• Title/Summary/Keyword: Current Density and Temperature Distribution

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Porous SnO2 Films Fabricated Using an Anodizing Process (양극산화법에 의한 다공성 SnO2 피막)

  • Han, Hye-Jeong;Choi, Jae-Ho;Min, Seok-Hong
    • Korean Journal of Materials Research
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    • v.16 no.8
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    • pp.503-510
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    • 2006
  • The measurement of specific gases is based on the reversible conductivity change of sensing materials in semiconductor type gas sensors. For an application as gas sensors of high sensitivity, porous $SnO_2$ films have been fabricated by anodizing of pure Sn foil in oxalic acid and characteristics of anodic tin oxide films have been investigated. Pore diameter and distribution were dependent on process conditions such as electrolyte concentration, applied voltage, anodizing temperature, and time. Characteristics of anodic films were explained with current density-time curves.

Electrical Conduction Properties due to Electron Beam Irradiation of Low Density Polyethylene (전자선 조사에 따른 절연재료(LDPE)의 전기전도특성)

  • Lee, Jong-Pil;Kim, Lee-Doo;Oh, Se-Young;Kim, Suk-Hwan;Kim, Wang-Kon;Lee, Chung-Ho;Hong, Jin-Woong
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1416-1418
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    • 1998
  • In this paper, the physical and electrical conduction properties due to the electron beam irradiation for low density polyethylene using insulating materials of the distribution cable and ultra-high voltage cable are studied. In FTIR spectrum for physical properties, the strong absorptions by methyl groups in wavenumbers 720[$cm^{-l}$] and 1463[$cm^{-l}$] are observed, and the effect by residual carbonyl groups (C = 0) is hardly appeared. So, as a result of the electrical conduction properties, it is confirmed that the conduction current is increased nearly to 50[$^{\circ}C$], and is not changed until the crystalline melting point from the temperature over 60[$^{\circ}C$] because of the defects of morphology and the formation of many trap centers by means of electron beam irradiation.

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Heat Transfer Analysis of a Pulse Magnetron Sputtering Cathode (펄스 마그네트론 스퍼터링 음극의 열전달 해석)

  • Joo, Jung-Hoon
    • Journal of the Korean institute of surface engineering
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    • v.41 no.6
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    • pp.274-278
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    • 2008
  • 3-dimensional numerical analysis for a rectangular magnetron cathode model is done to predict cooling characteristics of high power sputtering system for ZnO deposition. It includes cooling channel design, heat transfer analysis of a target, bonding layer and backing plate. In order to model erosion profiles of a target, ion current density distribution from 3D Monte Carlo simulation is used to distribute total sputtering power to 5 discrete regions. At 3 kW of sputtering power and cooling water flow of 1 liter/min at $10^{\circ}C$, the maximum surface temperature was $45.8^{\circ}C$ for a flat new target and $156^{\circ}C$ for a target eroded by 1/3 of its thickness, respectively.

Design for Weight Reduction of the Linear induction Motor for MAGLEV (도시형 자기부상열차용 선형유도전동기의 경량화 설계)

  • Park, Seung-Chan;Lee, Won-Min;Kim, Kyung-Min;Kim, Jung-Cheol;Park, Yeong-Ho;Kim, Kuk-Jin
    • Proceedings of the KSR Conference
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    • 2007.11a
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    • pp.1460-1465
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    • 2007
  • In this paper, the conventional linear induction motor(LIM) used in propelling the MAGLEV in Korea is redesigned in order to reduce its weight. The specifications of the newly designed model for base speed, acceleration, rated thrust and maximum output is respectively 45km/h, 4.0km/h/sec, 5,200[N] and 65 [kW]. Weight reduction effect of the LIM according to the change of pole number from 8 to 6 is shown. Equivalent circuit analysis considering end effect and finite element method are used for the analysis of the redesigned model. Finally the weight reduction ratio of the newly designed LIM to the conventional model, thrust, attraction force, line current, temperature rise, flux density distribution are presented.

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Thermal managing effects by cooling channels on performance of a PEMFC (냉각채널 열관리에 따른 고분자연료전지의 성능영향 연구)

  • Sohn, Young-Jun;Kim, Min-Jin;Park, Gu-Gon;Kim, Kyoung-Youn;Lee, Won-Yong
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.373-373
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    • 2009
  • Relative humidity, membrane conductivity and water activity are critical parameters of polymer electrolyte membrane fuel cells (PEMFC) for high performance and reliability. These parameters are closely related with temperature. Moreover, the ideal values of these parameters are not always identical along the channels. Therefore, the cooling channel design and its operating condition should be well optimized along the all location of the channels. In the present study, we have performed a numerical investigation on the effects of cooling channels on performance of a PEMFC. Three-dimensional Navier-Stokes equations are solved with the energy equation including heat generated by the electrochemical reactions in the fuel cell. The present numerical model includes the gas diffusion layers (GDL) and serpentine channels for both anode and cathode gas flows, as well as cooling channels. To accurately predict the water transport across the membrane, the distribution of water content in the membrane is calculated by solving a nonlinear differential equation with a nonlinear coefficient, i.e., the water diffusivity which is a function of water content as well as temperature. Main emphasis is placed on the heat transfer between the solid bipolar plate and coolant flow. The present results show that local current density is affected by cooling channels due to the change of the oxygen concentration and the membrane conductivity as well as the water content. It is also found that the relative humidity is influenced by the generated water and the gas temperature and thus it affects the distribution of fuel concentration and the conductivity of the membrane, ultimately fuel cell performance. Unit-cell experiments are also carried out to validate the numerical models. The performance curves between the models and experiments show reasonable results.

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Study on the Synthesis of Alumina Membrane by Anodization in Sulfuric Acid (황산전해액에서 양극산화에 의한 알루미나 막 제조에 관한 연구)

  • Kim, Hyun;Chang, Yoon Ho;Hahm, Yeong Min
    • Applied Chemistry for Engineering
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    • v.8 no.5
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    • pp.756-762
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    • 1997
  • The experiment was carried out to fabricate alumina membrane which has a cylindrical pore structure by anodizing aluminium plate in sulfuric acid solution with the electrochemical technique. The aluminium plate for anodizing was prepared by the pretreatment process such as chemical, electro-polishing and thermal treatment. The pore size distribution and the film thickness of alumina membrane were investigated by the implementation of scanning electron microscope(SEM) and BET method. The results show that the oxide film has a geometrical structures like a Keller model and that the membrane has a uniform pore distribution. The pore size and the oxide film thickness are dependent on the anodizing process variables such as the electrolyte concentration, the reation temperature and the anodizing current density.

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OXYGEN CONCENTRATION IN THE CATHODE CHANNEL OF PEM FUEL CELL USING GAS CHROMATOGRAPH

  • Ha, T.H.;Kim, H.S.;Min, K.D.
    • International Journal of Automotive Technology
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    • v.8 no.1
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    • pp.119-126
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    • 2007
  • Because of the low temperature operation, proton exchange membrane (PEM) fuel cell has a water phase transition. Therefore, water management is an important operation issue in a PEM fuel cell because the liquid water in the fuel cell causes electrode flooding that can lower the cell performance under high current density conditions. In this study, in order to understand the reactant distributions in the cathode channels of the PEM fuel cell, an experimental technique that can measure the species concentrations of reactant gases by using gas chromatograph (GC) is applied for an operating PEM fuel cell. The oxygen distribution along the cathode flow channels of PEM fuel cell is mainly investigated with various operating conditions. Also, the relations between cathode flooding and oxygen concentrations and oxygen consumption pattern along the cathode channel configurations of the unit cell adopted for this study are discussed using GC measurement and visualization experiment of cathode flooding. It is found that the amount of oxygen consumption is very sensitive to various operating conditions of the fuel cell and was much affected by the flooding occurrence in cathode channels.

Electrolytic Synthesis of Cobalt Nanorods without Using a Supporting Template (템플릿 없이 전해 합성된 코발트 나노 로드)

  • Kim, Seong-Jun;Shin, Heon-Cheol
    • Korean Journal of Materials Research
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    • v.24 no.6
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    • pp.319-325
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    • 2014
  • Cobalt nano-rods were fabricated using a template-free electrochemical-deposition process. The structure of cobalt electro-deposits strongly depends on the electrolyte composition and on the density of the applied current. In particular, as the content of boric acid increased in the electrolyte, deposits of semi-spherical nuclei formed, and then grew into one-dimensional nano-rods. From analysis of the electro-deposits created under the conditions of continuous and pulsed current, it is suggested that the distribution of the active species around the electrode/electrolyte interface, and their transport, might be an important factor affecting the shape of the deposits. When transport of the active species was suppressed by lowering the deposition temperature, more of the well-defined nano-rod structures were obtained. The optimal conditions for the preparation of well-defined nano-rods were determined by observing the morphologies resulting from different deposition conditions. The maximum height of the cobalt nano-rods created in this work was $1{\mu}m$ and it had a diameter of 200 nm. Structural analysis proved that the nano-rods have preferred orientations of (111).

Dielectric Characteristics of $Ta_2O_5$ Thin Films Prepared by ECR-PECVD (ECR-플라즈마 화학 증착법에 의해 제조된 $Ta_2O_5$ 박막의 유전 특성)

  • 조복원;안성덕;이원종
    • Journal of the Korean Ceramic Society
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    • v.31 no.11
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    • pp.1330-1336
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    • 1994
  • Ta2O5 films were deposited on the p-Si(100) substrates by ECR-PECVD and annealed in O2 atmosphere. The thicknesses of Ta2O5/SiO2 layers were measured by an ellipsometer and a cross-sectional TEM. Annealing in O2 atmosphere enhanced the stoichiometry of the Ta2O5 film and reduced the impurity carbon content. Ta2O5 films were crystallized at the annealing temperatures above 75$0^{\circ}C$. The best leakage current characteristics and the maximum dielectric constant of Ta2O5/SiO2 film capacitor were observed in the specimen annealed at $700^{\circ}C$ and 75$0^{\circ}C$, respectively. The flat band voltage of the Al/Ta2O5/SiO2/p-Si MOS capacitor was varied in the range of -0.6~-1.6 V with the annealing temperature. The conduction mechanism in the Ta2O5 film, the variation of the effective oxide charge density with the annealing temperature, and the effective electric field distribution in the Ta2O5/SiO2 double layer were also discussed.

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Characteristics of Ni/YSZ Cermet Prepared by Mechanical Alloying Method for the High Temperature Electrolysis of Steam

  • Choo, Soo-Tae;Kang, Kyoung-Hoon;Chae, Ui-Seok;Hong, Hyun-Seon;Hwang, Kab-Jin;Bae, Ki-Kwang;Shin, Seock-Jae
    • Journal of the Korean Ceramic Society
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    • v.43 no.12 s.295
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    • pp.764-767
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    • 2006
  • Ni/YSZ $(Y_2O_3-stabilized\;ZrO_2)$ composite as an electrode component for High Temperature Electrolysis (HTE) was fabricated by mechanical alloying method using Ni and YSZ powders. Characterization of the synthesized composite was investigated with various analysis tools, including XRD, SEM and PSA, and a self-supporting planar unit cell prepared with the Ni/YSZ composite was prepared to study the electrochemical reactions for the production of hydrogen. The Ni/YSZ cermet is composed of crystalline Ni and YSZ, in a sub-micro scale, and has an even distribution without aggregated particles. In addition, under an electrochemical reaction, the unit cell showed an $H_2$ evolution rate from steam of 14 Nml/min and $600mA/cm^2$ of current density at the electrode.