• Journal of the Korean Society of Propulsion Engineers
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• v.22 no.4
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• pp.55-60
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• 2018

The thermal property is one of the most important characteristics in the field of energetic materials. Because energy materials release decomposition heat, differential scanning calorimetry (DSC) is frequently used for thermal analysis. However, thermodynamic events, such as melting can interfere with DSC kinetic analysis. In this study, we use isothermal mode for DSC measurement to avoid thermodynamic issues. We also merge accelerating rate calorimetry(ARC) data with DSC data to obtain a robust prediction results for small scale samples and for large scale samples as well. For the thermal property prediction, advanced kinetics and technology solutions(AKTS) programs are used.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.172-178
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• 2017

Thermal property is one of the important characteristic in the field of energetic materials. As the energy material is released during decomposition, DSC(Differential Scanning Calorimetry) is frequently used for the thermal analysis. In case of the dynamic DSC measurements, thermal dynamic change like melting is prevented from the thermal property measurements. And due to the predicting kg scale, the conditions of the heat exchange with the environment significantly is changed. In this study, As the method to resolve the problem, we predict the thermal aging property using the AKTS thermokinetic program from DSC measurements which performed isothermal method. Predicting the thermal aging properties from ARC(Accelerating Rate Calorimetry) measurement, we compare two results.

• International Journal of Industrial Entomology and Biomaterials
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• v.37 no.1
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• pp.29-32
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• 2018

Silkworm powder's thermal property is an important factor for its storage and marketing. This study examined the effect of edible enzyme on the thermal property of silkworm powder using Thermogravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC). Results of the TGA showed that regardless of the enzyme treatment, the weight loss patterns of silkworm powders exhibited 3 step thermal property deterioration at approximately $80^{\circ}C$, $280^{\circ}C$, and $480^{\circ}C$ due to water evaporation and thermal degradation. This is similar with the DSC which also resulted in all samples two endothermic peaks attributed also to water evaporation and thermal degradation. These results indicated that the use of enzyme such as protease and cellulase might not affect significantly the thermal properties of silkworm powder.

• The Journal of Sustainable Design and Educational Environment Research
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• v.16 no.2
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• pp.54-63
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• 2017

The various colors and transparency of DSC and operability unrelated with directions greatly expand the use of BIPV, as a multi-functional composite of module. Therefore the possibility of DSC BIPV is examined by the case study and the analysis and then its applicability is examined. Most of the DSC BIPVs, which are found through a total of six case studies and analyzes in Korea and abroad, are mainly implemented with window glass and shading devices. This is related to the DSC transparency property. Improvements are due to the irritation of the eye due to the color of the red module. Therefore, it is important to take into account the color of the BIPV window depending on the use of the building and the room. Meanwhile, some colors of application model may stimulate eyes and such colors should be considered by use of buildings and rooms in the application of BIPV window. DSC BIPV has prospective diffusibility with the development of flexible module for the application of building surface.

• Applied Chemistry for Engineering
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• v.24 no.2
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• pp.144-147
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• 2013

Sweating, which is the excretion of oil on the surface of a solid product containing several kinds of pigments in oil and is also solidified with wax, is a unique phenomenon often observed on the surface of cover make-up or lipstick. The cause of sweating is an imbalanced formula. Many studies have been conducted to decrease the symptoms of sweating in the field of cosmetics. Differential scanning calorimetry (DSC) is a thermo-analytical technique that measures the amount of heat required to increase the temperature of a sample as a function of temperature or time under certain conditions. DSC has been used to determine the thermal properties of oil/wax structures. This study investigates how the thermal characteristics correlate with the sweating symptoms. An oil/wax formulation with an optimal melting point was studied in an attempt to make a stable product by considering the thermal properties that represent minimal structural changes with temperature variation. In addition, the sweating of the oil/wax formulation was observed over a various temperature range. As a result, it was found that sweating was minimized when the structure remained static or little bit changed over a variety of temperatures.

• Applied Chemistry for Engineering
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• v.23 no.3
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• pp.352-357
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• 2012

Techniques of thermal analyses such as DSC and TGA have been used in the study of activation energy (Ea) and frequency factor (A) depending on the particle size of RDX and HMX. Activation energy and frequency factor were calculated by Kissinger's method and Vyazovkin's method. As the particle size of RDX increased, TGA showed activation energy increased, but DSC didn't show. However, In case of HMX, as the particle size increased, both of DSC and TGA showed increase in activation energy. Moreover, Vyazovkin's method can obtain activation energy and mechanism according to decomposition of RDX and HMX.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.53 no.6
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• pp.293-299
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• 2004

In this paper, thermal and mechanical properties of electric epoxy with water aging were discussed. We made elastic epoxy specimen adding a ratio of 0〔phr〕20〔phr〕, 35〔phr〕 and 53〔phr〕 with modifier to existing epoxy. We studied mechanical property of elastic resin after absorption in water from 0 to 484 hours. As a result, diffusion factor of elastic epoxy showed 20-21${\times}$10$^{-4}$ $\textrm{mm}^2$/s and general epoxy showed 9.5${\times}$10$^{-4}$ $\textrm{mm}^2$/s. Elastic property increased linearly according to addiction and decreased according to water absorption. Tensile strength was reduced according to addition. It was affected by water absorption of micro-void of elastic epoxy. Hardness inclined to decrease after increasing according to absorbed time. In water-absorption state, it was experimented a change of heat flow by temperature of elastic epoxy and change of thermal expansion coefficient. DSC (Differential Scanning Calorimetry) and TMA (Thermomechanical Analysis) equipments were used to measure Tg. A temperature ringe of DSC was from -0($^{\circ}C$) to 200($^{\circ}C$). One of TMA was from -0($^{\circ}C$) to 350($^{\circ}C$). In addition, we investigated structural analysis of water absorbed specimen using SEM (Scanning Electron Microscope).

• Korean Journal of Food Science and Technology
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• v.27 no.4
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• pp.571-575
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• 1995

Transition temperature$(T_m)$ and $enthalpy({\Delta}H)$ were examined by means of DSC to obtain basic information on heat stability of skin tissue collagen. From DSC properties of insoluble collagen on hydration time and moisture content, it was found that moisture content had more effect on structural stability of collagen than hydration time. As moisture content increased, $({\Delta}H)$ increased while $(T_m)$ decreased. DSC properties of acetone dried skin on the variation of age and sex showed higher heat stability in case of male rat and heat stability seemed to be connected with age, as $(T_m)$ and $({\Delta}H)$increased with age. Meanwhile, DSC properties of salt soluble collagen showed higher values in female rat than in male rat, and the $(T_m)$ and $({\Delta}H)$ decreased significantly with age in female rat. These results seemed to suggest indirectly that collagen structure varied with age or sex in the same tissue.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.06a
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• pp.110-110
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• 2010

Suspension insulator have made use of porcelain insulator mainly, but polymer insulator is using recently. Polymer suspension insulator have advantage that it is light than porcelain insulator. The ageing performance is excellent and it is possible for mass production. There is high possibility of mountain fire because a lot of potential inflammables such as fallen leaves are stacked on the ground Therefore surface aging of polymer insulator most of the overhead transmission lines in Korea are operated on the mountain need analysis of transmission line into forest fire. surface aging property is analyzed by SEM, EDX, XPS, FTIR, DSC in this paper.

• Fibers and Polymers
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• v.5 no.3
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• pp.245-251
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• 2004

Poly(trimethylene terephthalate-co-trimethylene 2,6-naphthalate)s (P(TT-co-TN)s) with various copolymer composition were synthesized, and their chain structure, thermal property and crystalline structure were investigated by using $^1$H-NMR spectroscopy, differential scanning calorimetry (DSC) and wide-angle X-ray diffraction (WAXD), respectively. It was found from sequence analysis that all the P(TT-co-TN) copolymers synthesized have a statistical random distribution of TT and TN units. It was also observed from DSC thermograms that the glass transition temperature increases linearly with increasing the TN comonomer content, whereas the melting temperature of copolymer decreases with increasing the corresponding comonomer content in respective PTT- and PTN-based copolymer, showing pseudo-eutectic melting behavior. All the samples melt-crystallized isothermally except for P(TT-co-66 mol % TN) exhibit multiple melting endotherms and clear X-ray diffraction patterns. The multiple melting behavior originates from the dual lamellar population and/or the melting-recrystallization-remelting. The X-ray diffraction patterns are largely divided into two classes depending on the copolymer composition, i.e., PTT and PTN $\beta$-form diffraction patterns, without exhibiting cocrystallization.