• Title/Summary/Keyword: DOM

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Advanced Analytical Techniques for Dissolved Organic Matter and Their Applications in Natural and Engineered Water Treatment Systems (최근 용존 유기물 분석 기법 및 자연환경과 수 처리 시스템 내 활용방안)

  • Lee, Yun Kyung;Hur, Jin
    • Journal of Korean Society on Water Environment
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    • v.38 no.1
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    • pp.31-42
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    • 2022
  • Dissolved organic matter (DOM), which changes according to various factors, is ubiquitously present from natural environments to engineered treatment systems. Only limited information is available regarding the environmental functions of DOM after bulk analyses are only applied for characterization. In this paper, latest DOM analytical techniques are briefly introduced, which include fluorescence excitation-emission matrix with parallel factor analysis (EEM-PARAFAC), size-exclusion chromatography with an organic carbon detector (SEC-OCD), carbon/nitrogen stable-isotope ratio, and Fourier transform-ion cyclotron resonance-mass spectroscopy (FT-ICR-MS). Recent examples of using advanced analyses to interpret the phenomena associated with DOM occurring in natural and engineered systems are presented here. Through EEM-PARAFAC, different components like protein-like, fulvic-like, and humic-like can be identified and tracked individually through the investigated systems. SEC-OCD allows researchers to quantify different size fractions. FT-ICR-MS provides thousands of molecular formulas present in bulk DOM samples. Lastly, carbon/nitrogen stable-isotope ratio offers reasonable tools for tracking the sources in environments. We also discuss the advantages and weakness of the above-mentioned characterizing tools. Specifically, they focus on single environmental factors (different sourced-DOM and interaction of sediment-pore water) or simple changes after individual treatment processes. Through collaboration with the advanced techniques later, they help the researchers to better understand environmental behaviors in aquatic systems and serve as essential tools for addressing various pending problems associated with DOM.

The Distribution of DOM and POM and the Composition of Stable Carbon Isotopes in Streams of Agricultural and Forest Watershed Located in the Han River System (한강수계 농경지역 하천과 삼림지역 하천에서 DOM과 POM의 분포 및 안정탄소동위원소 조성비)

  • Kim, Jai-Ku;Kim, Bom-Chul;Jung, Sung-Min;Jang, Chang-Won;Shin, Myoung-Sun;Lee, Yun-Kyoung
    • Korean Journal of Ecology and Environment
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    • v.40 no.1
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    • pp.93-102
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    • 2007
  • The runoff characteristics of organic matter in turbid water were investigated in eleven tributary streams of the Han River system, Korea. The flow-weighted event mean concentrations of organic matter ranged from 1.5 to 3.2 mg $L^{-1}$ of DOM and 2.2 of 29.1 mg $L^{-1}$ of POM, respectively. The SUVA value which reflects the proportion of humic substance in organic matters was higher during the rainfall season, meaning that the runoff of refractory form increase in this period. Stable carbon isotope ratios of both POM and DOM were different among streams, which reflect the sources of organic matter. DOM isotope ratios were less depleted of $^{13}C$ than that of POM by approximately 1 to $2%_{\circ}$ ${\delta}^{13}C$ of the several turbid streams (the Mandae Stream, the Jawoon Stream, and the Daegi stream) were heavier than those of clear streams. ${\delta}^{13}C$ values in the turbid upstream tributaries were similar to those of downstream reaches (such as the Soyang River, the Sum River, and the Seo River). From the ${\delta}^{13}C$ analysis of POM it could be calculated that $C_4$ pathway contributed approximately 15.9 to 23.6% of organic matter in several turbid upstream sites, and over 20% in the three sites of large downstream reaches. On the contrary it contributed only 9.1 to 12.8% in clear streams of forest watersheds. In the Soyang River, $C_4$ pathway organic matter contributed 8.8% of the DOM pool.

Storage properties of brown rice cultivar as affected by milling degree and storage conditions

  • Choi, Induck;Yoon, Mi-Ra;Kwak, Jieun;Chun, Areum;Jeon, Yong-Hee;Jeong, Tae-Wook;Kim, Sun-Lim
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2017.06a
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    • pp.262-262
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    • 2017
  • Brown rice contains a variety of nutritional and bio-functional components compared to milled rice. However, low consumer preference for steamed brown rice and short shelf life has been implicated as deterrents to the direct consumption of brown rice. This study was undertaken to determine the effect of degree of milling (DOM) on pasting and aging properties of brown rice cultivar. Short-grain (Japonica type) brown rice cv. Boseogchal (BSC), Baegjinju (BJJ), and Hiami (HIAM) were evaluated every month during 4 months storage. Rice cultivar were categorized into waxy (BSC), medium-waxy (BJJ), and non-waxy (HIAM) of which amylose contents were 6.81%, 10.06%, and 16.69~16.72%, respectively. Peak viscosity was the highest in BJJ followed by HIAM, and BSC, showing peak viscosity was lower at low temperature storage. At storage at room temperature from 60 to 120 days, the FFA content significantly increased in the rice samples with DOM1% followed by 3% and 5%, while not significant increase in DOM0% brown rice: at 120 days, the FFA ranged in 28.35~41.48, 111.99~130.06, 76.87~91.99, and 47.13~62.37 mg KOH/100g for DOM 0%, 1%, 3% and 5%, respectively. It indicated that the fat rancidity was the least in the order of DOM 0%, 5%, 3% and 1%. Storage at low temperature could reduce fat hydrolysis with lower FFA release, but rice grain with 1% MD also released more FFA compared to the other samples. It could be assumed that the most outer bran layer, approximately 1~3%, could provide a strong protection from fat rancidity. Pasting viscosity of rice samples also increased with increasing DOM rate. Results indicated that DOM was the most significant factor for lipid rancidity during storage, resulting in high FFA formation. It suggested that brown rice with DOM 0% and/or more than DOM 5% could provide the best shelf life.

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Fabrication of Three-dimensionally Ordered Macroporous Electrode Materials by Using PMMA Template (PMMA 구를 주형으로 이용한 3DOM 전극 구조체의 제조)

  • Seo Kyoung Soo;Jung Ha-Kyun;Son Yongkeun
    • Korean Journal of Materials Research
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    • v.14 no.8
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    • pp.587-594
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    • 2004
  • Three-dimensionally ordered macroporous (3DOM) structures of the $LiCoO_2$ electrode materials for Li secondary batteries were fabricated by using the close-packed arrays of PMMA spheres served as templates. In order to successfully fabricate the cathode materials with highly ordered array form, the metal citrates were applied to new precursors. The precursor/template composites were prepared by the infiltration with metal citrate precursors into the voids of template. By removing the PMMA templates, then, the inverse opal structures with the uniform pores of narrow size distribution were resulted. It was confirmed that the 3DOM $LiCoO_2$ material is to take a single phase of rocksalt (R3m) structure. In addition, 3DOM $LiNiO_2$ and $LiMn_{2}O_4$ cathode materials were fabricated using an identical preparation procedure. Also, the morphology of the 3DOM cathode materials calcined at $500^{\circ}C\;to\;700^{\circ}C$ was observed by scanning electron microscope.

A Web-based System for Embedding a Live Actor and Entity using X3DOM (X3DOM 을 이용한 라이브 행동자와 실체를 통합하기 위한 웹 기반 시스템)

  • Chheang, Vuthea;Ryu, Ga-Ae;Jeong, Sangkwon;Lee, Gookhwan;Yoo, Kwan-Hee
    • Proceedings of the Korean Society of Broadcast Engineers Conference
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    • 2016.11a
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    • pp.1-3
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    • 2016
  • Mixed and augmented reality (MAR) refers to a spatially coordinated combination of media/information components that represent on the real world and its objects, and on the other those that are virtual, synthetic and computer generated including any combination of aural, visual and touch. The extensible 3D (X3D) is the ISO standard for defining 3D interactive web-based 3D content integrated with multimedia. In this paper, we propose a model to integrate live actor and entity that captured from Microsoft Kinect to be represented in Web-based mixed augmented reality world by using X3DOM by which X3D nodes can be integrated seamlessly into HTML5 DOM content.

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Transformation of dissolved organic matter in a constructed wetland: A molecular-level composition analysis using pyrolysis-gas chromatography mass spectrometry

  • Park, Jongkwan;Choi, Mijin;Cho, Jaeweon;Chon, Kyongmi
    • Environmental Engineering Research
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    • v.23 no.4
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    • pp.390-396
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    • 2018
  • This study investigated the transformation of dissolved organic matter (DOM) in a free-water surface flow constructed wetland. Pyrolysis gas chromatography-mass spectrometry (Py-GC/MS) coupled with preparative high-performance liquid chromatography (prep-HPLC) was used to analyze the compositions of biopolymers (polysaccharides, amino sugars, proteins, polyhydroxy aromatics, lipids and lignin) in DOM according to the molecular size at three sampling points of the water flow: inflow, midflow, and outflow. The prep-HPLC results verified the decomposition of DOM through the decrease in the number of peaks from three to one in the chromatograms of the sampling points. The Py-GC/MS results for the degradable peaks indicated that biopolymers relating to polysaccharides and proteins gradually biodegraded with the water flow. On the other hand, the recalcitrant organic fraction (the remaining peak) in the outflow showed a relatively high concentration of aromatic compounds. Therefore, the ecological processes in the constructed wetland caused DOM to become more aromatic and homogeneous. This indicated that the constructed wetland can be an effective buffer area for releasing biochemically stable DOM, which has less influence on biological water quality indicators, e.g., biochemical oxygen demand, into an aquatic ecosystem.

Fate and Characteristics of Dissolved Organic Matters in a Water Reclamation Facility, Korea (하수처리수 재이용시설의 공정별 용존유기물질 거동 및 특성)

  • Kwon, Eun-Kwang;Lee, Wontae
    • Journal of Korean Society on Water Environment
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    • v.37 no.5
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    • pp.355-362
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    • 2021
  • This study investigated the fate of dissolved organic matter (DOM) in a water reclamation facility (WRF) in Korea. The WRF consists of coagulation, sedimentation, microfiltration, and reverse osmosis (RO) components. The production capacity of WRF is 90,000 m3/day. The reclaimed water is reused as industrial water. We also characterized DOM in raw, processed, and finished waters based on analysis of dissolved organic carbon (DOC), ultraviolet absorbance at 254 nm (UVA254), fluorescence excitation emission matrix (FEEM), and DOC fractions via liquid chromatography-organic carbon detection (LC-OCD). Based on the results of DOC, UVA254, and FEEM analyses, neither the coagulation/sedimentation nor the microfiltration at the WRF effectively removed DOM. The RO process removed more than 94% of DOM. The raw water (i.e., secondary treated effluent obtained from a wastewater treatment plant) exhibited tryptophan-like peaks, which are a promising marker of wastewater, in the FEEM analysis. Coagulation and microfiltration failed to eliminate the wastewater marker, whereas RO completely removed it. The raw water also carried high levels (89.4%) of hydrophilic and low-molecular weight substances, which are difficult to remove via coagulation-sedimentation or microfiltration. Humic substance was a major component of the hydrophilic fractions. Based on the LC-OCD analysis, RO effectively removed the humic and polymeric materials from DOM.

Photoalteration in Biodegradability and Chemical Compositions of Algae- derived Dissolved Organic Matter (자외선에 의한 조류기원 용존유기물의 생분해도 및 화학조성변환.)

  • Imai, Akio;Matsushige, Kazuo;Nagai, Takashi;Kim, Yong-Hwan;Kim, Bom-Chul;Choi, Kwang-Soon
    • Korean Journal of Ecology and Environment
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    • v.36 no.3 s.104
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    • pp.235-241
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    • 2003
  • The effect of ultraviolet (UV) radiation on the characteristics of algae-derived dissolved organic matter (DOM) was examined by comparing the biodegradability and DOM fraction distribution of algal DOM before and after UV exposure. Algal DOM from two axenic cultures of Microcystis aeruginosa and Oscillatoria agardhii were irradiated for 24 h at a UV intensity of 42 W/$m^2$. A complete degradation of algal DOM during the UV exposure did not occur, remaining at constant concentrations of dissolved organic carbon(DOC). After UV exposure, however, microbial degradations were reduced by 17% in M. aeruginosa and 53% in O. agardhii, respectively, and decomposition rates also were two times lower in UV exposed algal DOM. In addition, the chemical compositions of algal DOM altered substantially after UV radiation exposure. The proportions of hydrophilic bases (HiB; protein-like DOM) decreased considerably in both algal DOM sources after UV exposure (16.8% and 20.0% of DOM, respectively), whereas those of hydrophilic acids (HiA; carboxylic acids-like DOM) increased as much as the decrease of the HiB fraction. Capillary ion electrophoresis (CE) analysis showed that several carboxylic acids increased significantly after UV exposure, further confirming an increase in HiA fractions. The results of this study clearly indicate that algal DOM can be changed in its chemical composition as well as biodegradability without complete degradation by UV radiation.

Design and Implementation of DOM Interface for an XML Document Storage System (XML문서저장 시스템을 위한 DOM 인터페이스의 설계 및 구현)

  • 김성욱;정호영;김천식;손기락
    • Proceedings of the Korean Information Science Society Conference
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    • 2000.04b
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    • pp.75-77
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    • 2000
  • 구조적 정보의 표현방법으로 제시된 XML 문서를 가공하고 저장하는 방법에 대한 연구가 활발하게 진행되고 있다. XML을 가공하는 형태로는 몇 가지가 제시되어 일반화 되어있으나 계층적 특성을 가진 XML 문서를 관계형 데이터베이스에 효율적으로 저장하기는 어렵다. 본 연구에서는 XML 문서의 계층 구조를 DFS Numbering 으로 저장하고 데이터베이스에 저장된 문서에 대한 DOM 인터페이스를 효과적으로 제공하는 시스템의 설계 및 구현이다. 문서의 변경 내용을 저장할 때 SQL Query 횟수를 최소화하는 효율적인 기법을 제시한다.

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Extended DOM Interfaces for Spatial Operation in GML (GML문서의 공간연산 처리를 위한 DOM 인터페이스의 확장)

  • Kim, Ho-Seok;Park, Soon-Young;Chung, Won-Il;Bae, Hae-Young
    • Proceedings of the Korea Information Processing Society Conference
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    • 2002.11c
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    • pp.1867-1870
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    • 2002
  • OGC(Open GIS Consortium)에서는 GIS 분야에서 표준포맷을 이용한 공간데이터의 저장 및 상호운용성을 활성화하기 위하여 공간데이터를 XML(eXtensible Markup Language)로 인코팅하는 GML(Geographic Markup Language) 표준 메커니즘을 제안하였다. GML의 공간데이터를 이용하여 공간연산을 하기 위해서는 GML 문서에 접근하여 문서 내에 있는 공간객체를 다룰 수 있는 기능이 필요하다. GML의 기반인 GML에는 이러한 기능을 가진 표준인터페이스인 DOM(Document Obejct Model)이 있으나, GML문서 내의 공간객체에 대한 공간연산을 위한 인터페이스는 지원하지 않는다. 그래서 본 논문에서는 GML 문서의 공간데이터에 대한 공간연산을 위해 XML의 DOM 인터페이스를 확장하는 방안을 제안한다.

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