• 제목/요약/키워드: Cyclic Structure

검색결과 917건 처리시간 0.027초

Electrosynthesis and Electrochemical Properties of Metal Oxide Nano Wire/ P-type Conductive Polymer Composite Film

  • Siadat, S.O. Ranaei
    • Journal of Electrochemical Science and Technology
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    • 제6권3호
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    • pp.81-87
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    • 2015
  • This study introduces a facile strategy to prepare metal oxide/conducting polymer nanocomposites that may have promising applications in energy storage devices. Ploy aniline/nano wire manganese dioxide (PANI/NwMnO2) was synthesized by cyclic voltammetry on glassy carbon electrode. Morphology and structure of the composite, pure PANI, MnO2 nanowires were fully characterized using XRD and SEM analysis. Electrochemical studies shows excellent synergistic effect between PANI and MnO2 nanowires which results in its capacitance increase and cycle stability against PANI electrode. Specific capacitances of PANI/NwMnO2 and PANI were 456 and 190 F/g respectively. The electrochemical performance of electrodes studied using cyclic voltammetry, Galvanostatic charge/discharge and impedance spectroscopy.

Viologen 박막을 이용한 과산화수소의 전기화학적 검출 특성 (Electrochemical Detection of Hydrogen Peroxide based on Viologen Monolayers)

  • 최원석;이동윤;박상현;박재철;권영수
    • 전기학회논문지
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    • 제57권11호
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    • pp.2006-2010
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    • 2008
  • In this paper, we fabricated a biosensor for detecting hydrogen peroxide and investigated the sensing property. We prepared a viologen and hemoglobin modified gold electrode using self-assembly and layer by layer method. The electrochemical property of the viologen derivative was characterized in 0.1 M $NaClO_4$ electrolyte solution by cyclic voltammetry. The modified electrode showed reversible electrochemical properties and high stability. From the results, the viologen can act as a charge transfer mediator for access to the electrode surface. The catalytic characteristics of the designed sensor proved that hemoglobin has been kept in its natural structure and can retain its biological activity. The designed biosensor showed a fast amperometric response, excellent linearity and low detection limit. In addition, it had high sensitivity, good reproducibility and stability.

ON CONJUGACY OF p-GONAL AUTOMORPHISMS

  • Hidalgo, Ruben A.
    • 대한수학회보
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    • 제49권2호
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    • pp.411-415
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    • 2012
  • In 1995 it was proved by Gonz$\acute{a}$lez-Diez that the cyclic group generated by a p-gonal automorphism of a closed Riemann surface of genus at least two is unique up to conjugation in the full group of conformal automorphisms. Later, in 2008, Gromadzki provided a different and shorter proof of the same fact using the Castelnuovo-Severi theorem. In this paper we provide another proof which is shorter and is just a simple use of Sylow's theorem together with the Castelnuovo-Severi theorem. This method permits to obtain that the cyclic group generated by a conformal automorphism of order p of a handlebody with a Kleinian structure and quotient the three-ball is unique up to conjugation in the full group of conformal automorphisms.

An efficient numerical simulation of the cyclic loading experiments on RC structures

  • Lykidisa, Georgios Ch.;Spiliopoulos, Konstantinos V.
    • Computers and Concrete
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    • 제13권3호
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    • pp.343-359
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    • 2014
  • In this work a numerical method to simulate the response of reinforced concrete structures subject to cyclically imposed displacements is proposed. The method consists of a combination of a displacement and load controlled version of the Newton-Raphson iterative technique, used for the loading and the unloading part of the cycles respectively. The whole procedure is combined with a relatively simple concrete model whose only material parameter is its uniaxial compressive strength. The proposed methodology may realistically simulate, in an easy way, the physical process of any experimentally tested RC structure under imposed displacements cycles. The efficiency of the approach is demonstrated through a series of analyses of experimentally tested specimens reported in the literature.

Simultaneous Measurements of Stress and Birefringence Development during Extensional Deformation of Cyclic Olefin Copolymer

  • Yagisawa, Yusuke;Ito, Hiroshi;Kikutani, Takeshi
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.361-361
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    • 2006
  • To clarify the structure development of cyclic olefin copolymers in stretching and relaxation processes, on-line measurements of optical retardation and tensile force were performed. Birefringence increased continuously whereas stress showed yielding at stretching temperatures of $160^{\circ}C$. At $170^{\circ}C$, stress yielding was not observed and stress and birefringence increased monotonously with an increase in the strain. In the relaxation process, stress and birefringence decreased monotonously at all the temperatures examined. The slope for the stress vs. birefringence relation at initial stage of stretching increased with an increase in temperature, whereas that for the relaxation stage was significantly larger that for the stretching process, and therefore showed a significant hysteresis.

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New Types of Constrained Geometry Catalysts Containing Silacycloalkyl Bridging Unit: Synthesis, Structure, and Polymerization Activity

  • Ok, Myung-Ahn;Hahn, Jong-Sok;Jung, Jae-Ho;Kang, Sang-Ook
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.222-222
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    • 2006
  • New types of constrained geometry complexes comprising rigid silacycloalkyl group incorporated into the bridging position between cyclopentadienyl and amido functionalities were prepared. The catalytic activities of olefin polymerization were influenced by the change of exo-cyclic ring size on bridge-head silacycloalkyl unit. It has been noted that the activities of this unique series increase with increasing size of the silacycloalkyl bridge and reach the maximum in six-membered silacyclohexyl-bridged CGC complex. It is noteworthy that conformation of silacycloalkanes gives rise to enhanced catalytic activity of the titanium center although the cyclic ring and titanium center are far remoted from each other.

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Zn(HPB)q를 전자수송층으로 이용한 OLED의 전기.광학적 특성 연구 (Properties of Electrical and Optical for OLED using Zn(HPB)q as Electron Transporting Layer)

  • 김동은;박준우;김병상;이범종;권영수
    • 전기학회논문지
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    • 제59권5호
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    • pp.927-931
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    • 2010
  • Recently, high luminance and high efficiency were realized in OLED with multilayer structure including emitting materials such as metal-chelate complexes. We synthesized a new luminescent material, namely, [2-(2-hydroxyphenyl)quinoline] (Zn(HPB)q) which has low molecular compound and emitted in yellowish green region. The ionization potential(IP) and electron affinity(EA) of Zn(HPB)q were measured by cyclic-voltammetry(CV). As a result, IP and EA of Zn(HPB)q were calculated 6.8 eV and 3.5 eV, respectively. We fabricated the devices and observed the possibility of Zn(HPB)q as electron transporting layer. We have obtained an improvement of luminance and decrease of turn-on voltage using Zn(HPB)q as electron transporting layer.

피로하중을 받는 구조물의 결함분포에 대한 확률론적 해석 (Probabilistic Analysis of Flaw Distribution on Structure Under Cyclic Load)

  • 곽상록;최영환;김효정
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 춘계학술대회
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    • pp.604-609
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    • 2003
  • Flaw geometries, applied stress, and material properties are major input variables for the fracture mechanics analysis. Probabilistic approach can be applied for the consideration of uncertainties within these input variables. But probabilistic analysis requires many assumptions due to the lack of initial flaw distributions data. In this study correlations are examined between initial flaw distributions and in-service flaw distributions on structures under cyclic load. For the analysis, LEFM theories and Monte Carlo simulation are applied. Result shows that in-service flaw distributions are determined by initial flaw distributions rather than fatigue crack growth rate. So initial flaw distribution can be derived from in-service flaw distributions.

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ON FINITE GROUPS WITH EXACTLY SEVEN ELEMENT CENTRALIZERS

  • Ashrafi Ali-Reza;Taeri Bi-Jan
    • Journal of applied mathematics & informatics
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    • 제22권1_2호
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    • pp.403-410
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    • 2006
  • For a finite group G, #Cent(G) denotes the number of centralizers of its elements. A group G is called n-centralizer if #Cent(G) = n, and primitive n-centralizer if #Cent(G) = #Cent($\frac{G}{Z(G)}$) = n. The first author in [1], characterized the primitive 6-centralizer finite groups. In this paper we continue this problem and characterize the primitive 7-centralizer finite groups. We prove that a finite group G is primitive 7-centralizer if and only if $\frac{G}{Z(G)}{\simeq}D_{10}$ or R, where R is the semidirect product of a cyclic group of order 5 by a cyclic group of order 4 acting faithfully. Also, we compute #Cent(G) for some finite groups, using the structure of G modulu its center.

ON LCD CODES OVER FINITE CHAIN RINGS

  • Durgun, Yilmaz
    • 대한수학회보
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    • 제57권1호
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    • pp.37-50
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    • 2020
  • Linear complementary dual (LCD) codes are linear codes that intersect with their dual trivially. LCD cyclic codes have been known as reversible cyclic codes that had applications in data storage. Due to a newly discovered application in cryptography, interest in LCD codes has increased again. Although LCD codes over finite fields have been extensively studied so far, little work has been done on LCD codes over chain rings. In this paper, we are interested in structure of LCD codes over chain rings. We show that LCD codes over chain rings are free codes. We provide some necessary and sufficient conditions for an LCD code C over finite chain rings in terms of projections of linear codes. We also showed the existence of asymptotically good LCD codes over finite chain rings.