• Advances in materials Research
• /
• v.2 no.1
• /
• pp.1-13
• /
• 2013

Lead-free compound $(Na_{0.5}Bi_{0.5})(Zr_{0.75}Ti_{0.25})O_3$ was prepared using conventional ceramic technique at $1070^{\circ}C$/4h in air atmosphere. X-ray diffraction analysis showed the formation of single-phase orthorhombic structure. Permittivity data showed low temperature coefficient of capacitance ($T_{CC}{\approx}5%$) up to $100^{\circ}C$. Complex impedance studies indicated the presence of grain boundary effect, non-Debye type dielectric relaxation and evidences of a negative temperature coefficient of resistance. The ac conductivity data were used to evaluate the density of states at Fermi level and apparent activation energy of the compound.

• Bulletin of the Korean Chemical Society
• /
• v.29 no.6
• /
• pp.1131-1136
• /
• 2008

The electrical repulsive energy between two model cylinders was calculated by solving nonlinear Poission- Boltzmann (P-B) equation under Derjaguin approximation. Effects of the surface potential, Debye screening length, and configuration of cylinders on the repulsive interaction energy were examined. Due to the anisotropy of the shape of cylinder, the interaction repulsive energy showed dependence to the configuration of particles; cylinders aligned in end-to-end configuration showed largest repulsive energy and crossed particles had lowest interaction energy. The configuration effect is originated from the curvature effect of the interacting surfaces. The curved surfaces showed less repulsive energy than flat surfaces at the same interacting surface area. The configuration dependency of interaction energy agreed with the previous analytical solution obtained under the linearized P-B equation. The approach and results present in this report would be applicable in predicting colloidal behavior of cylindrical particles.

• Proceedings of the IEEK Conference
• /
• 2000.06b
• /
• pp.76-79
• /
• 2000

The 3$\mu\textrm{m}$-thick PVDF (Polyvinyiidene fluoride) thin film have been prepared using physical vapor deposition with electric field, and its FT-IR specrum, dielectric property and electric conduction phenomenon have been investigated. Since the characteristic peaks ate detected at 509.45 and 1273.6〔cm〕 in the FT-IR spectrum, we are confirmed that the ${\beta}$ -phase is dominant in the PVDF thin film. In the results of dielectric properties, the PVDF thin film shows anomalous dispersion, i.e. gradual decrease of dielectric constant with increase of frequency, and also that the dielectric absorption point changes from 200Hz to 7000Hz with increasing temperature of thin film, which is consistent with the Debye's theory. The activation energy (ΔH) obtained from temperature dependence of dielectric loss is 21.64 ㎉/㏖. We confirm that the electric conduction mechanism of PVDF thin film is dominated by ionic conduction by investigating the dependence of the leakage current of the thin film on the temperature and the electric field.

• Journal of the Korean institute of surface engineering
• /
• v.50 no.3
• /
• pp.225-229
• /
• 2017

ZnO nanotubes were synthesized to investigate the effect of wall thickness on the ethanol gas sensing performance. The wall thickness of the nanotubes was varied from approximately 20 to 60 nm. Transmission electron microscopy, X-ray diffraction and SAED (Selected Area Electron Beam Diffraction) analyses showed that the synthesized nanotubes were polycrystalline structured ZnO with the diameter of approximately 200-300nm. The ZnO nanotubes sensor with an optimum wall thickness of 51.8nm showed approximately 8 times higher response, compared to that with 21.14nm wall thick nanotubes, to the ethanol concentration of 500 ppm at the temperature of $300^{\circ}C$. The wall thickness of 51.8nm was found to be a little larger than 46nm, which was theoretically derived Debye length. Along with the study of the wall thickness effect on the performance of the sensors, the mechanisms of gas sensing of the polycrystalline ZnO nanotubes are also discussed.

• Proceedings of the KIEE Conference
• /
• 1988.11a
• /
• pp.186-188
• /
• 1988

Relaxation spectra of the linear dielectric constants $\varepsilon=\varepsilon'-j{\varepsilon}"$ have been measured as functions of temperature and frequency for alternating copolymers of vinylidene cyanide (VDCN/VAc, VDCN/VPr, VDCN/VBz and VDCN/St) It is found that the linear dielectric constants e show characteristics of the temperature dependence that the real part have a large peak related to the glass transition point(Tg), and of the frequency dependence that the real port increases with decreasing frequency and the imaginary part increases largely in low frequency range. These phenomena mean Debye-type relaxation due to the micro-Brownian moi ions of non-crystalline seqments.

• Journal of Magnetics
• /
• v.17 no.4
• /
• pp.255-260
• /
• 2012

In this study, we determine that the electron paramagnetic resonance line-width (EPRLW) is axially symmetric about the c-axis and analyze the spin Hamiltonian with an isotopic g-factor of 1.9920 at a frequency of 9.5 GHz. It should be noted that the electron paramagnetic resonance signals are Lorentzian. Our findings show that the EPRLW decreases exponentially with an increase in the temperature; i.e., its temperature dependence in the range 300-400 K obeys Arrhenius behavior, this kind of temperature dependence indicates an off-center a motional narrowing of the spectrum when $Mn^{2+}$ impurity ions substitute for $Nb^{5+}$ ions. The specific heats follow a linear dependence suggesting a simple Debye $T^3$ behavior.

• Journal of the Korean Electrochemical Society
• /
• v.10 no.3
• /
• pp.203-206
• /
• 2007

Electrochemical reaction of glucose was regulated by the electrochemically active area of nanoporous platinum, which is controlled by ionic strength. The profile of the oxidation current of glucose vs. ionic strength was identical with that of the electrochemically active area. This result confirms that the nanopores are virtually opened for the electrochemical reaction of glucose when the ionic strength climbs over a specific concentration and implies that the electrochemical reactions on nanoporous electrode surfaces can be controlled by concentration of electrolyte.

• Proceedings of the KIEE Conference
• /
• 1996.07c
• /
• pp.1627-1629
• /
• 1996

Polyvinylidene fluoride( : PVDF) has piezoelectric and pyroelectric. The ${\beta}-PVDF$ manufactured by induced-electric field. In accordance to increasing induced-electric field, the 530 $cm^{-1}$ peak decrease, whereas $510cm^{-1}$ peak increase. The dielectric constant of PVDF thin film is 6.8 and 10 MV/m induced-PVDF thin film is 9.4. The dielectric relaxation characteristic of PVDF thin films correspond to Debye's theory.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
• /
• 2012.10a
• /
• pp.37-38
• /
• 2012

In this research, the application of PUF modeling which is configured to be doped oxide material on Si substrate and this oxide material is to prevent corrosion of the security chip device. It is to design device replication technology through applying the electromagnetic formulation and its analysis of a device and find ways to PUF design.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 1994.11a
• /
• pp.147-151
• /
• 1994

In order to investigate the dielectric characteristic insulating oil is chosen insulating oil for electric cable, and experiment is performed in the temperature range of 30∼120[$^{\circ}C$] and frequency range of 30∼1${\times}$10$\^$6/[㎐]. As a result, the observed linear decrease in tan $\delta$ value at the low frequency range is due to the influence of frequency, whereas the increase in tan $\delta$ value at high frequency range is contributed by the electrode's resistance and dielectric loss. The dipole moment and activation energy of specimen are obtained 1.22(debye) and 12.75∼18.66[㎉/㏖e] of high temperature region, 15.68 ∼ 20.6[㎉/㏖e] of low temperature region respectively.