• Title/Summary/Keyword: DMFC

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Selection of Fuel/Air feeders in BOP system for a DMFC (직접메탄올 연료전지 BOP 시스템에서 연료/공기 공급 장치의 선정)

  • Kim, Ki-Wong;Kim, Seo-Young;Kang, Byung-Ha
    • 한국전산유체공학회:학술대회논문집
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    • 2008.03b
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    • pp.248-251
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    • 2008
  • The objective of this study is to select fuel/air feeders for reliable operation of BOP(Balance of Plant) system for a DMFC (direct methanol fuel cell). A 42-cell 50W DMFC stack is considered for performance comparison of selected fuel pumps and air blowers. The present stack has two serpentine anode channels with depth of 1.2 mm and rib of 1 mm and one serpentine cathode channel with depth of 1.5 mm and rib of 1 mm. The pressure drop through the stack is estimated in advance by utilizing the pre-existing loss coefficients data for various flow configurations. Then the operating points of feeders are determined at the balance point of the flow impedance curves for the channels in the DMFC stack and the selected pump and blower performance curves. After estimating the operating flow rates in the anode and cathode channels, the flow measurement with the selected feeders is performed for the comparison with the estimated flow rates. The measured results show that the discrepancy between the estimation and the measurement for the cathode is about 26%, about 3% for the anode

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Development of Lightweight DMFC System for Charging Secondary Battery in Military Operational Environment (군 운용환경에서 이차전지 충전을 위한 경량화 DMFC 시스템 개발)

  • LEE, SUWON;GWAK, GEONHUI;RO, JUNGHO;CHO, YOUNGRAE;KIM, DOYOUN;JU, HYUNCHUL
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.5
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    • pp.481-491
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    • 2017
  • In this study, we developed 300 W lightweight DMFC system for charging secondary battery in small unit military operation. In order to reduce the volumetric shape and weight of the system considering the environment of the individual soldier's, the arranging of system components has been optimized. A metal bipolar plates made of STS-470FC have been implemented to the DMFC stack to meet the weight demand of the system. As a result of the performance test of the stack, the target value was satisfied by outputting 561 W exceeding 24% of the stack output 450 W required to output 300 W required for the entire system. Moreover, 2,655 hours exceeding 1,000 hours also has been satisfied. To ensure good robustness of the metallic bipolar plate based DMFC stack, finite element method based simulations are conducted using a commercial ANSYS Fluent software.

Relationship between the Thickness of Micorporous Layer and the Flow of Fuel at the Anode GDL of DMFC (DMFC의 연료극에서 GDL의 Microporous layer의 두께와 연료흐름과의 관계)

  • Lee, Eun-Suk;Yang, Kyoung-Hun;Lim, Jong-Man
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.474-476
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    • 2006
  • 본 연구에서는 다양한 두께, loading 및 기공 구조를 갖는 MPL을 형성하여 DMFC용 확산층을 제조하였다. 본 실험에서 제조한 확산층의 경우, 두께가 증가하면서 기공이 micro-pore에서 meso-pore 영역으로 옮겨감을 확인할 수 있었으며, 또한 기공구조에 따라 공기 투과도 특성이 변화하는 것을 확인할 수 있었다 각각의 확산층은 서로 다른 운전 조건에서 우수한 성능(흑은 안정적인 성능)을 갖는 것으로 확인되었으며, 이는 용도에 따른 확산층의 적합한 구조 설계가 요구됨을 의미한다.

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Analytical polarization curve of DMFC anode

  • Kulikovsky, A.A.
    • Advances in Energy Research
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    • v.1 no.1
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    • pp.35-52
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    • 2013
  • A model for DMFC anode performance is developed. The model takes into account potential--independent methanol adsorption on the catalyst surface, finite rate of proton transport through the anode catalyst layer (ACL), and a potential loss due to methanol transport in the anode backing layer. An approximate analytical half--cell polarization curve is derived and equations for the anode limiting current density are obtained. The polarization curve is fitted to the curves measured by Nordlund and Lindbergh and parameters resulted from the fitting are discussed.

Development of hybrid system with fuel cell and lithium secondary battery (연료전지와 리튬 이차전지의 하이브리드 시스템 개발)

  • Hwang, Sangmoon;Jung, Eunmi;Son, Dongun;Shim, Taehee;Song, Hayoung
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.143.2-143.2
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    • 2010
  • Therefore, with this development assignment we'd like to develop the hybrid system combining 800W DMFC (Direct Methanol Fuel Cell) and 1.6kW of Lithium secondary battery pack which can be applied to the most common small cart. a scooter, to secure the development capability of hundreds of Watts DMFC, the high-capacity Lithium secondary battery pack, the technology of BMS (Battery Management System) and the development technology of hybrid system. DMFC, in fact, has lower energy efficiency than PEMFC (Polymer Electrolyte Membrane Fuel Cell); however, it has several advantages in terms of fuel storage and use. It is pretty easy to be stored and used without any additional colling and heating devices because of its insensitive liquid methanol to temperature. In conclusion, DMFC system is the most suitable device for small mobile vehicles.

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The fabrication of electrode and characterization of performance in the PEMFC (고분자 연료전지의 전극 제조 및 성능 평가)

  • Park In-Su;Cho Yonghun;Choi Baeckbeom;Jung Daesik;Cho Yoonhwan;Sung Yung-Eun
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.227-230
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    • 2005
  • There is a worldwide interest In the development and commercialization of PEMFCs for vehicular and stationary applications. The major problem in the practical use of PEMFCs is the deactivation of the Pt anode electrocatalyst by the adsorption of carbon monoxide. Therefore, intensive work has been devoted to finding electrocatalysts that are tolerant to CO in hydrogen at operating temperatures bellow $100^{\circ}C$. Also, DMFC is considered to be one of the most promising technologies for energy generation. But, the most important problem associated with the DMFC is the slow reaction rate of methanol oxidation and the second major problem is fuel crossover. So, the performance of a state-of-the-art DMFC is considerably lower than that of hydrogen-fuelled PEMFC. In this research, the preparation and characterization of electrode materials will be introduced. Also, some electrochemical techniques for the characterization of PEMFCs will be presented.

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Development of portable DMFC systems (휴대용 직접 메탄올 연료전지 시스템 개발)

  • Moon, Go-Young;Kim, Hyuk;Yoo, Hwang-Chan;Noh, Tae-Geun;Lee, Won-Ho
    • New & Renewable Energy
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    • v.3 no.1 s.9
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    • pp.46-53
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    • 2007
  • Direct Methanol Fuel Cell, DMFC is a potential power source for portable IT application. DMFC works at low temperature ($<100^{\circ}C$) without fuel processing. Methanol has high energy density, fuel economy, and easiness to handle. This paper focuses high efficient catalyst to increase utilization in the electrode, new membrane reducing methanol crossover, new material parts, and optimization of system integration. Lightweight and small-sized DMFC based on new materials, efficient stack, and improved system control will be applied to the 50W prototype system for the notebook computer.

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Development of methanol resistance catalysts for DMFC cathodes (Methanol에 저항성을 가진 DMFC용 cathode catalyst의 개발)

  • Oh, Jong-Gil;Kim, Han-Sung
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.204-207
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    • 2007
  • DMFC(direct methanol fuel cell)는 액체연료의 이동과 저장의 용이성 때문에 이동용 장치를 위한 전원공급 장치로서 오랫동안 관심을 받아왔다. 하지만 methanol crossover는 DMFC의 상용화 이전에 해결해야 할 문제이다. 이를 위해 많은 분야에서 연구가 진행되고 있고, 그중에서 methanol에 저항성을 가진 촉매의 개발에 활발히 연구가 진행되고 있다. 본 연구에서는, 표연개질 된 PtCo/C 촉매를 사용하여 메탄올에 저항성을 가진 촉매를 합성하였다. 합성된 촉매의 size와 morphology를 알아보기 위해 transmission electron microscopy (TEM)를 사용하였다. 또한 methanol 존재 하에 산소환원반응의 activity를 알아보기 위해 Rotating ring disk electrode(RRDE) test를 하였고, MEA를 제작하여 full cell test도 병행하였다.

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Current Status and Roles of Proton Exchange Membrane in Direct Methanol Fuel Cell Systems (직접메탄올연료전지 시스템에서의 수소이온고분자전해질막의 역할 및 현황)

  • Kim, Hae-Kyoung
    • Journal of the Korean Electrochemical Society
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    • v.12 no.3
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    • pp.219-233
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    • 2009
  • Mobile devices in the next generation such as camera, cell phone, network, Note PC, etc. require higher power and energy sources due to convergences of various functions. Direct methanol fuel cell (DMFC) has been focused as an attractive power source, but there are critical issues involved in its commercialization with regard to the core technologies of materials, components, and system. The requirements of key technologies are differentiated from applications and fuel supply methods. Here, the roles of the proton-conducting membrane are discussed and the current status of DMFC systems is discussed in terms of proton conductivity, methanol permeability, and water management. Materials such as perfluorinated and partially fluorinated membranes, hydrocarbon membranes, composite membranes, and other modified ionomers have been studied. These would explain the critical issues of DMFC and the role of membranes for commercialization.

Battery charging device using DMFC for an electric bicycle (DMFC를 사용한 전기자전거 배터리 충전장치)

  • Kim, Young-Ho;Ji, Young-Hyok;Kim, Jae-Hyung;Won, Chung-Yuen;Kim, Young-Real
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2008.05a
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    • pp.255-258
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    • 2008
  • In this paper, the battery charging device using DMFC(Direct Methanol Fuel Cell) for electric bicycle is proposed. In the proposed system, phase-shift full-bridge converter is used as a battery charger by boosting the 12V DMFC output voltage up to 36V. By using the phase-shift technique, the ringing of the transformer is reduced and the efficiency of the converter can be improved. The operation modes of proposed phase-shift full-bridge converter is analyzed and verified by the simulation and the experimental results.

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