• 공업화학
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• 제17권3호
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• pp.274-279
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• 2006

해중합 촉매인 zinc acetate ($C_{4}H_{6}O_{4}Zn{\cdot}2H_{2}O{\cdot}0.2\;mol$)와 lithuium hydroxide $H_{2}O$ ($LiOH{\cdot}H_{2}O{\cdot}0.14\;mol$)를 용매인 ethyl alcohol (99.9%)에 용해시킨 후 분산제인 hydroxypropyl cellulose (HPC)를 첨가하여 균일하게 분산된 ZnO (산화아연) 콜로이드 용액을 졸-겔법을 이용하여 합성하였다. ZnO 입자들의 크기와 모양은 분산제인 HPC에 의해 결정되었다. 또한 나노 크기의 ZnO 입자들은 zinc-2-ethylhexagonate를 기초로 한 침천법을 이용하여 얻었다. 이렇게 얻어진 ZnO 분말을 DLS, XRD, FE-SEM, 그리고 UV-Vis를 통하여 특성 분석을 하였다. 그 결과, 산화아연 분말은 자기조립 반응으로 균일하고 육방정계 모양의 구조를 가지는 것을 볼 수 있었다. 또 평균 입자 크기는 거의 40 nm이고 균일하게 분산되었다.

• Journal of Electrochemical Science and Technology
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• 제8권1호
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• pp.7-14
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• 2017

This study aims to examine the influences of substrates/diffusion layers (DL) and oxygen reduction reaction catalysts ($M_{ORR}$) on the performance of $M_{ORR}/IrO_2$/DL-type bifunctional oxygen electrodes for use in polymer electrolyte membrane (PEM)-type unitized regenerative fuel cells (URFC). The $M_{ORR}/IrO_2$/DL electrodes were prepared via two sequential steps: anodic electrodeposition of $IrO_2$ on various DLs and fabrication of $M_{ORR}$ layers (Pt, Pd, and Pt-Ru) by spraying on $IrO_2/DL$. Experiments using different DLs, with Pt as the $M_{ORR}$, revealed that the roughness factor of the DL mainly determined the electrode performance for both water electrolyzer (WE) and fuel cell (FC) operations, while the contributions of porosity and substrate material were insignificant. When Pt-Ru was utilized as the $M_{ORR}$ instead of Pt, WE performance was enhanced and the electrode performance was assessed by analyzing round-trip efficiencies (${\varepsilon}_{RT}$) at current densities of 0.2 and $0.4A/cm^2$. As a result, using Pt-Ru instead of Pt alone provided better ${\varepsilon}_{RT}$ at both current densities, while Pd resulted in very low ${\varepsilon}_{RT}$. Improved efficiency was related to the additional catalytic action by Ru toward ORR during WE operation.

• Earthquakes and Structures
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• 제9권3호
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• pp.481-501
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• 2015

Current design codes and technical recommendations often provide rough indications on how to assess effective stiffness of Reinforced Concrete (R/C) frames subjected to seismic loads, which is a key factor when a linear analysis is performed. The Italian design code (NTC-2008), Eurocode 8 and ACI 318 do not take into account all the structural parameters affecting the effective stiffness and this may not be on the safe side when second-order $P-{\Delta}$ effects may occur. This paper presents a study on the factors influencing the effective stiffness of R/C beams, columns and walls under seismic forces. Five different approaches are adopted and analyzed in order to evaluate the effective stiffness of R/C members, in accordance with the scientific literature and the international design codes. Furthermore, the paper discusses the outcomes of a parametric analysis performed on an actual R/C building and analyses the main variables, namely reinforcement ratio, axial load ratio, concrete compressive strength, and type of shallow beams. The second-order effects are investigated and the resulting displacements related to the Damage Limit State (DLS) under seismic loads are discussed. Although the effective stiffness increases with steel ratio, the analytical results show that the limit of 50% of the initial stiffness turns out to be the upper bound for small values of axial-load ratio, rather than a lower bound as indicated by both Italian NTC-2008 and EC8. As a result, in some cases the current Italian and European provisions tend to underestimate second-order $P-{\Delta}$ effects, when the DLS is investigated under seismic loading.

• Macromolecular Research
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• 제15권5호
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• pp.437-442
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• 2007

Poly(ethylene glycol) methyl ether (PEG)-poly(${\beta}$-amino ester) (PAE) block copolymers were synthesized using a Michael-type step polymerization, and the construction of pH-sensitive polymeric micelles (PM) investigated. The ${\beta}$-amino ester block of the block copolymers functioned as a pH-sensitive moiety as well as a hydrophobic block in relation to the ionization of PAE, while PEG acted as a hydrophilic block, regardless of ionization. The synthesized polymers were characterized using $^1H-NMR$, with their molecular weights measured using gel permeation chromatography. The $pK_b$ values of the pH-sensitive polymers were measured using a titration method. The pH-sensitivity and critical micelle concentration (CMC) of the block copolymers in PBS solution were estimated using fluorescence spectroscopy. The pH dependent micellization behaviors with various bisacrylate esters varied within a narrow pH range. The critical micelle concentration at pH 7.4 decreased from 0.032 to 0.004 mg/mL on increasing the number of methyl group in the bisacrylate from 4 to 10. Also, the particle size of the block copolymer micelles was determined using dynamic light scattering (DLS). The DLS results revealed the micelles had an average size below 100 nm. These pH-sensitive polymeric micelles may be good carriers for the delivery of an anticancer drug.

• 한국응용과학기술학회지
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• 제38권4호
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• pp.1176-1182
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• 2021

본 연구에서는 유화안정제 중 하나인 cetyl alcohol 함량에 따른 천연 염모제 헤나의 유화 안정성을 분석하고 가장 안정한 유화를 나타내는 cetyl alcohol 함량을 확인하였다. 유화 안정성을 분석하기 위해 cetyl alcohol의 함량에 따른 입자 크기, 입자 형태, 점도 및 염색 후 색상의 차이를 비교하였다. Dynamic light scattering (DLS) zeta 분석 결과, cetyl alcohol 3 % 가 zeta potential 값이 115.9 mV로 가장 높은 값을 보였으며, 입자크기분포는 cetyl alcohol의 함량이 3 %인 크림 제형 염모제가 증류수에 분산된 헤나와 비교해 입도분포의 폭이 좁았다. 점도계 분석 결과 cetyl alcohol의 함량이 증가할수록 점도가 증가하였고, 크림 제형의 헤나 pH 측정 결과 두피에 적합한 pH 범위로 측정되었다. 또한 헤나 크림 제형 염모제에서는 cetyl alcohol의 함량이 증가할수록 유화 안정성이 증가하였다.

• 한국가스학회지
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• 제27권1호
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• pp.23-32
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• 2023

본 연구에서는 고갈된 가스전의 사암 저류층 또는 심부 대염수층 내 이산화탄소(CO₂) 주입효율 및 저장용량 증진을 위한 주입 첨가제로써 Al₂O₃ 나노유체를 합성하였다. 기반 유체로 탈이온수(deionized water, DIW)와 API Brine의 조성을 참고하여 제조한 염수를 사용하였으며, 양이온성 계면활성제인 CTAB (cetyltrimethyl-ammonium bromide)을 첨가한 Al₂O₃ 나노유체를 이용하여 유체를 합성하였다. 육안관찰, 동적광산란광도계(dynamic light scattering, DLS), 전자투과현미경(transmission electron microscope, TEM), 혼화성 시험(miscibility test)의 방법을 활용한 유체의 분산 안정성 평가 결과, 나노입자 농도가 0.05 wt% 이하 조건에서 70,000 ppm의 염수와 반응 후에도 응집 및 침전되지 않는 안정한 유체를 합성할 수 있음을 확인하였다.

• 한국비블리아학회지
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• 제20권4호
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• pp.85-100
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• 2009

본 연구는 교사와 학생들이 가르치고 배우는 상황 즉, 교육적 맥락을 고려하여 학교도서관의 목록 서비스를 제공한다면 목록의 유용성을 높이고, 교수-학습 과정과 목록 서비스를 직접적으로 연계시킬 수 있다는 전제하에 교육적 맥락에 관한 정보를 목록 데이터 요소에 추가로 목록 정보를 확장하기 위한 방안을 제시하였다. 우선 학교도서관의 정보자료와 교육 즉, 교수-학습 과정에 관련된 맥락 요인을 분석하고, 실제로 교육적 맥락 요소를 제공하고 있는 정보 시스템의 사례를 분석하여 교육적 맥락을 고려한 목록 정보의 확장 방안을 제시하였다. 분석 결과를 바탕으로 학교도서관 목록(DLS)에 추가로 기술해야 할 교육적 맥락 요소를 이용자(학생, 교사), 수업상황(교수방법, 수업목표, 교육과정, 평가방법, 학습집단 편성, 준비물, 수업환경), 자료 내용 유형(성격, 학문분야, 형태), 독서 상황(상황별 독서, 문학 주제), 관련 자료(교사 표현물, 학생 표현물) 등 5개 요소로 추출하였다.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2002년도 ITC-CSCC -1
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• pp.220-223
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• 2002

The digital logic systems(DLS) is classified into digital combinational logic systems(CDLS) and digital sequential logic systems(SDLS). This paper presents a method of constructing the digital sequential logic systems without feedback. Firstly we assign all elements in Finite Fields to P-valued digit codes using mathematical properties of Finine Fields. Also, we discuss the operarional properties of the building block T-gate that is used to realizing digital sequential logic systems over Finite Fields. Then we realize the digital sequential logic systems without feedback. This digital sequential logic systems without feedback is constructed ny following steps. Firstly, we assign the states in the state-transition diagram to state P-valued digit dodo, then we obtain the state function and predecessor table that is explaining the relationship between present state and previous states. Next, we obtained the next-state function and predecessor table. Finally, we realize the circuit using T-gate and decoder.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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• pp.651-651
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• 2013

Templated strategy is a very powerful tool for creating multi-dimensional self assembly of nanomaterials. Since viral protein cages have a uniform size with a well-defined structure, they can serve as an excellent template for the formation of a three-dimensional self-assembly of synthetic nanoparticles. In this study, we have examined the feasibility of the 3D self-assembly of gold nanoparticles of various sizes using a brome mosaic virus (BMV) capsid with cysteine groups expressed on its surface as a scaffold for the assembly. It was found that the three-dimensional clusters of gold nanoparticles with a designed structure were attainable by this approach, which was verified by transmission electron microscope (TEM) and dynamic light scattering (DLS) analysis.

• Advances in materials Research
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• 제3권2호
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• pp.117-128
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• 2014

Processable conducting polyaniline derivative with free amine functional groups was successfully synthesized from the monomer o-phenylenediamine in aqueous hydrochloric acid medium using ammonium persulfate as an oxidative initiator. The synthesized poly(o-phenylenediamine) (PoPD) in critical condition was found to be completely soluble in common organic solvents like dimethyl sulfoxide, N,N-dimethyl formamide etc. From the intrinsic viscosity measurement, the optimum condition for the polymerization was established. The polymer was characterized by ultraviolet visible spectroscopy, Fourier transform infrared spectroscopy, proton magnetic resonance spectroscopy ($^1HNMR$) and thermogravimetric (TGA) analyses. The weight average molecular weights of the synthesized polymers were determined by the dynamic light scattering (DLS) method. From the spectroscopic analysis the structure was found to resemble that of polyaniline derivative with free amine functional groups attached to ortho/meta position in the phenyl ring. However, very little ladder unit was also present with in the polymer chain. The moderate thermal stability of the synthesized polymer could be found from the TGA analysis. The average DC conductivity of $2.8{\times}10^{-4}S/cm$ was observed for the synthesized polymer pellet after doping with hydrochloric acid.