• Title/Summary/Keyword: Cu contact

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Fatigue Life Properties of Messenger Wire with Service Environments (가설환경에 따른 조가선의 피로수명 특성)

  • 김용기;장세기;조성일
    • Journal of the Korean Society for Railway
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    • v.6 no.1
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    • pp.21-28
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    • 2003
  • Environment-dependent fatigue life of Cu-Cd alloy wires used as messenger wires was investigated. Tensile test results showed the decrease of tensile strength and elongation of messenger wires by 3.7% and 16.8%, respectively, in used specimens when compared to new ones. Messenger wires used at industrial region for 26 yeras showed 35∼50% decrease in fatigue life, which is partly due to the in stress concentrations by formation of corrosion products at the surface. Single wires showed better fatigue properties than stranded wires, especially at low cycle regions with higher stresses. Stranded wires showed shorter fatigue lives than single wires because of friction between wires by surface contact. Service life of messenger wires was dependent upon the environments which they were exposed to. SO$_2$ and humidity deteriorated the fatigue properties by environmental degradation.

Development of the High Performance Thermoelectric Modules for High Temperature Heat Sources

  • Jinushi, Takahiro;Okahara, Masahiro;Ishijima, Zenzo;Shikata, Hideo;Kambe, Mitsuru
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.79-80
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    • 2006
  • From a viewpoint of heat stress at high temperatures and contact thermal resistance, it is confirmed that the optimal structure is the skeleton structure using Cu substrate on the cooling side, which has excellent heat conductivity and the optimal installation method is to adopt a carbon sheet and a mica sheet to the high temperature side, where Si grease is applied to the low temperature side, under pressurized condition. The power of the developed modules indicated 0.5W in an $FeSi_2$ module and 3.8 W with a SiGe module at 823K, respectively.

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Development of the FCCL Tie-coating layer using a Polymerization (Polymerization을 이용한 FCCL Tie-coating layer 개발 )

  • Hwang, Yeong-Rae;Yun, Yeo-Wan;Kim, Sang-Ho
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.11a
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    • pp.166-168
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    • 2007
  • 스퍼터링법으로 제작된 FCCL은 PI필름(Poly-imide film)과 Cu layer사이에 Tie-coating layer로 Ni-Cr을 많이 사용한다. 하지만 완성된 FCCL에서 페터닝을 실시할 때 Cr성분이 소멸되지 않고 잔존하는 현상으로 누설전류가 발생 한다. 또한 Cr으로 인해 Eatching액의 오염으로 재사용의 어려움도 발생된다. 이러한 원인들은 제품의 특성들을 저하 시키므로 이를 개선할 필요가 있다. 따라서 본 연구에서는 기존의 Tie-coating layer를 대체할 물질로 Acrylic acid를 이용하여 FCCL을 제작하여 표면특성 평가를 위해 Contact angle측정과 부착력을 위한 Peel test측정과 조직분석 및 성분분석을 위해 SEM-EDS를 측정을 통하여 Polymerization을 이용한 Ti-coating layer 개발의 가능성을 확인하였다.

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Self-Assembled Monolayers of Alkanethiols on Clean Copper Surfaces

  • Sung, Myung M.;Kim, Yeon Su
    • Bulletin of the Korean Chemical Society
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    • v.22 no.7
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    • pp.748-752
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    • 2001
  • Alkanethiols (CH3(CH2)n-1SH) based self-assembled monolayers (SAMs) on the clean copper surfaces have been examined for n = 4, 8, and 16. Using X-ray photoelectron spectroscopy (XPS) and contact angle analysis, it is found that alkanethiolate monolayers similar to those on gold are formed on clean copper surfaces. The monolayers are stable in air up to about 140 $^{\circ}C.$ Above 160 $^{\circ}C$ the monolayers begin to desorb through the oxidation reaction of the thiolate to sulfonate, with the alkyl chains remaining intact. Following this desorption step, the copper surface has begun to oxidize to CuO at about 180 $^{\circ}C$.

Experimental Study on Film Boiling of CuO-Water Nanofluid Droplets (산화구리-순수 물 나노유체 액적의 막비등에 관한 실험적 연구)

  • Yeung Chan Kim
    • Journal of ILASS-Korea
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    • v.29 no.3
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    • pp.134-139
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    • 2024
  • An experimental study was conducted on the film boiling of nanofluid droplets at a surface temperature range of 300 to 500℃. The nanofluid was made by mixing pure water with copper oxide powder of diameter of 80 nm. The initial volume of the nanofluid droplet ranged from about 21 to 44 ㎕, and the volume, base diameter, and time were measured during the evaporation process. It was found that nanofluid droplets evaporate faster as the surface temperature increases. Also experimental results showed the droplets evaporate quickly at the beginning of evaporation, but as the volume of the droplets decreases, the evaporation rate gradually slows down, and this trend becomes stronger as the surface temperature increases. In addition, the evaporation rate of nanofluid droplets was slightly faster than that of pure water droplets, this was believed to be because the contact area of nanofluid droplets increased.

Potential Element Retention by Weathered Pulverised Fuel Ash : I. Batch Leaching Experiments (풍화 석탄연소 고형폐기물(Pulverised Fuel Ash)의 중금속 제거가능성 : I. 뱃치 용출실험)

  • Lee, Sanghoon
    • Economic and Environmental Geology
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    • v.28 no.3
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    • pp.251-257
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    • 1995
  • Three PEA (Pulverised Fuel Ash) samples, which were fresh, 17 and some 40 years weathered, were collected from two major British power plants. Batch leaching tests with these samples using distilled water and simulated industrial leachate showed higher amounts of element liberation from fresh ash, including Ca, Na, K, S (as $SO^{2-}_4$, $Cr_{total}$, Cu, Li Ni, Mo and CI and this seems to indicate their surface association and easier dissolution when contact with water. On the contrary Mg, Al, Ba, Si, V, As and Se do not show such readily leachable concentrations and these elements might be more associated with glass fraction in PFA particle rather than surface. Although element concentrations in the weathered ash are much lower than those in the initial leachate from the fresh ash, elements are still detected as resonable concentrations, with rather constant levels and this seems to demonstrate the element release from unstable glass phase of PFA particle. Fe, Ca, $Cr_{total}$, Cu, Ni, Zn and Hg were removed from the synthetic leachate by PFA and this is also confirmed by gain in solid PFA. The order of element retention is Meaford weathered ash > Drax weathered ash > Drax fresh ash in decreasing order and this conforms with the degree of weathering. Namely, the more wethered, the more wethered, the more effective in metal retention from the synthetic leachate.

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Magnetoresistance of IrMn-Based Spin Filter Specular Spin Valves (IrMn 스핀필터 스페큘라 스핀밸브의 자기저항 특성)

  • Hwang, J.Y.;Rhee, J.R.
    • Journal of the Korean Magnetics Society
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    • v.14 no.6
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    • pp.236-239
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    • 2004
  • We studied the specular spin valve (SSV) having the spin filter layer (SFL) in contact with the ultrathin free layer composed of Ta3/NiFe2/IrMn7/CoFel/(NOLl)/CoFe2/Cu1.8/CoFe( $t_{F}$)/Cu( $t_{SF}$ )/(NOL2)/Ta3.5 (in nm) by the magnetron sputtering system. For this antiferromagnetic I $r_{22}$M $n_{78}$-pinned spin filter specular spin valve (SFSSV) films, an optimal magnetoresistance (MR) ratio of 11.9% was obtained when both the free layer thickness ( $t_{F}$) and the SFL thickness ( $t_{SF}$ ) were 1.5 nm, and the MR ratio higher than 11% was maintained even when the $t_{F}$ was reduced to 1.0 nm. It was due to increase of specular electron by the nano-oxide layer (NOL) and of current shunting through the SFL. Moreover, the interlayer coupling field ( $H_{int}$) between free layer and pinned layer could be explained by considering the RKKY and magnetostatic coupling. The coercivity of the free layer ( $H_{cf}$ ) was significantly reduced as compared to the traditional spin valve (TSV), and was remained as low as 4 Oe when the $t_{F}$ varied from 1 nm to 4 urn. It was found that the SFL made it possible to reduce the free layer thickness and enhance the MR ratio without degrading the soft magnetic property of the free layer.

Fabrication and characterization of the nano- and micro-particles applied dry adhesives (나노 또는 마이크로 입자의 전사를 이용한 건식 접착제의 제조 및 특성 분석)

  • Yu, Min Ji;Vu, Minh Canh;Han, Sukjin;Park, Jae Hong;Kim, Sung-Ryong
    • Journal of Adhesion and Interface
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    • v.20 no.1
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    • pp.23-28
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    • 2019
  • In this study, the micro- and nano-particles were used and their shapes were transferred into the polydimethylsiloxane (PDMS) film to fabricate the dry adhesives and their properties were investigated. The Cu nanoparticles of the sizes of 20 nm, 40 nm and 70 nm and the polymethylmethacrylate (PMMA) beads of the size of $5{\mu}m$ were used to transfer their images and the resultant properties of the dry adhesives were compared. The effects of particle size and materials on the mechanical property, tensile adhesion strength, light transmittance, surface morphology, water contact angle were studied. The dry adhesives obtained from the transfer process of Cu nanoparticles with the size of 20 nm resulted in the enhancement of tensile adhesion strength more than 300% compared to that of the bare PDMS. The formation of nanostructure of large surface area on the surface of the PDMS film by the Cu nanoparticles may responsible for the improvement. This study suggests that the use of nanoparticles during the fabrication of PDMS dry adhesives is easy and effective and could be applied to the fabrication of the medical patch.

Effect of Soil Properties on Leaching of Preservative Components from CCA-treated Wood (토양 특성이 CCA 처리재로부터 방부제 성분의 용탈에 미치는 영향)

  • Jeong, Yong Gi;Kim, Gyu-Hyeok
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.6 s.134
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    • pp.87-94
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    • 2005
  • This study was carried out to investigate the effect of soil types and soil properties on wood preservative leaching. Radiata pine (Pinus radiata Don.) sapwood stakes, which had been treated with 2.0%(w/v) CCA, were leached for 12 weeks by a common laboratory method in four different soils and for 14 days by the AWPA standard leaching method in water. The physical and chemical properties of the four soils were determined, and the percent leaching of the individual component of CCA was correlated with the various soil properties. The data show that leaching of preservative chemicals from treated wood exposed to soil is influenced by the type of soil. The preservative leaching was greater when wood was exposed to water than when the wood was in contact with water-saturated soil. The greatest chromium, copper and arsenic leaching from CCA-treated stakes were observed in the sandy loam, loam, and sand, respectively, and the least amount of leaching of CCA components occurred in the silty loam. The leaching of preservative components from treated wood is extremely complex and appears to be influenced differently by the soil properties. The extent of copper leaching from CCA treated wood appears to be related to exchangeable Mg and sum of bases. There is a reasonably good relationship between chromium leaching and exchangeable Mg, and between arsenic leaching and exchangeable K, soil Ni, Mn, Fe, Cr, or Cu content. Since this study was conducted based on laboratory leaching method using small cross-sectional dimensions; thus, data obtained from this experiment should not be used to predict leaching characteristics from commercial-size wood used in real situation. Accordingly, further studies are necessary using outdoor ground-contact leaching.

A Study on Wetting Behaviors of Al-Coated $SiC_f$ Composite (Al-$SiC_f$ 복합재료에서 보강재의 coating처리가 젖음성에 미치는 영향)

  • Kim, Kyun-Young;Lee, Kyung-Ku;Choi, Dap-Chun;Lee, Doh-Jae
    • Journal of Korea Foundry Society
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    • v.14 no.3
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    • pp.274-284
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    • 1994
  • SiC fibers were coated with Cu, Ag and Ni metallic thin films by magnetron sputtering in order to improve wetting properties between Al matrix and SiC fiber. The wetting behavior of metal coated SiC fiber by pure Al has been studied at $670^{\circ}C{\sim}900^{\circ}C$ range for $10{\sim}90min$. under vacuum atmosphere. Besides, the effect of coated film thickness on the wettability has been investigated. The wetting behavior and interfacial reaction between Al and SiC fibers were analysed with optical microscope and SEM (scanning electron microscope). The wetting behavior of the as-received SiC fiber with Al melt was not uniform, indicated by the contact angles from less than $90^{\circ} to more Al melt was appeared in the initial stage of reation. It was considered that the metallic thin film played an important role in reducing the interfacial free energy and breaking down the aluminum oxide film by eutectic reaction with Al melt. However the wettability of Ni coated SiC fiber was not improved as much as that of Cu or Ag coated SiC fiber. The improvement of wettability by coating thickness is clearly showed in $1{\mu}m$ coated SiC fiber compared with $0.25{\mu}m$ coated SiC.

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