• Title/Summary/Keyword: Curing agent

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Dyeing of Cotton/Polyester Blends with Disperse Dyes in the Presence of DMDHEU/PEG (DMDHEU/PEG와 분산염료를 이용한 면/폴리에스테르 혼방직물의 염색)

  • 김은아;유효선
    • Journal of the Korean Society of Clothing and Textiles
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    • v.24 no.7
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    • pp.1025-1034
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    • 2000
  • Cotton differs from polyester in physical and chemical properties. When cotton/polyester blends are dyed, water-soluble dyes are generally used for cotton and disperse dye for polyester. Thus, two bath or one bath-two step dyeing process are usually accepted. These processes consume more energy and cost compared to a single step process. To save energy and cost, a single step dyeing and finishing is carried out with disperse dyes in the presence of a crossslinking agent. K/S values of the dyed fabrics were determined to examine the dyeing property of cotton, cotton/polyester, polyester fabrics dyed with disperse dyes in the presence of DMDHEU/PEG. The concentration of DMDHEU, molecular weight and concentration of PEG, curing time and curing temperature were varied.

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The Temperature Characteristics of Epoxy Resin by Curing Time (에폭시 수지의 경화에 따른 온도 특성)

  • Lee, Jin;Lee, Eun-Hak;Lim, Young-Choel;Lee, Kye-Ho;Park, Jong-Kun;Kim, Tae-Seoung
    • Proceedings of the KIEE Conference
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    • 1988.07a
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    • pp.771-773
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    • 1988
  • The Mechanical strength and the electrical insulation properties of the Epoxy Resin vary with the formation of chemical reactions between Epoxy and curing agent. Therefore, to study their reactions is important for understanding the properties of the cured Epoxy. In this paper, to get the cured Epoxy having good electrical insulation property, it is studied the effects of the surrounding temperature during the cure process on the property of the cured Epoxy. In the experiment, Epoxy is cured with the surrounding temperature varied between -5[$^{\circ}C$] to 50[$^{\circ}C$]. As the results, it follows that the higher the temperature is, the faster the cross-link process is.

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Studies on the m-Toluate Degradating Plasmid in Pseudomonas (m-Tluate를 분해하는 Peudomonas의 분리 및 Dgradative Pasmid와의 연관성에 관하여)

  • 박순희;하영칠;홍순우
    • Korean Journal of Microbiology
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    • v.17 no.1
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    • pp.25-41
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    • 1979
  • A strain able to grow up m-toluate minimal medium has been isolated after selective enrichment and given the name T81X, which was later identified as pseudomonase putida according to its morphological and biochemical characteristics. After treatment with plasmied specific curing agent, mitomycin C, followed by replica plating on m-toluate and xylene minimal agar plate, T81Xstrain has been shown to harbour a curable plasmid relating to the m-toluate and xylene metabolism. Spontaneous curing frquency of this plasmid was also greatly enhanced by growing on benzoate minimal medium. After then, it was also xylene metabogrowing on benzoate minimal medium. After then, it was found to be conjugally nontransmissible. From the comparative investigation of catechol 1,2-oxygenase and catechol 2,3-oxygenase activities in wild type and cured strain on various growth substrate, it appeared that T81X strain has both of these two enzymes while cured strain has catechol 1,2-oxygenase only. Growing on m-toluate minimal medium T81X strain should carry the genetic information necessary for coding the catechol 1,2-oxygense induced by m-toluate or benzoate, on that curable plasmid.

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Analysis of Peroxide Curing Agents in EVA Compounds and Vulcanizates

  • Chae, Eunji;Choi, Sung-Seen
    • Elastomers and Composites
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    • v.55 no.1
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    • pp.6-12
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    • 2020
  • Poly(ethylene-co-vinyl acetate) compounds and vulcanizates containing dicumyl peroxide (DCP) (HD) were prepared, and the curing agent and reaction products were analyzed using gas chromatography/mass spectrometry (GC/MS). Samples containing trially cyanurate (TAC) and DCP (HDT) were also prepared and analyzed. Some raw DCP were decomposed in the injector region of GC to produce acetophenone. DCP was detected in the HD compound but was not observed in the HD vulcanizate, and instead acetophenone and 2-phenyl-2-propanol were detected. Both DCP and TAC were observed in the HDT compound but not in the HDT vulcanizate, where acetophenone and 2-phenyl-2-propanol were detected. Thus, some of the DCP decomposed during the compounding process. The formation mechanism for acetophenone and 2-phenyl-2-propanol during the crosslinking reaction was identified, and differences in the crosslinking reactions of HD and HDT compounds were discussed.

The Cure and Rheological Behavior of Diglycidyl Ether of Bisphenol F /Nadic Methyl Anhydride Resin System for Liquid Encapsulant (액상봉지재용 Diglycidyl Ether of Bisphenol F/Nadic Methyl Anhydride 수치 시스템의 경화 및 유변학적 거동)

  • 김윤진;김창제;윤호규
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2002.05a
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    • pp.152-157
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    • 2002
  • The cure and rheological behavior of Diglycidyl ether of bisphenol F, catalyzed by four kinds of imidazoles and a Nadic methyl anhydride curing agent were studied using a differential scanning calorimeter (DSC) and rheometer. The isothermal traces were employed to analyze cure reaction. The DGEBF/anhydride conversion profiles showed autocatalyzed reaction characterized by maximum conversion rate at 20~40 % of the reaction. The rate constants obtained from isothermal test showed temperature dependance, but reaction order did not. The order of reaction (m+n) was calculated to be close to 3. The measurements of viscosity and relation time in the presence of inorganic fillers were carried out at different isothermal curing temperatures. The viscosity and gelation time increased with filler content at the same isothermal temperature.

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Thermal stabilities and dynamic mechanical properties of dielectric materials for thermal imprint lithography (임프린트 공법적용을 위한 절연재료의 열적, 기계적 성질)

  • Cho, Jae-Choon;Ra, Seung-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.220-221
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    • 2007
  • Recently, imprint lithography have received significant attention due to an alternative technology for photolithography on high performance microelectronic devices. In this work, we investigated thermal stabilities and dynamic mechanical properties of dielectric materials for thermal imprint lithography. Curing behaviours, thermal stabilities, and dynamic mechanical properties of the dielectric materials cured with various curing agent and spherical filler were studied using dynamic differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), rheometer and universal test machine(UTM).

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Preparation and Physical Properties of Acrylic Resin Coatings Containing Tertiary Amine and Epoxysilane Curing Agent (3급아민기 함유 아크릴수지 합성과 에폭시실란 경화형 도료의 도막 물성)

  • Kim, Seong-Kil;Park, Hyong-Jin
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.164-165
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    • 2021
  • To prepare the good-adherent and weather-resistant acrylic resin coatings, acrylic resin was prepared by a radical polymerization. Glass transition temperature(Tg) of the acrylic copolymer was fixed at 30℃ and the contents of tertiary amine monomer(DMAEMA) was varied to be 5, 10, 15, 20 wt% respectively. γ-Glycidoxypropyltrimethoxysilane(GPTMS) containing epoxy group was used for curing agents and di-n-butyltindilaurate(DBTDL) was used for drying accelerator. The equivalent ratio of amine to epoxy was 1:1. The prepared coatings exhibited excellent adhesion to various substrates, and various physical properties of the coatings were satisfactory. The gloss retention and color difference were improved at low tertiary amine concentration. The coatings containing 10wt% tertiary amine concentration have especially good weather resistant properties.

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Optimum Conditions of Simple Solidifying Agent for the Improvement of Loose Sand Ground (느슨한 모래지반 개량을 위한 간편고화재의 최적 배합비 및 혼합률)

  • Kwon, Ho-Jin;Jeong, Ki-Ryong
    • Journal of the Korean GEO-environmental Society
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    • v.5 no.2
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    • pp.15-21
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    • 2004
  • This study is to develop simple solidifying agent to improve loose sand ground by admixing or injecting. This paper studied the optimum mixing ratio of micro cement, bentonite, chemistry admixture, plasticizer, accelerator for the optimum fluidity and strength. The optimum mixing ratio of micro cement and bentonite is 70% : 20%, the optimum ratio of the weight of rapid solidifying agent to the weight of total improved soil is about 8%, the optimum curing period is five days.

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Novel thermoplastic toughening agents in epoxy matrix for vacuum infusion process manufactured composites

  • Bae, Jin-Seok;Bae, Jihye;Woo, Heeju;Lee, Bumjae;Jeong, Euigyung
    • Carbon letters
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    • v.25
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    • pp.43-49
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    • 2018
  • This study suggests the novel thermoplastic toughening agent, which can be applied in the monomer forms without increasing the viscosity of the epoxy resin and polymerized during the resin curing. The diazide (p-BAB) and dialkyne (SPB) compounds are synthesized and mixed with the epoxy resin and the carbon fiber reinforced epoxy composites are prepared using vacuum infusion process (VIP). Then, flexural and drop weight tests are performed to evaluate the improvement in the toughness of the prepared composites to investigate the potential of the novel toughening agent. When 10 phr of p-BAB and SPB is added, the flexural properties are improved, maintaining the modulus as well as the toughness is improved. Even with a small amount of polytriazolesulfone polymerized, due to the filtering effect of the solid SPB by the layered carbon fabrics during the VIP, the toughening and strengthening effect were observed from the novel toughening agent, which could be added in monomer forms, p-BAB and SPB. This suggests that the novel toughening agent has a potential to be used for the composites prepared from viscosity sensitive process, such as resin transfer molding and VIP.

Improvement Effectiveness of Soft Ground Using Hardening Agent (고화재 혼합처리를 이용한 연약지반개량효과)

  • Chun, Byung-Sik
    • Journal of the Korean GEO-environmental Society
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    • v.2 no.2
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    • pp.59-64
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    • 2001
  • Recently, the application of shallow mixing method using hardening agent has increased because of the advantage of securing trafficability, reducing the working period, solving environmental problems caused by dumped and replaced soil, etc. In this paper, three types of representative hardening agents in Korea are used to achieve the optimum of ground improvement. 1he unconfined compression tests are carried out with specimens under various mixing ratios and curing periods of hardening agent to assess the stabilizing ability. The unconfined strengths on site were estimated with various mixing ratios based on the results of the laboratory tests. It was estimated that the improved strength on site was higher than that of the required strength $5.0kgf/cm^2$.

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