• Title/Summary/Keyword: CuNi

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Low Firing Temperature Nano-glass for Multilayer Chip Inductors (칩인덕터용 저온소성 Nano-glass 연구)

  • An, Sung-Yong;Wi, Sung-Kwon
    • Journal of the Korean Magnetics Society
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    • v.18 no.1
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    • pp.43-47
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    • 2008
  • [ $ZnO-Bi_2O_3-Al_2O_3-B_2O_3-SiO_2$ ] nano-glass has been prepared by sol-gel method. The mean particle size was 60.3 nm with narrow size distribution. The nano-galss has been used as a sintering aid for the densification of the NiZnCu ferrites. The ferrite was sintered with nano-glass sintering aids at $840{\sim}900^{\circ}C$, 2 h and the initial permeability, quality factor, density, and saturation magnetization were also measured. The initial permeability of 0.5 wt% nano-glass added toroidal sample for NiZnCu ferrites sintered at $900^{\circ}C$ was 193.3 at 1 MHz. The initial permeability and saturation magnetization were increased with increasing annealing temperature. As a result, $ZnO-Bi_2O_3-Al_2O_3-B_2O_3-SiO_2$ nano-glass systems were found to be useful as sintering aids for multilayer chip inductors.

Portable Amperometric Glucose Detection based on NiS/CuS Nanorods Integrated with a Smartphone Device

  • Heyu Zhao;Kaige Qu;Haoyong Yin;Ling Wang;Yifan Zheng;Shumin Zhao;Shengji Wu
    • Journal of Electrochemical Science and Technology
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    • v.14 no.3
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    • pp.252-261
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    • 2023
  • Glucose detection is particularly important for clinical diagnosis and personal prevention and control. Herein, the smartphone-based amperometric glucose sensors were constructed using the NiS/CuS nanorods (NRs) as sensing electrodes. The NiS/CuS NRs were prepared through a facile hydrothermal process accompanied by the subsequent vulcanization treatment. The morphological and structural properties of NiS/CuS NRs were characterized with SEM, EDS, XRD, and XPS. Electrochemical measurements including cyclic voltammetry, chronoamperometry, and electrochemical impedance spectroscopy display that NiS/CuS NRs can act as highly efficient electrocatalyst for glucose detection. The NiS/CuS NRs electrodes present a wide detection range of 1-8000 µM for glucose sensing with the sensitivity of 956.38 µA·mM-1·cm-2. The detection limit was 0.35 µM (S/N=3). When employed in smartphone-based glucose sensing device, they also display a high sensitivity of 738.09 µA·mM-1·cm-2 and low detection limit of 1.67 µM. Moreover, the smartphone-based glucose sensing device also presents favorable feasibility in determination of glucose in serum samples with the recoveries ranging between 99.5 and 105.8%. The results may provide a promising viewpoint to design other new portable glucose sensors.

A Study of Intermetallic Compound Growth in the Sn/Cu and Sn/Ni Couples (II) : Sheet Resistance and Solderability Changes (Sn/Cu 및 Sn/Ni 계면에서 금속간화합물 형성 및 성장에 관한 연구(II))

  • 김홍석;이성래
    • Journal of the Korean institute of surface engineering
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    • v.22 no.2
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    • pp.47-54
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    • 1989
  • The effects of intermetallic compound growt on the sheet resistance and soldreability as functions of the aging time, the temperature, and the conditions of substrates have been investi-gated in the electroplallic compound (mainy Cu6Sn5and Ni3Sn4) and the number of phase interface increased, the sheet resistance increased. Spread tests showed that the solderability was dereased with the intermetallic compounds growth and increased with the thickness of electroplated Sn. The surface morphology or agin size of the compound layer singificantly affect the solderability. The solderability of Sn/Ni system was superiot to Sn/Ni system was sperior to that of Sn/Cu system and the intermetallic compounds growth was solwer in the former system.

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Research of carbon formation on Ni-YSZ and Cu-Ceria-YSZ to internal reforming using n-Butane (n-Butane 내부개질시 Ni-YSZ와 Cu-Ceria-YSZ에 대한 탄소침적에 관한 연구)

  • Bae, Gyu-Jong;Bae, Joong-Myeon;Park, Kwang-Jin;Kim, Yong-Min
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.9-12
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    • 2008
  • The internal reforming of n-Butane on Ni-YSZ and Cu-Ceria-YSZ was investigated with anode granule at steam to carbon ratio from 0 to 3 and at temperature of $750^{\circ}C$. Although hydrogen production was lager at Ni-YSZ, resistivity for carbon deposition was better at Cu-Ceria-YSZ. These phenomena occur because unwanted side reaction go on with reforming reaction for hydrogen production at Ni-YSZ.

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Effect of Transition-Metal (Ni) on the Superconductor Y-Ba-Cu-O (Y-Ba-Ca-O 초전도체에서 천이금속(Ni)의 효과)

  • Han, Byoung-Sung
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.27 no.5
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    • pp.724-728
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    • 1990
  • The X-ray diffraction pattern, electrical resistance, density and critical temperature of a series of YBa2(Cu3-xNix)O7-\ulcornersamples (0\ulcorner\ulcorner.5) were investigated with the increase of the Ni content. The samples show a principal 1.2.3-like phase with well resolved orthorhombic peaks. The final pattern of the x=0.1 sample appears to be well reacted orthorhombic YBa2(Cu,Ni)3O7-\ulcornerwith minor impurities and an appreciable amorphous fraction. From the above results, we conclude that Ni does not play an important role for the superconductivity in the Y-Ba-Cu-O system.

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Fabrication and Mechanical Properties of Ni-based Amorphous Bulk Alloys (Ni기 비정질 벌크합금의 제조와 기계적 성질)

  • Kim, Sung-Gyoo
    • Journal of Korea Foundry Society
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    • v.22 no.6
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    • pp.288-292
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    • 2002
  • Ni-base amorphous alloys were manufactured using melt-spinning and Cu-mold die casting methods. Amorphous formability, the supercooled liquid region before crystallization and mechanical properties were examined. The reduced glass transition temperature and the supercooled liquid region of $Ni_{51} Nb_{20} Zr_9 Ti_9 Co_8 Cu_3$alloy were 0.621 and 46 K respectively. $Ni_{51} Nb_{20} Zr_9 Ti_9 Co_8 Cu_3$ alloy was produced in the rod shape 3mm diameter using the Cu-mold die casting. Hardness, compression strength, elongation and elastic modulus of the alloy were 850 DPN, 2.75 GPa, 1.8% and 150 GPa respectively. Moreover, compression strength of 2.75 GPa was the highest value in the amorphous bulk alloy produced up to now.

A Study on the Manufacturing Process of Ni-P Doped W-Cu Electric Contacts (Ni-P 합금첨가한 W-Cu계 전기접점 제조에 관한 연구)

  • Lee, J. S.;Shin, H.;Bae, K. W.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1988.10a
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    • pp.64-66
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    • 1988
  • The present investigation has been performed on the manufacturing process of Ni-P doped W-Cu electric contacts by infiltration techniques. The addition of small amount of Ni-P alloy aimed at forming a rigid and homogeneous skeleton structure of W-powders which favours subsequent infiltration process of Cu-melts. The experimental results revealed that the small addition of Ni-P alloy appreciably enhances the sintering process of W at low temperatures (even at 1000$^{\circ}C$), simultaneously causing a considerable change of skeleton Morphology and its related best infiltration behaviour of Cu-melts.

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Effect of Plating Condition and Plating Rate on the Magnetic Properties of Electroless Ni-Cu-P Deposits (무전해 Ni-Cu-P 도금층의 자성에 미치는 도금조건과 도금속도의 영향)

  • Oh, I.S.;Lee, T.H.
    • Journal of Power System Engineering
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    • v.10 no.3
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    • pp.58-66
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    • 2006
  • The effect of bath composition, plating condition and plating rate on the magnetic properties of electroless Ni-Cu-P deposits were investigated. With increasing $CuSO_4$ concentration in the bath, plating rate increased, while the Br value of deposits decreased Sharply. Plating rate increased up to 34% with the addition of 200ppm of NaF and 0.8ppm of Thiourea to the bath. Plating reaction had been ceased by the increase of pH above 11.3, bath temperature higher than $90^{\circ}C$ and under $70^{\circ}C$. The Br value of deposit was uniform with various concentration of complexing agent (Sodium citrate, Ethylenediamine) in the bath. The Br value of deposit was almost equal to that found by the addition of stabilizer(Thiourea) and accelerator(NaF). The Br value of deposit was uniform in plating time(120 min) and heat treatment temperature(below $200^{\circ}C$), and were confirmed to have adequate bath stability for practical use.

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Interfacial Layer and Thermal Characteristics in Ni-Zn-Cu Ferrite and Pb(Fe1/2Nb1/2)O3 for the Low Temperature Co-sintering (저온 동시소결을 위한 Ni-Zn-Cu 폐라이트와 Pb(Fe1/2Nb1/2)O3에서의 열적 거동 및 계면층 특성)

  • Song, Jeong-Hwan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.10
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    • pp.873-877
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    • 2007
  • In order to apply a complex multilayer chip LC filter, this study has estimated the interfacial reaction and coupling properties of dielectric materials $Pb(Fe_{1/2}Nb_{1/2})O_3$ and Ni-Zn-Cu ferrite materials through low-temperature co-sintering (LTCS). PFN powders were fabricated using double calcinated at $700^{\circ}C$ and then $850^{\circ}C$. While the perovskite phase rate was found to be 91 %, after heat treatment at $900^{\circ}C$ for 6h, the perovskite phase rate and density exhibited a value of 100 % and 7.46$g/cm^3$, respectively. The PFN/Ni-Zn-Cu ferrite, PFN/CUO (or $Pb_2Fe_2O_5$) and ferrite/CuO (or $Pb_2Fe_2O_5$) were mechanically coupled through interfacial reactions after the specimen was co-sintered at $900^{\circ}C$ for 6 h. No intermediate layer exists for the mutual coupling reaction. This result indicates the possibility of low-temperature co-sintering without any interfacial reaction layer for a multilayer chip LC filter.

Formation of Electromagnetic Wave Shielding Thin Film on PET Film Substrate and Their Properties (PET 필름상 형성한 전자파차폐용 박막과 그 특성)

  • Im, Gyeong-Min;Lee, Hun-Seong;Bae, Il-Yong;Mun, Gyeong-Man;Choe, Cheol-Su;Lee, Myeong-Hun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2011.05a
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    • pp.205-206
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    • 2011
  • Cu thin films for electromagnetic wave shielding were prepared on PET film and Ni-coated PET film by using Dry and Wet coating method, such as evaporation method, DC sputtering method and copper sulfate($CuSO_4$). After that, Zn thin film and Ni thin film were prepared onto the Cu thin films by using evaporation dry process and Ni electro plating wet process as a finishing treatment, respectively. The result of conductivity test and corrosion resistance test revealed Cu thin films which were formed with bigger grain size and high Cu composition rate have superior properties. Zn thin film by dry evaporation process and Ni thin film by wet electro plating process on Cu thin films were largely contributed to corrosion resistance. However, Ni thin film by wet process made conductivity of all specimen worse, the other hand, Zn thin film by dry process made it better to improve condictivity of specimens just prepared by dry process.

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