• 제목/요약/키워드: DET

검색결과 138건 처리시간 0.026초

다양한 구조 유도제로 합성된 SAPO촉매를 이용한 자일로오스의 탈수화반응 (Dehydration of D-xylose over SAPO Catalysts Synthesized with Various Structure Directing Agents)

  • 김샛별;유수진;김용태;채호정;정순용;박은덕
    • Korean Chemical Engineering Research
    • /
    • 제48권6호
    • /
    • pp.684-689
    • /
    • 2010
  • 본 연구에서는 다양한 구조 유도제로 합성된 SAPO촉매를 이용하여 자일로오스의 탈수화 반응을 진행하였다. 구조 유도제로는 테트라에틸암모늄수산화물(TEAOH), 디프로필아민(DPA), 디에틸아민(DEA), 몰포린(Morpholine) 그리고 디에탄올아민(DEtA)을 사용하였다. 촉매의 특성을 파악하기 위하여 질소 흡착-탈착 등온선, 암모니아 승온탈착($NH_3$-TPD), 그리고 승온산화분석(TPO)을 이용하였다. 구조 유도제로 몰포린(Morpholine)을 사용하여 제조한 SAPO-34를 촉매로 사용하였을 경우 사용한 촉매중에서 푸르푸랄 수율이 가장 높았다. 고체산 촉매의 외부 표면적과 산농도가 자일로오스의 탈수화 반응에 영향을 주는 것으로 나타났다.

다섯자리 Schiff Base Molybdenum(Ⅴ) 착물들의 합성과 비수용매에서의 전기화학적 성질 (Synthesis of Pentadentate Schiff Base Molybdenum(Ⅴ) Complexes and Their Electrochemical Properties in Aprotic Solvents)

  • 김선숙;최주형;최용국;정병구
    • 대한화학회지
    • /
    • 제38권2호
    • /
    • pp.160-168
    • /
    • 1994
  • 다섯자리 Schiff base의 molybdenum(Ⅴ)착물로써 [Mo(Ⅴ)O(Sal-DET)(NCS)] 와 [Mo(Ⅴ)O(Sal-DPT)(NCS)]들을 Sabat법에 의해 합성하였다. 이들 착물들의 원소분석, IR-spectrum, UV-Vis spectroscopy 및 Thermogravimetric analysis(T.G.A.)곡선으로부터 리간드 대 금속의 몰비가 1:1착물임을 확인하였다. 0.1M tetraethyl ammonium perchlorate(TEAP)지지전해질을 포함한 비수용매에서 순환 전압-전류법과 시차펄스 폴라그래피에 의한 전기화학적 측정으로부터 이들 착물들은 dimer로 형성된 후, 일전자 전이의 확전자 전이의 확산지배적인 환원과정이 다음과 같이 네단계로 진행됨을 알았다. 2Mo(Ⅴ)$\rightleftarrow^{e-}$ Mo(Ⅴ)Mo(Ⅳ) $\longrightarrow^{e-}$ 2Mo(Ⅳ), Mo(Ⅳ)$\longrightarrow^{e-}$ Mo(Ⅲ) $\longrightarrow^{e-}$ Mo(Ⅱ)

  • PDF

음향 방출 신호와 히스토그램 모델링을 이용한 유도전동기의 베어링 결함 검출 (Bearing Faults Identification of an Induction Motor using Acoustic Emission Signals and Histogram Modeling)

  • 장원철;서준상;김종면
    • 한국컴퓨터정보학회논문지
    • /
    • 제19권11호
    • /
    • pp.17-24
    • /
    • 2014
  • 본 논문에서는 저속으로 회전하는 유도 전동기의 베어링 결함을 검출하기 위해 음향 방출 신호와 히스토그램 모델링을 이용하는 방법을 제안한다. 제안한 방법은 정규화된 결함 신호가 구성하는 히스토그램의 포락선을 모델링하여, 부분 상관 계수와 DET(Distance Evaluation Technique) 기법을 이용하여 결함 유형별 고유한 특징을 추출 및 선택한다. 추출된 특징을 SVR(Support Vector Regression) 분류기의 입력으로 사용하여 베어링의 내륜, 외륜 및 롤러 결함을 분류한다. 최적의 분류 성능을 위해 SVR 커널함수의 매개변수를 0.01에서 1.0까지 변화시키고, 특징 개수는 2에서 150까지 변화시키면서 실험한 결과, 0.64-0.65의 매개변수와 75개의 특징 개수에서 제안한 방법은 약 91%의 분류 성능을 보였고, 또한 기존의 결함 분류 알고리즘보다 높은 분류 성능을 보였다.

GAUSS SUMS FOR U(2n + 1,$q^2$)

  • Kim, Dae-San
    • 대한수학회지
    • /
    • 제34권4호
    • /
    • pp.871-894
    • /
    • 1997
  • For a lifted nontrivial additive character $\lambda'$ and a multiplicative character $\chi$ of the finite field with $q^2$ elements, the 'Gauss' sums $\Sigma\lambda'$(tr $\omega$) over $\omega$ $\in$ SU(2n + 1, $q^2$) and $\Sigma\chi$(det $\omega$)$\lambda'$(tr $\omega$) over $\omega$ $\in$ U(2n + 1, $q^2$) are considered. We show that the first sum is a polynomial in q with coefficients involving certain new exponential sums and that the second one is a polynomial in q with coefficients involving powers of the usual twisted Kloosterman sums and the average (over all multiplicative characters of order dividing q-1) of the usual Gauss sums. As a consequence we can determine certain 'generalized Kloosterman sum over nonsingular Hermitian matrices' which were previously determined by J. H. Hodges only in the case that one of the two arguments is zero.

  • PDF

Human Detection 을 위한 Bayesian Logistic Regression (Bayesian Logistic Regression for Human Detection)

  • ;;이칠우
    • 한국HCI학회:학술대회논문집
    • /
    • 한국HCI학회 2008년도 학술대회 1부
    • /
    • pp.569-572
    • /
    • 2008
  • The possibility to extent the solution in human detection problem for plug-in on vision-based Human Computer Interaction domain is very attractive, since the successful of the machine leaning theory and computer vision marriage. Bayesian logistic regression is a powerful classifier performing sparseness and high accuracy. The difficulties of finding people in an image will be conquered by implementing this Bavesian model as classifier. The comparison with other massive classifier e.g. SVM and RVM will introduce acceptance of this method for human detection problem. Our experimental results show the good performance of Bavesian logistic regression in human detection problem, both in trade-off curves (ROC, DET) and real-implementation compare to SVM and RVM.

  • PDF

선박간 이격거리에 따른 WIND SHIELDING EFFECT 검토 (The Study on Wind Shielding Effects According to Distance Between Two Ships)

  • 구명준;하문근;최재웅;배준홍
    • 대한기계학회:학술대회논문집
    • /
    • 대한기계학회 2004년도 추계학술대회
    • /
    • pp.1413-1417
    • /
    • 2004
  • The environmental elements which naturally occur can result in structural damages and operating faults of vessels under the navigation and mooring. These primary factors are considered as wind, waves and tide. In order to investigate wind shielding effects with respect to wind load conditions between two ships which face the wind directly or slantingly to the wind direction, this numerical simulation was preferred in terms of the variation of wind loads according to different distances, wind velocities and wind directions between two ships. The results were proved to be quite reasonable, comparing with experimental data from Danish Maritime Institute, and the report, "Environmental Conditions And Environmental Loads" published by Det Norske Veritas.

  • PDF

GTT.NO 96 멤브레인형 170K ICE-1A급 천연액화가스 운반선 개발 (Development of a GTT NO96 Membrane Type 170K $m^3$ LNG Carrier with Ice Class IA)

  • 오영태;한성곤;유인상;엄항섭
    • 대한조선학회 특별논문집
    • /
    • 대한조선학회 2009년도 특별논문집
    • /
    • pp.6-17
    • /
    • 2009
  • The present paper addresses development of a GTT NO96 membrane type 170K m3 LNG carrier targeted to operate in moderate ice infested seas including Baltic Sea, Sakhalin port of Sea of Okhotsk, Murmansk port of Barents Sea, etc. Critical design issues are covered in detail to meet the requirements coming from the missioned operation conditions comprising low design ambient temperature, harsh wave conditions, stringent environmental protection policies, etc.

  • PDF

MPMD 방식의 동기/비동기 병렬 혼합 멱승법에 의한 거대 고유치 문제의 해법 (A Synchronous/Asynchronous Hybrid Parallel Power Iteration for Large Eigenvalue Problems by the MPMD Methodology)

  • 박필성
    • 정보처리학회논문지A
    • /
    • 제11A권1호
    • /
    • pp.67-74
    • /
    • 2004
  • 대부분의 병렬 알고리즘은 동기 알고리즘으로, 올바른 계산을 위해 작업을 일찍 끝낸 빠른 프로세서들은 동기점에서 느린 프로세서를 기다려야 하는데, 프로세서들의 성능이 다를 경우 연산 속도는 가장 느린 프로세서에 의해 결정된다. 본 논문에서는 거대 고유치 문제의 주요 고유쌍을 구하는 문제에 있어서 빠른 프로세서의 유휴 시간을 줄여 수렴 속도를 가속한 수 있는 동기/비동기 혼합 알고리즘을 고안하고 이를 MPMD 프로그래밍 방식을 사용하여 구현하였다.

Modeling of non-isothermal CO2 particle leaked from pressurized source: I. Behavior of single bubble

  • Chang, Daejun;Han, Sang Heon;Yang, Kyung-Won
    • Ocean Systems Engineering
    • /
    • 제2권1호
    • /
    • pp.17-31
    • /
    • 2012
  • This study investigated the behavior of a non-isothermal $CO_2$ bubble formed through a leak process from a high-pressure source in a deep sea. Isenthalpic interpretation was employed to predict the state of the bubble just after the leak. Three modes of mass loss from the rising bubble were demonstrated: dissolution induced by mass transfer, condensation by heat transfer and phase separation by pressure decrease. A graphical interpretation of the last mode was provided in the pressure-enthalpy diagram. A threshold pressure (17.12 bar) was identified below which the last mode was no longer present. The second mode was as effective as the first for a bubble formed in deep water, leading to faster mass loss. To the contrary, only the first mode was active for a bubble formed in a shallow region. The third mode was insignificant for all cases.

Modeling of non-isothermal CO2 particle leaked from pressurized source: II. Behavior of single droplet

  • Chang, Daejun;Han, Sang Heon;Yang, Kyung-Won
    • Ocean Systems Engineering
    • /
    • 제2권1호
    • /
    • pp.33-47
    • /
    • 2012
  • This study revealed the behavior of droplets formed through leak process in deep water. There was a threshold depth named the universal attraction depth (UAD). Droplets rose upward in the zone below the UAD called the rising zone, and settled down in the zone above the UAD called the settling zone. Three mass loss modes were identified and formulated: dissolution induced by mass transfer, condensation by heat transfer and phase separation by pressure decrease. The first two were active for the settling zone, and all the three were effective for the rising zone. In consequence, the life time of the droplets in the rising zone was far shorter than that of the droplets in the settling zone.