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Synthesis and Properties of Anionic Tetrakis(pentafluorophenyl)indium(Ⅲ) Complexes (Tetrakis(pentafluorophenyl)indium(Ⅲ) 음이온 착물의 합성과 특성)

  • Choi, Zel Ho
    • Journal of the Korean Chemical Society
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    • v.43 no.1
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    • pp.52-57
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    • 1999
  • The anionic complexes, [ln($C_6F_5)_4$]-, which are thermal and moisture sensitive, have been prepared by the reaction of In($C_6F_5)_3{\cdot}D(D=CH_3CN$, O($C_2H_5)_2$) with the system ($CH_3)_3SiC_6F_5$/CsF, $C_6F_5$MgBr or Cd($C_6F_5)_2$. The stable anionic indium(III) complexes are obtained through cation exchange with PNPCI ([PNP]= bis(triphenylphosphino)ammonium). The pure substance is obtained by column chromatography. These new anionic complexes are unambiguously identifed by NMR-spectroscopy, IR spectroscopy, molecular weight, DTA/TG and elemental analysis.

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The R & D of SiC Fiber Reinforced Composites for Energy and Transportation Applications

  • Kohyama, Akira
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2006.11a
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    • pp.5-13
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    • 2006
  • Based on the inventions of continuous ceramic fibers, such as C, SiC, $Al_2O_3$ etc., by polymer precursor driven methods, there have been many efforts to fabricate ceramic continuous fiber reinforced composite materials with metals and ceramics matrices. The main purpose of the R & D efforts has been to produce materials for severe environments, including advanced energy systems, advanced transportation systems. The efforts have been started from the R & D of metal matrix composite materials and now the strong emphasis on ceramic matrix composites R & D can be recognized. This paper provides a brief review about the national efforts to establish advanced composite materials for future industries starting from mid 70s. C/Al and SiC/Al are the typical examples to be applied transportation systems and energy systems. The excellences in specific strength and overall mechanical properties, the excellences in environmental resistance make those materials as potential materials for advanced ocean construction and marine transportation systems. About the recent progress in ceramic fiber reinforced ceramic composites, advanced SiC/SiC composites including NITE-SiC/SiC will be introduced and the present status will be introduced.

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Effects of Heat Temperature in Sizing and Pretreatment Processes on the Appearance Colour of the Polyester Fabrics (사이징 및 전처리 공정에서의 열처리 온도 변화에 따른 폴리에스테르 직물의 염색성 변화)

  • Cho, D.H.;Kim, S.J.;Chang, D.H.
    • Textile Coloration and Finishing
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    • v.11 no.2
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    • pp.1-8
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    • 1999
  • 이 연구에서는 사이징 공정을 포함해서 수세, 전처리 그리고 최종 열처리 둥의 염색.가공 공정에서의 습열 및 건열 처리 온도가 폴리에스테르 직물의 열응력과 염색성에 미치는 영향을 조사하였다. 사용된 폴리에스테르 필라멘트사는 경사가 50d/24f 스파크사이며 위사는 75d/72f semi-dull사이다. 평직물은 션틀직기, 주자직물은 water jet 직기로 제직하였으며, sizing dryer 온도는 $90^\circ{C}$, $125^\circ{C}$, $150^\circ{C}$, 수세공정의 습열처리 온도는 $90^\circ{C}$, $110^\circ{C}$, $120^\circ{C}$, 전처리 공정의 건열처리 온도는 $180^\circ{C}$, $200^\circ{C}$, $220^\circ{C}$, 마지막 세팅 공정의 건열처리 온도는 $170^\circ{C}$, $180^\circ{C}$, $200^\circ{C}$로 변화시켰다. 이들 습열과 건열처리 온도 변화에 따른 직물내의 필라멘트사의 열 수축률과 직물의 겉보기 염색성의 변화를 조사 분석하였다.

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Effects of Water Temperature and Photoperiod on the Oxygen Consumption Rate of Juvenile Dark-banded Rockfish, Sebastes inermis (수온과 광주기에 따른 볼락, Sebastes inermis 치어의 산소 소비율)

  • Oh Sung-Yong;Noh Choong-Hwan
    • Journal of Aquaculture
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    • v.19 no.3
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    • pp.210-215
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    • 2006
  • An experiment was conducted to investigate the effects of four water temperatures (10, 15, 20, and $25^{\circ}C$) in combination with three photoperiods (24L:0D, 12L: 12D, and OL:24D) on the oxygen consumption rate of juvenile dark-banded rockfish, Sebastes inermis (mean body weight $20.5{\pm}0.7g$). The oxygen consumption rates of S. inermis were measured in triplicate for 24 hours using a continuous flow-through respirometer. Different combinations of water temperatures and photoperiods resulted in significant differences in the mean oxygen consumption rate of S. inermis (P<0.001). The oxygen consumption increased with increasing water temperatures for all photoperiod treatments (P<0.01). Mean oxygen consumption rates at 10, 15,20 and $25^{\circ}C$ ranged $178.3\sim283.5,\;386.7\sim530.7,\;529.2\sim754.3$ and $590.0\sim785.5mg\;O_2kg^{-1}h^{-1}$, respectively. $Q_{10}$ values ranged $3.17\sim5.51$ between 10 and $15^{\circ}C,\;1.87\sim2.10$ between 15 and $20^{\circ}C$ and $1.08\siml.24$ between 20 and $25^{\circ}C$, respectively. Fish held in continuous darkness (OL:24D) used consistently less okygen than fish exposed to continuous light (P<0.05). The mean oxygen consumption offish in a 12L:12D photoperiod was higher than that offish in 24L:0D and 0L:24D photoperiods under all temperature treatments except $10^{\circ}C$. The oxygen consumption of fish exposed to the 12L:12D photoperiod was significantly higher during the light phase than during the dark phase under all temperature treatments except $10^{\circ}C\;(P<0.05)$. This study provides empirical data for estimating oxygen consumption of S. inermis under given condition. This result has application for culture management and bioenergetic model for growth of this species.

Optimum Lactose: Sucrose Ratio for the Pigs Weaned at 21 Days of Age

  • Jin, C.F.;Kim, J.H.;Han, In K.;Yeon, J.U.
    • Asian-Australasian Journal of Animal Sciences
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    • v.11 no.2
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    • pp.185-191
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    • 1998
  • A total of 240 weaned pigs (BW 5.4 kg) were allotted in a completely randomized block design to find out the optimum lactose : sucrose ratio for the weaned pigs. Treatments were 100:0 (A), 75:25 (B), 50:50 (C), 25:75 (D) and 0:100 (E) in lactose : sucrose ratio. For the first week after weaning, average daily gain (ADG) and feed/gain (F/G) were improved (p < 0.05) for pigs fed A, B and C diets compared to pigs fed diets D and E, but the average daily feed intakes (ADFI) of the pigs were not different. From d 7 to 14, no significant differences was found in ADG and ADFI among the treatments, but pigs fed the diets A, B and C had improved F/G compared with the pigs fed diets D and E (p < 0.05). From d 15 to 21, no significant differences were found in ADG, ADFI and F/G among the treatments. The digestibility of nutrients was not influenced by the lactose : sucrose ratio except nitrogen. Nitrogen digestibility of A diet was significantly higher than D and E diets (p < 0.05) but no significant differences were found among diets A, B and C. Dry matter and phosphorus excretions were not influenced by the treatments. The pigs fed diets A, B and C excreted significantly less nitrogen than the pigs fed diets D and E. In conclusion, the results suggest that sucrose can effectively replace up to 50% lactose in starter diets.

Effect of Water Temperature and Photoperiod on the Oxygen Consumption Rate of Juvenile Pacific Cod Gadus macrocephalus (대구 Gadus macrocephalus 치어의 산소 소비율에 미치는 수온과 광주기의 영향)

  • Oh, Sung-Yong;Park, Heung-Sik;Kim, Chong-Kwan
    • Ocean and Polar Research
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    • v.32 no.3
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    • pp.229-236
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    • 2010
  • A study was conducted to investigate the effect of water temperature and photoperiod on the oxygen consumption of the fasting juvenile Pacific cod Gadus macrocephalus (mean body weight 79.9${\pm}$2.0 g) in order to quantify metabolic response of the species under given conditions. The oxygen consumption rate (OCR) of G. macrocephalus was measured under a combination of four different water temperatures (7, 10, 13 and $16^{\circ}C$) and three different photoperiods (24L:0D, 12L:12D and 0L:24D) with an interval of 5 minutes over a 24-hour period using a closed recirculating respirometer. Three replicates were set up in each treatment. OCRs increased with increased water temperatures under all photoperiod conditions (P<0.001). Mean OCRs at 7, 10, 13 and 16oC ranged from 793.7~1108.4, 1145.7~1570.3, 1352.8~1742.5 and 1458.2~1818.6 mg $O_2$ $kg^{-1}$ $h^{-1}$, respectively. Under all water temperature conditions except $7^{\circ}C$ (P<0.001), mean OCRs of G. macrocephalus were the highest in continuous light (24L:0D) followed by 12L:12D and 0L:24D photoperiods. Mean OCRs of fish exposed to the 12L:12D photoperiod were significantly higher during the light phase than during the dark phase under all temperature conditions (P<0.001). $Q_{10}$ values ranged from 3.19~5.13 between 7 and $10^{\circ}C$, 1.41~1.74 between 10 and $13^{\circ}C$ and 1.15~1.35 between 13 and $16^{\circ}C$, respectively. Based on overall results, water temperature, photoperiod and their combinations exerted a significant influence on the metabolic rate of juvenile cod. This study provides empirical data for estimating the amount of oxygen demand and managing the culture of cod under the given water temperatures and photoperiods.

Effect of droplet length on a burning constant rate of suspended droplet (액적간격이 고정액적의 연소율상수에 미치는 영향에 관한 연구)

  • Han, Jae-Seob;Kim, Seon-Jin;Kim, Yoo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.6 no.1
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    • pp.47-54
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    • 2002
  • This paper presents the results of an experimental investigation on the combustion of single droplets and 1-D droplet arrays of jet A-1 fuel droplets in atmospheric pressure. Experimental results indicate that burning rate constants$({\kappa}_c)$ of jet A-1 fuel droplets were independent of initial droplet size as $0.915{mm}^2$/sec. It was acquired a general relationship expressing the variation of $d^2$ with time for droplet burning For 1-D droplet arrays $(l/d_o$=1.208{\sim}2.922)$/TEX>, the burning rate constant ${\kappa}_c$ decreased with decreasing droplet spacing $l/d_o$ and, The effect on combustion rate constant ${\kappa}_c$ was stronger to second fuel droplet than third fuel droplet with uniform droplet distance

Metamorphism and Deformation of the Late Paleozoic Pyeongan Supergroup in the Taebaeksan Basin: Reviews on the Permo-Triassic Songrim Orogeny (태백산분지에 분포하는 후기 고생대 평안누층군의 변성-변형작용: 페름-삼첩기 송림 조산운동의 고찰)

  • Kim, Hyeong-Soo
    • The Journal of the Petrological Society of Korea
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    • v.21 no.2
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    • pp.151-171
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    • 2012
  • The Permo-Triassic Songrim orogeny in the Korean peninsula was a major tectonic event involving complicated continental collisions at the eastern margin of Eurasia. Based on the previous studies on the metamorphic and deformations features of the Songrim orogeny, this paper presents metamorphic and structural characteristics and timing of the Songrim orogeny in the Taebaeksan basin, and discuss about correlation of the tectono-metamorphic evolution of the Taebaeksan basin with the Okcheon basin and the Imjingang belt with a combined analysis of bulk crustal shortening direction, metamorphic P-T and T-t (time) paths. The metapelites in the Pyeongan Supergroup in the northeastern margin of the Taebaeksan basin have experienced lower-temperature/medium-pressure (LT/MP) regional metamorphism followed by high-temperature contact metamorphism due to the Jurassic granite intrusion. The earlier LT/MP regional metamorphism produced two loops of clockwise P-T-d (deformation) paths combined with four deformation events ($D_1-D_4$). The first loop concomitant with $D_1$ and $D_2$ occurred at $400-500^{\circ}C$, 1.5-3.0 kbar, and related with growth of syn-$D_1$ chloritoid and andalusite, post-$D_1$ margarite, Ca-rich syn-$D_2$ or post-$D_2$ plagioclase. The second loop accompanying $D_3$ and $D_4$ occurred at $520-580^{\circ}C$, 2.0-6.0 kbar, and associated with the growth of syn-$D_3$ garnet and staurolite, and syn-$D_4$ and/or post-$D_4$ andalusite porphyroblasts. Furthermore the syn-$D_1$ chloritoid and andalusite porphyroblasts grew during E-W bulk crustal shortening, whereas the syn-$D_3$ garnet and staurolite, and the syn-$D_4$ and/or post-$D_4$ andalusite porphyroblasts have grown under N-S bulk crustal shortening. The similarity in the characteristics and timing of the metamorphism and bulk crustal shortening directions between the Okcheon and Imjingang belts suggest that the peak metamorphic conditions tend to increase toward the western part (Imjingang belt and southwestern part of the Gyeonggi Massif) from the eastern part (Taebaeksan basin). The E-W bulk crustal shortening influenced the eastern part of the Okcheon belt, whereas the N-S bulk crustal shortening resulted in strong deformation in the Imjingang and Okcheon belts. Consequently, the Permo-Triassic Songrim orogeny in the Korean peninsula is probably not only related to collision of the North and South China blocks, but also to the amalgamation of terrane fragments at the eastern Eurasia margin (e.g., collision of the Sino-Korean continent and the Hida-Oki terrane).

Influence of supplemental canola or soybean oil on milk yield, fatty acid profile and postpartum weight changes in grazing dairy goats

  • Lerma-Reyes, Israel;Mendoza-Martinez, German D.;Rojo-Rubio, Rolado;Mejia, Mario;Garcia-Lopez, J.C.;Lee-Rangel, Hector A.
    • Asian-Australasian Journal of Animal Sciences
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    • v.31 no.2
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    • pp.225-229
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    • 2018
  • Objective: This experiment was designed to evaluate the effect of supplementation with soybean or canola oil on milk production and the composition of long chain fatty acids as well as weight changes in the goats and their kids. Methods: Thirty nine mulitparous crossed Alpine${\times}$Nubian goats (initial body weight [BW] $43.5{\pm}1.7kg$) from the day of parturition were assigned to the treatments: grazing control (n = 15); grazing plus 20 mL/goat/d of supplemental soybean oil (n = 12); and grazing plus 20 mL/goat/d of supplemental canola oil (n = 12) from November 26, 2014 to March 7, 2015. The planned contrasts were: CI (control vs supplemented with oils); CII (soybean vs canola oil) to compare the treatment effects. Results: The vegetable oil supplementation reduced weight losses in lactating goats (CI: -0.060 vs 0.090 kg/d; p = 0.03) but did not improve milk production or affect kids' growth. The content of C4, C6, C8, C10, C11, C14, and C18:1n9t in the milk was increased (p<0.05) with respect to control. However, C12, C14, C16, C18, C18:1n9c, C18:2n6c, and C18:3n3 were reduced (p<0.05) in supplemented goats. Conjugated linoleic acid (CLA) was increased (p<0.05) in goats supplemented with oils compared to the control group. Conclusion: Supplementation with 20 mL/d of soybean or canola oil did not affect milk production or kids' performance; however, it increased CLA concentration and reduced the reduced weight losses in lactating goats.

A Phytochemical Study on Components of Codonopsis pilosulae Radix (만삼의 성분에 관한 연구)

  • 이인란
    • YAKHAK HOEJI
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    • v.22 no.1
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    • pp.1-7
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    • 1978
  • Two yellowish oily liquid compounds, $C_{6}H_{6}O_{3}$(A) bp $189^{\circ}$, $n^{20}_{D}$ 1.3697 and $C_{7}H_{8}O_{3}$(D) bp $164^{\circ}$, $n^{20}_{D}$1.5075, were isolated from root of Codonopsis pilosula (Franch.) Nannfeldt (Campanulaceae). Their structures were identified as 5-(hydroxymethyl)-2-furaldehyde(A) and 5-(methoxymethyl)-2-furaldehyde(D). The latter is a new compound among the known natural products.

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