338
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    • 1996
  • In order to investigate the reaction in the system of fly ash-sulfuric acid-calcium hydroxide the hydrates were produced by the addition of Ca(OH)2 to fly ash activated with sulfuric acid at various temperatures. And then they were characterized by XRD. SEM and TG-DTA. It was found that in the reaction of fly ash with sulfuric acid fly ash was not decomposed but Al2O3 and SiO2 component in it were activated. The addition of calcium hydroxide into this system resulted in the formation of ettringite and calcium silicate hydrate (C-S-H) As the concentration of sulfuric acid and reaction temperature increased the amount of calcium hydroxide decreased fast. At this time gypsum produced by the reaction calcium hydroxide with sulfuric acid was consumed to form ettringite. Accordingly the formation of ettringite increased with calcium hydroxide and reaction time. And it showed faster than the formation of C-S-H.

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Analysis of Varietal Variation in Alkali Digestion of Milled Rice at Several Levels of Alkali Concentration (쌀의 KOH 농도별 붕괴양상에 따른 품종변이 해석)

  • 최해춘;손영희
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.38 no.1
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    • pp.31-37
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    • 1993
  • To analyze and classify the varietal variation of alkali digestibility in detail, which is closely connected with the gelatinization temperature and physical characteristics of cooked rice, the patterns of alkali decomposition changed along the alkali concentration were investigated for thirty three Korean leading rice cultivars and new breeding lines(japonica : 25, Tongil-type:8) including five glutinous rice. Principal component analysis was used to condense the information and to classify rice materials according to decomposed reaction pattern at several levels of potassium hydroxide(KOH) concentration. Thirty three rice varieties were classified largely into four groups by the distribution on the plane of upper two principal component scores which contained above 92% of total informations. Group I was consisted of one variety, Dobongbyeo, which owned almost same strong resistance to alkali digestion at the range of 0.8% to 1.6% KOH solutions. Group II included three japonica and Tongil-type glutinous rice varieties, which revealed medium alkali digestion value(ADV) at 1.4% KOH solution and intermediate change in ADV from 0.8% to 1.6% KOH solutions. Most of Tongil-type and early-maturity japonica rice, which exhibited medium-high ADV at 1.4% of KOH concentration and large ADV difference between low and high alkali solutions, were contained in Group III. Group N included most of medium or medium-late-maturity japonica, which showed high ADV at 1.4% KOH and medium or intermediate-high ADV change between low and high alkali solutions. The 1st principal component indicated the average index of ADV through 0.8-1.6% KOH solutions and the 2nd principal component pointed out the factor related with ADV difference between low and high alkali solutions or regression coefficients of ADV change along with the KOH concentrations.

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Studies on the Absorption and Excretion of Ginsenosldes (인삼사포인의 흡수 및 배설에 관한 연구)

  • Han, Byeong-Hun;Park, Man-Gi;Lee, Eun-Sil
    • Journal of Ginseng Research
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    • v.15 no.2
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    • pp.112-116
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    • 1991
  • The metabolic fate of ginsenosides including gastrointestinat absorption, organ distribution, excretion and metabolism in liver was investigated by tracer studies using the radio-labeled ginsenosides. 3H-ginsenosides were shown to be absorbed from the mouse digestive tract and then to be excreted rapidly into urine and/or bile. Bile juice was concluded to play a significant role in absorption of ginsenosides. The total concentration of radioactivity persisted in tissues 24 hrs after oral administration was less than 1.3% of the administered dose and Rbl showed the highest value. The concentrations of radioactivity were relatively high in the liver and kidney. After administration of Rbl radioactivity was detected in the brain. After oral administration of 8H-ginsenosides, major component excreted into urine was found to be the intact ginsenosides and decomposed and/or metabolized products were found in GIT in the case of Rbl. 3H-ginsenoside Rbl was shown to be metabolized in the liver and the metabolite was suggested to be an acylated compound of Rbl by a certain organic acid.

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The Study of the Effects of Nonthermal Plasma-Photocatalyst combined Reactor on Hydrocarbon Decomposition and Reduction during Cold Start and Warm-up in a SI Engine (스파크 점화기관 냉간 시동시 플라즈마 광촉매 복합장치에 의한 탄화수소 화합물 저감에 관한 실험적 연구)

  • Lee, Taek-Heon;Chun, Kwang-Min;Chun, Bae-Hyeock;Shin, Young-Gy
    • 한국연소학회:학술대회논문집
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    • 2001.11a
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    • pp.169-178
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    • 2001
  • Among the recent research ideas to reduce hydrocarbon emissions emitted from SI engines till light-off of catalyst since cold start are those exploiting non-thermal plasma technique and photo-catalyst that draws recent attention by virtue of its successful application to practical use to clean up the atmosphere using the feature of its relative independence on temperature. Based on the previous research results obtained with model exhaust gases using an experimental emissions reduction system that utilizes the non-thermal plasma and photo-catalyst technique, further investigation was conducted on a production N/A 1.5 liter DOHC engine during cold start to warm-up. For the effects of non-thermal plasma-photocatalyst combined reactor, 10% concentration reduction was achieved with the fuel component paraffins, and the large increase in non-fuel paraffinic components and acetylene concentrations were similar to those of base condition. However the absolute value was locally a bit higher than those of base condition since the products was made from the dissociation and decomposition of highly branched paraffins by plasma-photocatalyst reactor. Olefinic components were highly decomposed by about 75%, due to these excellent decompositions of olefins which have relatively high MIR values, and the SR value was 1.87 that is 30% reduction from that of base condition, then, the photochemical reactivity was lowered.

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A Study on Water Quality Management Methods of Waterscape Facilities in Accordance Legislation of Water Quality Criteria (수질기준 법제화에 따른 물놀이형 수경시설의 수질관리방안 연구)

  • Na, Kyung-Ho;Yong, Jeong-Ju;Kim, Ji-Soo;Byeon, Ju-Young
    • Journal of Korean Society on Water Environment
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    • v.33 no.4
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    • pp.487-493
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    • 2017
  • This study was conducted to propose measures of water quality management as the water criteria for waterscape facilities which have been highlighted as alternatives to wading pools in summer season was legislated. The number of public waterscape facilities has reached 290 sites in Gyeounggi province and 971 sites in South Korea in 2017. The water tank capacity of 80.3 % public waterscape facilities was less than $100m^3$. Facilities with disinfection system were only 6.5 % and facilities with filtration function were also very low at 6.9 %. Most of the waterscape facilities, about 93%, are expected to be vulnerable to complying with revised water quality criteria because they have to be disinfected by handling. Chlorine disinfectants, which are more persistent than ozone or ultraviolet sterilization methods, are more preferred. However, care should be taken when adding disinfectans because hypochlorous acid, which is an effective component of chlorine disinfectant, remains after the disinfection, but it is easily decomposed with time. For this study, ${\bigcirc}{\bigcirc}$ park floor fountain with a capacity of $63m^3$ was selected and the amount of free residual chlorine concentration was measured by injecting a certain amount of chlorine bleach. As a result, it took 5 hours to decrease from the water quality standard of 4 mg/L to 0.04 mg/L. If the waterscape facility is operated for 7 to 8 hours, the chlorine bleach should be re-injected after 5 hours. In addition, the problem of pH increase due to the input of chlorine disinfectant is expected, and the neutralization method using vinegar was proposed.

Sources and Distributions of Dissolved Organic Matter by Fluorescence Method in the Northeastern Pacific Ocean (북동태평양에서 형광 기법을 이용한 용존유기물의 기원 및 분포)

  • Son, Ju-Won;Son, Seung-Kyu;Ju, Se-Jong;Kim, Kyeong-Hong;Kim, Woong-Seo;Park, Yong-Chul
    • Ocean and Polar Research
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    • v.29 no.2
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    • pp.87-99
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    • 2007
  • This study was conducted to understand the source and behavior of organic matter using the fluorescent technique (excitation-emission matrix) as a part of environmental monitoring program in the Korea manganese nodule mining site in the Northeastern Pacific Ocean. Water samples were collected at $0^{\circ},\;6^{\circ}N$, and $10.5^{\circ}N$ along $131.5^{\circ}W$ in August 2005. The concentration of total organic carbon (TOC) ranged from 58.01 to $171.93\;{\mu}M-C$. The vertical distribution of TOC was characterized as higher in the surface layer and decreased with depth. At $6^{\circ}N$, depth-integrated (from surface to 200 m depth) TOC was $337.1\;gC/m^2$, which was 1.4 times higher value than other stations. The exponential decay curve fit of vertical profile of TOC indicated that 59% of organic carbon produced by primary production in the surface layer could be decomposed by bacteria in the water column. Dissolved organic matter is generally classified into two distinctive groups based on their fluorescence characteristics using three-dimensional excitation/emission (Ex/Em) fluorescence mapping technique. One is known as biomacromolecule (BM; protein-like substance; showing max. at Ex 280/Em 330), mainly originated from biological metabolism. The other is geomacromolecule (GM; humic-like substance; showing max. at Ex 330/Em 430), mainly originated from microbial degradation processes. The concentration of BM and GM was from 0.42 to 7.29 TU (tryptophan unit) and from 0.06 to 1.81 QSU (quinine sulfate unit), respectively. The vertical distribution of BM was similar to that of TOC as high in the surface and decreased with depth. However, the vertical distribution of GM showed the reverse pattern of that of BM. From these results, it appeared that BM occupied a major part of TOC and was rapidly consumed by bacteria in the surface layer. GM was mainly transformed from BM by microbial processes and was a dominant component of TOC in the deep-sea layer.