• Title/Summary/Keyword: Decay Rate Method

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Singlet Oxygen Quenching by Deoxygadusol and Related Mycosporine-Like Amino Acids from Phytoplankton Prorocentrum micans

  • Suh, Hwa-Jin;Lee, Hyun-Woo;Jung. Jin
    • Journal of Photoscience
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    • v.11 no.32
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    • pp.77-81
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    • 2004
  • Deoxygadusol (DO) and structurally related mycosporine-like amino acids, i.e. mycosporine glycine (MO) and mycosporine taurine (MT), were isolated from phytoplankton Prorocentrum micans and studied for the reactivity toward singlet oxygen. These water-soluble compounds with a cyclohexenone chromophore were all shown to be highly effective in quenching singlet oxygen ($^1$ $O_2$), with the efficiencies being significantly larger compared with histidine, a well-known $^1$ $O_2$ quencher. The $^1$ $O_2$ reaction rate constant ( $k_{Q}$) of DG was determined to be 5.4 ${\times}$ 10$^{7}$ $M^{-1}$ $s^{-1}$ by a steady state method based on competitive inhibition of rubrene oxidation. The feasibility of this method was confirmed by estimating the $k_{Q}$ values for MG and two other quenchers, furfuryl alcohol and 1,4-diazabicyclo [2,2,2]octane, and comparing with those values determined by the time-resolved $^1$ $O_2$ decay method in the previous work.ork.

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A Substitute Model Learning Method Using Data Augmentation with a Decay Factor and Adversarial Data Generation Using Substitute Model (감쇠 요소가 적용된 데이터 어그멘테이션을 이용한 대체 모델 학습과 적대적 데이터 생성 방법)

  • Min, Jungki;Moon, Jong-sub
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.29 no.6
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    • pp.1383-1392
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    • 2019
  • Adversarial attack, which geneartes adversarial data to make target model misclassify the input data, is able to confuse real life applications of classification models and cause severe damage to the classification system. An Black-box adversarial attack learns a substitute model, which have similar decision boundary to the target model, and then generates adversarial data with the substitute model. Jacobian-based data augmentation is used to synthesize the training data to learn substitutes, but has a drawback that the data synthesized by the augmentation get distorted more and more as the training loop proceeds. We suggest data augmentation with 'decay factor' to alleviate this problem. The result shows that attack success rate of our method is higher(around 8.5%) than the existing method.

A Numerical Study on the Triboelectrostatic Separation of PVC Materials From Mixed Plastics for Waste Plastic Recycling

  • Ha, Man-Yeong;Jeon, Chung-Hwan;Park, Doo-Seong;Park, Hae-Jin
    • Journal of Mechanical Science and Technology
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    • v.17 no.10
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    • pp.1485-1495
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    • 2003
  • We investigate the triboelectrostatic separation of polyvinylchloride (PVC) from mixed plastics in the laboratory scale triboelectrostatic separation system. The flow and electric fields in the precipitator are obtained from the numerical solution of finite volume method. Using these flow and electric fields, we solved the particle motion equation considering the inertia, drag, gravity and electrostatic forces acted on the particles. The particle trajectories are obtained using a Lagrangian method as a function of different important variables such as Reynolds number, Stokes number, electrostatic force, electric charge and electric field distribution, inclined angle of plane electrodes, particle rebounding, particle charge decay rate after impact on the electrode surface, etc., in order to determine the optimal design conditions. The present predicted results for the cumulative yield represent well the experimental ones.

A Reliable Control of Nonlinear Systems via a Sum of Squares Approach (제곱합 접근법에 의한 비선형시스템의 신뢰성제어)

  • Yoo, Seog-Hwan
    • Journal of Applied Reliability
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    • v.12 no.2
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    • pp.121-129
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    • 2012
  • This paper deals with a design of reliable state feedback controllers for continuous time polynomial systems with actuator failures. The goal is to find an asymptotically stabilizing controller such that the closed loop system achieves the prescribed decay rate in the actuator failure cases. Based on a sum of squares (SOS) approach, a design method for reliable nonlinear controller is presented. In order to demonstrate our design method, a numerical example is shown.

Economic management of human businesses: Extending the life span of vegetables

  • Honglei Zhu;Duo Li
    • Structural Engineering and Mechanics
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    • v.85 no.4
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    • pp.461-468
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    • 2023
  • Edible coatings are one of the most innovative methods to preserve the quality and increase the shelf life of fresh fruits and vegetables. A successful edible coating should have a barrier against gases, especially oxygen and water vapor, and have good surface characteristics. Today, chitosan coating is widely used due to its properties, such as non-toxic, biodegradable, and biocompatibility. Is. Coating the surface of fruits and vegetables with chitosan increases shelf life due to reducing weight loss and reducing respiration rate and also reduces decay due to its antimicrobial and anti-fungal effect. This work discusses the effect of using chitosan coating containing chamomile extract to increase fresh vegetables'shelf life. In addition to increasing the shelf life of vegetables, this method can be used as a solution for the economic management of human resources. The results of this method confirm the successful synthesis of these nanoparticles, and the results of applying this food coating on vegetables have been successful. They have increased the shelf life of vegetables such as basil and spinach.

Photochemical Kinetics of Maleic to Fumaric Acid on Silver Nanoparticle Surfaces

  • Jang, Nak-Han;Jeong, Dae-Hong;Suh, Jung-Sang
    • Bulletin of the Korean Chemical Society
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    • v.26 no.5
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    • pp.791-794
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    • 2005
  • A visible photochemistry of maleic to fumaric acid adsorbed on silver nanoparticle surfaces was investigated as probed by SERS using a simple flow method. Photoisomerization of maleic to fumaric acid was consecutively observed in the condition of various flow rates, which varied the exposure time of laser beam. The sequential SERS spectra of maleic acid indicated that the photochemical isomerization and desorption took place simultaneously on silver nanoparticle surfaces as a function of laser fluency and wavelength. For 530.9nm laser line excitation, the rate constant coefficients were obtained with a = 5.9 $sec^{-1}$ mW for isomerization and b = 13.9 $sec^{-1}$ mW for desorption, which $k_1\;=\;aI^n\;and\;k_2\;=\;bI^m$. Both reactions were one photon process (n = 1, m = 1) of a visible light and relatively fast process whose decay time was in the range of milli-second for 50 mW laser power. The rate of photochemical reaction increased on going toward the blue and photodesorption was a dominant process. A simple flow method used in this study was very useful to study a relatively fast photochemical reaction of molecules adsorbed on silver nanoparticle surfaces.

An Experiment on Verification of Multi-Gas Tracer Technique for Air Exchange Rate Between Rooms (실간환기량 측정을 위한 멀티추적가스법의 검증실험)

  • Han, Hwa-Taik;Cho, Seok-Hyo
    • Proceedings of the SAREK Conference
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    • 2007.11a
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    • pp.99-104
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    • 2007
  • Tracer gas technique is widely used to measure the ventilation rates and/or ventilation effectiveness of building spaces. However, the conventional method using a single tracer gas can measure only outdoor air change rates in a single zone. This paper deals with the multi-gas tracer technique to measure air exchange rates between rooms. Interzonal air movements are important to characterize overall ventilation performance of complicated multi-zone buildings. Experiments are conducted in a simple two-room model with known airflow rates using tracer gases of SF6 and R134a. The concentration decays of two tracer gases are measured after simultaneous injections in each room. The governing equations are derived from the continuity and the mass balance of each room. The data reduction procedure are developed to obtain the inter-room airflow rates using the governing matrix inversion, and various data manipulation methods are tested, such as data shift, interpolation, smoothing, and etc, to improve the estimate and interpretation of the results.

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Investigation of 180W separation by transient single withdrawal cascade using Salp Swarm optimization algorithm

  • Morteza Imani;Mahdi Aghaie
    • Nuclear Engineering and Technology
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    • v.55 no.4
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    • pp.1225-1232
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    • 2023
  • The 180W is the lightest isotope of Tungsten with small abundance ratio. It is slightly radioactive (α decay), with an extremely long half-life. Its separation is possible by non-conventional single withdrawal cascades. The 180W is used in radioisotopes production and study of metals through gamma-ray spectroscopy. In this paper, single withdrawal cascade model is developed to evaluate multicomponent separation in non-conventional transient cascades, and available experimental results are used for validation. Numerical studies for separation of 180W in a transient single withdrawal cascade are performed. Parameters affecting the separation and equilibrium time of cascade such as number of stages, cascade arrangements, feed location and flow rate for a fixed number of gas centrifuges (GC) are investigated. The Salp Swarm Algorithm (SSA) as a bio-inspired optimization algorithm is applied as a novel method to minimize the feed consumption to obtain desired concentration in the collection tank. Examining different cascade arrangements, it is observed in arrangements with more stages, the separation is further efficient. Based on the obtained results, with increasing feed flow rate, for fixed product concentration, the cascade equilibrium time decreases. Also, it is shown while the feed location is the farthest stage from the collection tank, the separation and cascade equilibrium time are well-organized. Finally, using SSA optimal parameters of the cascade is calculated, and optimal arrangement to produce 5 gr of 180W with 90% concentration in the tank, is proposed.

A Study on the Ozone Consumption Rate for Drinking Water Treatment Process with Ozone Application (오존의 정수처리 적용을 위한 오존소비인자에 관한 연구)

  • Kang, Tae-Hee;Oh, Byung-Soo;Kwon, Soon-Buhm;Sohn, Byeong-Yong;Kang, Joon-Wun
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.6
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    • pp.663-669
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    • 2005
  • The aim of this study was to investigate the ozone decay pattern for the effective application of ozone in drinking water treatment. In order to measure the ozone decomposition in water, ozone measuring instrument was developed with flow injection analysis (FIA) method. From the result of continuous residual ozone concentration in water, it was confirmed that the ozone decay pattern was divided with instantaneous ozone demand(I.D) and pseudo first-order rate($k_c$) phases, which were influenced by the variation of ozone dose. The empirical model obtained from I.D and $k_c$ values enabled us to predict the residual ozone concentration according to the reaction time, showing the high correlation between model and experimental values. The concentration of OH radical and $R__{ct}$ could be indirectly measured by OH radical probe compound. In both I.D and $k_c$ phases, the production pattern of OH radical could be observed, which was also affected by the variation of ozone dose. Finally, it was confirmed that the ozone consumption rate was varied according to the each drinking water treatment process and seasoning. Therefore, the optimum position and dosage of ozone have to be selected by considering various factors.

Analysis on Ventilation Efficiency of Standard Duck House using Computational Fluid Dynamics (전산유체역학을 이용한 표준 오리사 설계안에 대한 환기효율성 분석)

  • Yeo, Uk-Hyeon;Jo, Ye-Seul;Kwon, Kyeong-Seok;Ha, Tae-Hwan;Park, Se-Jun;Kim, Rack-Woo;Lee, Sang-Yeon;Lee, Seung-No;Lee, In-Bok;Seo, Il-Hwan
    • Journal of The Korean Society of Agricultural Engineers
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    • v.57 no.5
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    • pp.51-60
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    • 2015
  • In Korea, 69.4 % of duck farms had utilized conventional plastic greenhouses. In this facilities, there are difficulties in controlling indoor environments for raising duck. High rearing density in duct farms also made the environmental control difficult resulting in getting more stressed making their immune system weaker. Therefore, a facility is needed to having structurally enough solidity and high efficiency on the environmental control. So, new design plans of duck house have recently been conducted by National Institute of Animal Science in Korea. As a study in advance to establish standard, computational fluid dynamics (CFD) was used to estimate the aerodynamic problems according to the designs by means of overall and regional ventilation efficiencies quantitatively and qualitatively. Tracer gas decay (TGD) method was used to calculate ventilation rate according to the structural characteristics of duck houses including installation of indoor circulation fan. The results showed that natural ventilation rate was averagely 164 % higher than typically designed ventilation rate, 1 AER ($min^{-1}$). Meanwhile, mechanically ventilated duck houses made 81.2 % of summer ventilation rate requirement. Therefore, it is urgent to develop a new duck house considering more structural safety as well as higher efficiency of environmental control.