• Title/Summary/Keyword: CuO addition

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The Microwave Dielectric Properties of $ZnNb_2O_{6}$ Ceramics with Sintering Temperature and CuO Addition (소결온도와 CuO 첨가에 따른 $ZnNb_2O_{6}$ 세라믹스의 마이크로파 유전특성)

  • 김정훈;김지헌;배선기;이성갑;이영희
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.53 no.7
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    • pp.347-351
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    • 2004
  • The $ZnNb_2O_{6}$ ceramics with CuO(1, 3, 5wt%) were prepared by the conventional mixed oxide method. The ceramics were sintered at the temperature of $950^{\circ}C$$1075^{\circ}C$ for 3hr in air The structural properties and the microwave dielectric properties of $ZnNb_2O_{6}$ ceramics were investigated with sintering temperature and the addition of CuO. Increasing the addition of CuO, the peak of second phase($Cu_3Nb_2O_{8}$) was increased. The grain size of the $ZnNb_2O_{6}$ ceramics with CuO was increased with CuO addition at same temperature. The dielectric constant of $ZnNb_2O_{6}$ ceramics with CuO was increased with sintering temperature and CuO addition. While the quality factor of the $ZnNb_2O_{6}$ ceramics with lwt% CuO depended on sinterability, the quality factor of $ZnNb_2O_{6}$ with 3wt% and 5wt% CuO depended on second Phase due to the CuO addition. The optimum dielectric Properties of $\varepsilon$$_{r}$ = 21.73 Q${\times}$f = 19,276 were obtained from the condition of 3wt% CuO addition and sintering temperature of $1025^{\circ}C$(3hr).

Dielectric Relaxation Properties of 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 Ceramics with CuO Addition (CuO 첨가에 따른 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 세라믹스의 유전 이완 특성)

  • Bae, Seon Gi;Shin, Hyea-Kyoung;Lee, Suk-Jin;Im, In-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.2
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    • pp.80-84
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    • 2015
  • We investigated the dielectric relaxation properties $0.5Ba(Zr_{0.2}Ti_{0.8})O_3-0.5(Ba_{0.7}Ca_{0.3})TiO_3$ ceramics with CuO addition. With increasing CuO addition, the lattice parameter was increased by substitution of small amount $Cu^{2+}$ ion in B-site of $0.5Ba(Zr_{0.2}Ti_{0.8})O_3-0.5(Ba_{0.7}Ca_{0.3})TiO_3$ ceramics. Also the grain size and the maximum dielectric constant of $0.5Ba(Zr_{0.2}Ti_{0.8})O_3-0.5(Ba_{0.7}Ca_{0.3})TiO_3$ ceramics was decreased with increasing amounts of CuO addition. Moreover, the diffused phase transition properties (${\gamma}$) of $0.5Ba(Zr_{0.2}Ti_{0.8})O_3-0.5(Ba_{0.7}Ca_{0.3})TiO_3$ ceramics was increased by compositional fluctuation with increasing of CuO amount, changed from 1.45 at 1 wt% CuO addition to 1.94 at 7 wt% CuO addition.

The Effect of CuO and SiO2 on the Magnetic Properties of Sr-Ferrite (CuO와 SiO2가 Sr-페라이트의 자기적 특성에 미치는 영향)

  • 김동식;김동엽;정원용;오재현
    • Journal of the Korean Ceramic Society
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    • v.26 no.6
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    • pp.747-754
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    • 1989
  • The effects of CuO and SiO2 on the sintered density, grain growth and magnetic properties of Sr-ferrite were investigated. The sintered density of Sr-ferrite is increased with increasing the amount of CuO or SiO2 addition. The grain of Sr-ferrite grow uniformly with the addition of CuO, so remanence increases and coercivity decreases. The addition of SiO2 increase coercivity but does not affect remanence prominently. The sintering temperature above 125$0^{\circ}C$ and SiO2 addition above 0.8wt% causes abnormal grain growth in Sr-ferrite. When CuO and SiO2 are added simultaneouly, remanence does not decrease but coercivity shows low value.

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Effects of CuO on Low-temperature Sintering Characteristics of PSN-PZT System Ceramics (CuO가 PSN-PZT세라믹스의 저온소결 특성에 미치는 영향)

  • 류주현;우원희;오동언;정영호;정광현;정문영;정회승
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.12S
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    • pp.1200-1204
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    • 2003
  • In this study, in order to develop the low temperature sintering ceramics for multi-layer piezoelectric transformer, PSN-PZT system ceramics were manufactured as a function of CuO addition and their dielectric and piezoelectric characteristics were Investigated. CuO addition facilitated densification at low temperature due to the effect of Cu$_2$O-PbO liquid phase. Through the X-ray diffraction pattern study, absence of second phase unwanted was confirmed. Among the specimen to which CuO was added, the 0.6wt% CuO added specimen sintered at 900$^{\circ}C$ and 920$^{\circ}C$ showed the most excellent mechanical quality factor and electromechanical coupling factor, respectively. Besides the densification accelerator, CuO acted as a accepter and increased mechanical quality. Compared with the specimen with no addition sintered at 1150$^{\circ}C$ , the 0.6wt% CuO added specimen sintered at 920$^{\circ}C$ showed the appropriate dielectric and piezoelectric characteristics for multi-layer piezoelectric transformer.

Effect of CuO and $Al_2O_3$ Addition on the Electrical Conductivity of ZnO (ZnO의 전기전도도에 미치는 CuO 및 $Al_2O_3$의 첨가영향)

  • 전석택;최경만
    • Journal of the Korean Ceramic Society
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    • v.32 no.1
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    • pp.106-112
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    • 1995
  • In order to examine the effect of CuO and Al2O3 addition on the electrical conductivity of ZnO, both Al2O3 (0, 1, 2, 5, 10at.%) and CuO (1, 5at.%) were added to ZnO. Al2O3 addition (~2at.% Al) increased the total electrical conductivity of ZnO which was already decreased by CuO doping effect Above solid solubility of Al (~2at.%), ZnAl2O4 formed and the total electrical conductivity decreased due to the decrease of sintered density. Impedance measurements were used to know the reason and degree of contribution of three resistive elements, ZnO grain, ZnO/CuO, and ZnO/ZnO grain boundaries, to the total electrical conductivity changed.

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Piezoelectric and Dielectric Characteristics of Low Temperature Sintering PMN-PZN-PZT Ceramics with the Amount of CuO addition (CuO첨가에 따른 저온소결 PMN-PZN-PZT 세라믹스의 압전 및 유전특성)

  • Lee, Il-Ha;Lee, Kab-Soo;Yoo, Ju-Hyun;Paik, Dong-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.288-289
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    • 2007
  • In this study, in order to develop low temperature sintering ceramics for multilayer piezoelectric actuator application, PMN-PZN-PZT ceramics were manufactured as a function of the amount of CuO addition and their dielectric and piezoelectric characteristics were investigated. With the amount of CuO addition, the physical characteristics of specimens decreased. The specimens showed the optimum value at 0.5wt%CuO addition. Their optimum values were density=$7.93g/m^3$, ${\varepsilon}_r$=1398, kp=0.560, Qm=1706, $d_{33}$=327pC/N, respectively.

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Effects of CuO Addition on the Dielectric Properties of $Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3$ Ceramics (CuO의 첨가가 PMN-PT 세라믹스의 유전특성에 미치는 영향)

  • 김효태;변재동;김인태;김윤호
    • Journal of the Korean Ceramic Society
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    • v.32 no.9
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    • pp.1056-1064
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    • 1995
  • 95Pb(Mg1/3Nb2/3)O3-5PbTiO3 (hereinafter designated as 95PMN-5PT) system was prepared by the columbite-precursor method with 2 mol% excess PbO to compensate the PbO loss during thermal process. The amount of CuO was 1~10 mol%, and the effects of CuO addition on the dielectric properties of this system have been investigated. From the microstructures, XRD analysis and dielectric measurements, the solubility limit of CuO in 95PMN-5PT was found to be around 3 mol%. Lattice parameter and Curie temperature were found to be decreased as the amount of CuO increased up to the solubility limit. This result confirmed that the Cu2+-ions substituted the Pb2+-ions. It was revealed that the addition of CuO on 95PMN-5PT promoted the sinterability and properties. The room temperature dielectric constant, the loss factor and the specific resistivity of the specimens processed with optimum conditions were 23000, 1%, and 8$\times$1011Ω.cm, respectively.

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Effect of CuO on the PSN-PNN-PZT Ceramics (CuO가 PSN-PNN-PZT 세라믹스에 미치는 영향)

  • Nam, Seung-Hyon;Yoo, Ju-Hyun;Lee, Su-Ho;Yoon, Hyon-Sang;Jeong, Yeong-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.701-704
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    • 2003
  • In this study, to develop the low temperature sintering ceramics for multilayer piezoelectric transformer, PSN-PNN-PZT system ceramics were manufactured as a function of CuO addition. Its dielectric and piezoelectric characteristics were investigated. With increasing the amount of CuO addition, grain size was increased and density increased until 0.3wt% CuO. Taking into consideration electromechanical coupling factor(kp) of 0.53, mechanical quality factor(Qm) of 423 and ${\epsilon}r$ of 1759, it can be cincluded that the CuO 0.5wt% added composition sintered at $920^{\circ}C$ is suitable for piezoelectric transformer application if Qm is improved.

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Electromagnetic Properties of Bulk High-Tc Superconductor (벌크형 초전도체의 전기자기적 특성)

  • Lee, Sang-Heon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.2
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    • pp.111-114
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    • 2017
  • In this research, the development of fabrication technique of bulk YBaCuO superconductors for application was studied. In fluence of $BaZrO_3$ addition on magnetization characteristics of thermal pyrolysis textured YBaCuO superconductor was investigated. Fine $BaZrO_3$ particle were dispersed within the textured YBaCuO matrix by means of the thermal pyrolysis processing. Magnetic levitation force for YBaCuO superconductors were obtained using Nd-B-Fe permanent magnet, at 77 K and at the magnetic field from 0 to 5.3 K gauss. In the unadded superconductor and 5 wt% $BaZrO_3$ addition, anomalous magnetization behavior, which is characterized by the intermediate magnetic field, was observed at 77 K. Critical current density was about few hundreds $A/cm^2$ and the magnetic characteristics increased slightly by addition of $BaZrO_3$ powder. Maximum magnetic force was obtained in the YBaCuO superconducting bulk with 3 wt.% $BaZrO_3$ addition.

A Study on the Tribological Characteristics of PTFE Composites-filled with Nano CuO Particles Under a Slow Sliding Speed and Low Load Condition (나노 CuO입자로 충진된 PTFE 나노복합소재의 저속 및 하중 조건에서의 트라이볼로지 특성에 관한 연구)

  • Minhaeng Cho;Junghwan Kim
    • Tribology and Lubricants
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    • v.39 no.3
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    • pp.111-117
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    • 2023
  • This paper presents an experimental investigation of the tribological characteristics of PTFE composites filled with nano CuO particles under low sliding speed and load. All the specimens were prepared by sintering. Before sintering, the mixture of PTFE powder and CuO particles were mixed by a high-speed mixer using CuO volume fractions of 0.2 vol. % and 5 vol. %. Each mixture was sintered at 350 ℃ for 30 min on the steel disk. We conducted ball-on-disk sliding test an hour using a steel ball against PTFE composites, including pure PTFE. The load and sliding speed used was 2 N and 0.01 m/s, respectively. Adding nano CuO particles increases the friction coefficient because of the abrasiveness of hard nano CuO particles. The highest coefficient of frictions was obtained from 5 vol. % CuO. Conversely, the lowest wear of the composites was obtained from the 5 vol. % CuO nanocomposite. This study reveals that the addition of nano CuO particles can lower the wear of PTFE, despite an increase in the coefficient of friction. However, the coefficient friction is still moderate compared to other engineering polymers. In addition, the amount of CuO nano particles has to be optimized to reduce friction and wear at the same time.