• Title/Summary/Keyword: Curing agent

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A Study on the Fashion Accessary Product Development by Use of Korean Traditional Hanji (Part I) -Physical Properties of the Korean Traditional Paper(Hanji) Treated with Silcone resin- (전통한지를 활용한 패션 악세서리 상품개발 (제1보) -실리콘 수지로 처리된 한지의 물성변화-)

  • Kim Eun-Ah;Ryu Hyo-Seon;Kim Yong-Sook
    • Journal of the Korean Society of Clothing and Textiles
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    • v.30 no.3 s.151
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    • pp.481-486
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    • 2006
  • There are attempts to utilize Hanji for apparel material, but, the reason that the strength and durability of Hanji decrease to a great extent in the wet condition, restricts the usability of Hanji. In order to improve the resistance against water, Hanji was treated with silicone type water repellent agents. The treatment was carried out by conventional pad-dry-cure method. The optimum treatment condition was obtained by varying the concentration of repellent agent, curing temperature and time. Water repellency was tested by spray rating method. Wet and dry tensile strength, tearing resistance and abrasion resistance were examined after the treatment. Flexural stiffness and wrinkle recovery angles of hanji were also measured. In result, the optimum condition of treatment was at resin concentration of 40g/l, catalyst concentration of 20g/l(half of resin concentration), curing temperature of 160$^{circ}C$, curing time of 120 sec. Flexural stiffness of Hanji was hardly increased and wrinkle recovery angle of Hanji was improved a little by resin treatment. After the treatment, in dry condition, tensile strength and tearing resistance were little changed but abrasion resistance was improved. In wet condition, tensile strength, tearing strength and abrasion resistance were improved.

A Study on Improvement of Field Implementation of Asphalt Surface Reinforcement Method (아스팔트 표면 강화공법의 현장 적용성 개선 방안 연구)

  • Jo, Shin Haeng;Kim, Kyungnam;Kim, Nakseok
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.37 no.2
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    • pp.389-395
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    • 2017
  • A study was carried out to improve the field implementation of asphalt surface reinforcement method which is a preventive maintenance. Mean Texture Depth (MTD) was measured to quantify the surface condition and used to determine the optimum application rate. Determining the application rate using MTD can reduce the material loss from 30% to 15%. In order to reduce the curing time to 30 minutes, the heat capacity of $317kcal/m^2$ is required. Therefore, the design capacity of the heating curing device requires more than 380,000 kcal/hr. The asphalt surface reinforcement method is preferably applied at a time when slight cracking occurs before the permanent deformation becomes serious. Through the analysis of the pavement survey data, it was decided to apply the surface reinforcement method at the crack rate of 3~4%. Heating the surface reinforcement agent to $50^{\circ}C$ improves workability and ensures sufficient penetration depth even at a crack width of 1 mm. The results will be utilized as basic data for the development of automated construction equipment for efficiency improvement.

Characteristics of Unconfined Compressive Strength of Dredged Clay Mixed with Friendly Soil Hardening Agent (준설토와 친토양 경화재 혼합지반의 일축강도특성)

  • Oh, Sewook;Yeon, Yonghum;Kwon, Youngcheul
    • Journal of the Korean GEO-environmental Society
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    • v.17 no.10
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    • pp.73-81
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    • 2016
  • In the construction on low strength and high compressible soft ground, the many problems have been occurred in recent construction project. therefore, the soil improvement have been developed to obtain high strength in relatively short period of curing time. Based on the laboratory tests using undisturbed marine clay, the effect of improvement on soft ground was estimated. Deep mixing method by cement have been virtually used for decades to improve the mechanical properties of soft ground. However, previous researches set the focus on the short term strength the about 10% of cement treated clay. In this paper, cement and Natural Soil Stabilizer (NSS) were used as the stabilizing agent to obtain trafficability and mechanical strength of the soft clay. Based on the several laboratory tests, optimum condition was proposed to ensure the mechanical strength and compressibility as the foundation soil using cement and NSS mixed soil. Finally, research data was proposed about the applicability of NSS as the stabilizing agent to soft clay to increase the mechanical strength of soil.

Analysis of Mechanical Properties of Solidified soil using Pig Iron Slag (용선슬래그를 활용한 고화토의 역학적 특성 분석)

  • Yang, Chul-Jin;Bae, Jun-Seok;Byun, Ho-Seok;Lee, Kang-Hwi;Lee, Jong-Sik
    • Journal of the Korean Geosynthetics Society
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    • v.17 no.1
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    • pp.1-10
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    • 2018
  • We conducted research to develop a solidification agent for the ground surface reinforcement method in which activator is fused by recycling pig iron slag, which is a byproduct generated in the steel making process. The purpose of this research is to solve the problems of surface soil by improving the strength and durability of foundation soil such as soil loss, settlement, sinkhole, etc. by recycling pig iron slag from disused or landfilled steelworks. For this purpose, the possibility of using pig iron slag as a solidification soil was evaluated by the compressive strength, elution test of harmful materials, permeability coefficient test. As a result of the compressive strength test, the values of the strength of the curing 28 days of the solidified soil having the solidification agent mixing ratio of 12% were found to be 0.93, 0.96 and 1.3 MPa, respectively, satisfying the required strength value of 1 MPa, In the case of permeability coefficients, the minimum values were $4.1{\times}10^{-8}$, $7.0{\times}10^{-7}$, and $1.7{\times}10^{-7}cm/sec$, respectively, at the solidification agent mixing rate of 12%. In addition, as a result of the elution test of harmful materials, a small amount was detected in the item of hexavalent chromium but satisfied the inclusion criteria, and in the remaining items, heavy metals were not eluted.

A Study on the Preparation of Durable Softening Water-repellenting Agent by Blending Acrylic Copolymer and Fatty Carbamide - I. Water-repellent Finish of Cotton Fabrics - (아크릴 공중합체와 지방산 카르바미드의 블렌딩에 의한 내구유연발수제의 제조에 관한 연구 - I. 면직물에의 발수가공 -)

  • Kim, Young-Keun;Lee, Chong-Min;Park, Eun-Kyung;Park, Hong-Soo
    • Applied Chemistry for Engineering
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    • v.5 no.2
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    • pp.345-356
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    • 1994
  • Each of the three cationized compounds synthesized previously, poly(OMA-co-DAMA)[PODC], poly(DMA-co-DAMA)[PDDC] and poly(EMA-co-DAMA)[PEDC] was blended with waxes, emulsifiers and cationized fatty carbamide(ODTCC) synthesized in this study for the preparation of some durable softening water-repellenting agents, PODCW, PDDCW and PEDCW. The results of washability, tearing strength, crease recovery and contact angle of the cotton fabrics treated with PODCW, PDDCW and PEDCW with and without textile finishing resin, showed remarkable improvement of the physical properties. Rating of water repellency of cotton fabric treated with PODCW was 80, but those treated with PDDCW and PEDCW were not high enough to use in industry. Proper curing temperature of the synthesized water-repelleting agents was $140^{\circ}C$; proper using concentration was 3wt%; sodium acetate was the best catalyst for water-repellenting agents among the used, and proper concentration was 0.6wt%. From the results of reaction mechanism of cellulosic fiber with water-repellenting agent and washability of the fibers treated with water-repellenting agents the prepared water-repellenting agent proved to be durable. Surface structures of cotton fabrics treated with water-repellenting agent were investigated by SEM.

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Effects of E-beam Irradiation on the Water-repellency and Washing Durability of the Water-repellent Finished Chemically-recycled PET(CR-PET) Fabrics (발수가공 시 전자빔 조사가 화학재생 폴리에스터 직물의 발수효과와 내세탁성에 미치는 영향)

  • Lee, Sun Young;Sohn, Han Guel;Lim, Sung Chan;Lee, Hyoung Dal;Lee, Seung Goo
    • Textile Coloration and Finishing
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    • v.27 no.2
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    • pp.119-125
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    • 2015
  • The effects of e-beam irradiation on water-repellency and washing durability of water-repellent finished chemically-recycled PET(CR-PET) fabrics were investigated. As results, more doses of e-beam irradiation damaged the fabric surface more severely. It was thought because the high densed energy was formed, where the more e-beam was converged. The contact angle measurement showed that as the dose of e-beam irradiation increased, water wettability of the CR-PET fabric increased slightly. It was thought to be due that the surface etching by e-beam irradiation let water droplet permeate into the fabric surface better. The concentration of the water-repellent finishing agent was more important factor than curing temperature as finishing parameter. It was considered because the water-repellent finishing agent used in this study got to cure sufficiently at low temperature. Consequently, e-beam irradiation improved the washing durability of water-repellent finishing on the CR-PET fabrics.

Effect of KOH Addition on Pore Structure of Glassy Carbon Prepared by Polymerization of Phenolic Resin (KOH 첨가에 의한 페놀수지로 제조된 유리상탄소의 미세구조제어)

  • 김지현;박세민;임연수;박홍수;김명수
    • Polymer(Korea)
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    • v.26 no.4
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    • pp.477-482
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    • 2002
  • In order to control the micro-pore structure of glassy carbon (GC), an activation agent of KOH was introduced as the glassy carbon was prepared from phenolic resin with a curing agent of phosphoric acid. The yield and properties of GC were investigated as a function of KOH content. Although the GC produced without KOH had nonporous structure except the trace of bubble formation, the GC with KOH had very porous structure. The surface area of GC with KOH increased continuously up to 870 $m^2$/g with the increase of KOH content. The carbonization yield and apparent density measured in water reduced from 40 to 15% and iron 1.5 to 0.9 g/$cm^3$, respectively, and the electrical resistivity increased from $50{\times}10^{-4}$ to $60{\times}10^{-4}$$\Omega$.cm with the increase of KOH content.

Properties Evaluation of Controlled Low Strength Materials Used Industrial by-Products of A Great Quantity (다량의 산업부산물을 활용한 슬러리계 되메움 재료의 물성 평가)

  • Liao, Xiaokai;Kim, Dong-Hun
    • Journal of the Korea Institute of Building Construction
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    • v.20 no.5
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    • pp.441-448
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    • 2020
  • In this study, the engineering characteristics of CLSM mixed with GBFS and GF were identified to review the applicability as a replacement material and further evaluate the recharge and field applicability as a joint filler material. This study has resulted in the following findings. First, Using more than 30% of GBFS to replace FA enabled bleeding control through improved fluidity. Moreover, it has been confirmed that effective strength and proper quality can be achieved when it was applied as a refiller and joint filler material with higher early strength than the base material. Second, When using more than 30% of FNS to replace sand, it was found that adding 0.3~0.35 of the AE agent is effective for bleeding control through improved fluidity. Third, When using more than 30% of both GBFS and FNS in combination, it was found that adding 0.3~0.35 of the AE agent is effective for bleeding control through improved fluidity. Also, it was confirmed that proper mixing of 15~60% of GF secured the effective strength and desired quality as a refiller and joint filler material. Fourth, The relationship between the superficial level and internal micro pores of CLSM from the curing process needs to be discussed and reviewed in more detail through further research studies.

Effect of silane activation on shear bond strength of fiber-reinforced composite post to resin cement

  • Kim, Hyun-Dong;Lee, Joo-Hee;Ahn, Kang-Min;Kim, Hee-Sun;Cha, Hyun-Suk
    • The Journal of Advanced Prosthodontics
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    • v.5 no.2
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    • pp.104-109
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    • 2013
  • PURPOSE. Among the surface treatment methods suggested to enhance the adhesion of resin cement to fiberreinforced composite posts, conflicting results have been obtained with silanization. In this study, the effects of silanization, heat activation after silanization, on the bond strength between fiber-reinforced composite post and resin cement were determined. MATERIALS AND METHODS. Six groups (n=7) were established to evaluate two types of fiber post (FRC Postec Plus, D.T. Light Post) and three surface treatments (no treatment; air drying; drying at $38^{\circ}C$). Every specimen were bonded with dual-curing resin cement (Variolink N) and stored in distilled water for 24 hours at $37^{\circ}C$. Shear-bond strength (MPa) between the fiber post and the resin cement were measured using universal testing device. The data were analyzed with 1-way ANOVA and by multiple comparisons according to Tukey's HSD (${\alpha}$=0.05). The effect of surface treatment, fiber post type, and the interactions between these two factors were analyzed using 2-way ANOVA and independent sample T-tests. RESULTS. Silanization of the FRC Postec Plus significantly increased bond strength compared with the respective non-treated control, whereas no effect was determined for the D.T. Light Post. Heat drying the silane coupling agent on to the fiberreinforced post did not significantly improve bond strength compared to air-syringe drying. CONCLUSION. The bond strength between the fiber-reinforced post and the resin cement was significantly increased with silanization in regards to the FRC Postec Plus post. Bond strength was not significantly improved by heat activation of the silane coupling agent.

Properties of Rubbers and Coated Fabrics according to Different Cross-linking Density of Coating Agent (코팅제의 가교 밀도에 따른 고무와 코팅원단의 물성 변화)

  • Suhong Kim;Kisuk Sung;Doohyun Baik
    • Textile Coloration and Finishing
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    • v.35 no.1
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    • pp.8-19
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    • 2023
  • Silicone rubber is widely used in most industries due to diverse advantages like heat stability, UV stability, durability, chemical resistance, environment friendliness, inertness and so on. But there is limitation to expand applications due to relatively weak rubber strengths such as tensile strength and tear strength, especially in fabric coating applications. The purpose of this study is to find influence of coating agent on performances of rubber and coated fabrics and their correlation according to different crosslinking densities of silicone rubbers. Addition cure type of silicones were formulated using crosslinked MQ-type silicone resin consisting of M (R3SiO1/2) and Q (SiO4/2) and linear polymers. Raw materials used were; 1) linear vinyl endblocked polymers and vinyl functional MQ resin as main polymers, 2) linear silicone hydride polymers as crosslinkers, 3) platinum catalyst and 4) inhibitor to control curing speed. Rubber specimens were prepared to check mechanical strength using universal testing machine (UTM). Crosslinking density was calculated using Flory-Rhener equation using solvent swelling method. Differential scanning calorimetry (DSC) and scanning electron microscope (SEM-EDS) were used to characterize rubbers. Consequently, it was found that physical properties of silicone rubbers and coated fabrics can be expected by crosslinking density of rubbers. Silicone rubber formulations that contain 20 ~ 30 wt% of vinyl MQ resin showed strongest balanced performances.