• Title/Summary/Keyword: Cu Oxide

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ENHANCEMENT OF PHOTOVOLTAIC PERFORMANCE IN COPPER PHTHALOCYNINE THICK FILM SOLAR CELLS

  • Ruiono, Yo Tomota;Momose, Yoshihiro;Takeuchi, Manabu
    • Journal of the Korean institute of surface engineering
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    • v.29 no.6
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    • pp.673-677
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    • 1996
  • Copper phthalocyanine(CuPc) thick film solar cells were fabgricated byspin coating and their photovoltaic behavior was studied. Polyvinylidene fluoride (PVdF) was used for the binder. Aluminum and indium were employed as electrode metals to form Schottky contact to CuPc layer. The cells showed rectifying J-V characteristics in the dark and photovoltaic effect associated with white light irradiation. The photovoltaic performance of the cells strongly depended on contact metals, in which the formation of oxide layer between binder layer and electrode interface affected the solar cell. Influnce of the CuPc layer thickness, CuPc/PVdF ratio on the photovoltaic performance of the cells were also examined.

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Formation of $YBa_2Cu_3O_x$ and the microstructure of melt infiltration processed YBCO superconductors

  • Kim, C.J.;Lee, D.M.;Park, H.S.;Jee, Y.A.;Hong, G.W.
    • Progress in Superconductivity
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    • v.1 no.2
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    • pp.89-94
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    • 2000
  • A YBCO superconductor was prepared in a short time by a melt infiltration process that utilizes meting of $Ba_3Cu5O_8$ powder and the infiltration into a porous $Y_2BaCuO_5$ compact. The processing parameters such as a reaction temperature and time, and atmosphere (air and $O_2$) were controlled to establish the fabrication condition. The formation of a $YBa_2Cu_3O_x$, phase and the developed microstructure are reported.

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Preparation of Cu2(btc)3-AAO Hybrid Membrane by Layer-by-layer Technique (Layer-by-layer 기법을 통한 Cu2(btc)3-AAO 하이브리드 분리막의 제조)

  • Yoo, Hyeonseok;Choi, Jinsub
    • Journal of the Korean institute of surface engineering
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    • v.51 no.1
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    • pp.21-26
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    • 2018
  • The $Cu_2(btc)_3$ metal-organic frameworks (MOF) coated anodic aluminum oxide (AAO) membrane was successfully prepared by layer-by-layer technique using hand spray method. It was confirmed that the $Cu_2(btc)_3$ layer, which has the pore sized in 2-3 nm, on surface of AAO exhibited the polycrystalline thin film structure by XRD analysis. More than 100 repetitive spray cycles were required to obtain more robust and thick MOFs on AAO and it was possible to uniformly coat both the top and bottom surfaces of the AAO. It should be noted that the MOFs also could be coated on surface of pores resulting in reduce the size of pore from 52 nm to 32 nm.

Microstructure and Prooperties of Y-Ba-Cu-O Superconductor Fabricated by Hot Isostatic Pressing (열간정수압소결(HIP)시킨 Y-Ba-Cu-O 초전도체의 조직과 특성)

  • 신미남;백수현;송진태
    • Journal of the Korean Ceramic Society
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    • v.26 no.2
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    • pp.267-275
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    • 1989
  • YBa2Cu3O7-x oxide superconductors were fabricated by sintering and hotisostatic pressing (HIP), and their microstructures and properties were compared with each other. Thougha part of the second phase was observed along grain boundaries, their structures were consisted of single (123) phase and they had many porosities. But, porosities were remakably reduced by Hiping and the densification was brought about. The structure of (123) compound also showed a number of twins, which are typical of high Tc superconductors. The on-set temperature of YBa2Cu3O7-x compound sintered at 96$0^{\circ}C$ in oxygen and hipped at 88$0^{\circ}C$ was highest, but that shwoed 0 resistance at 87$^{\circ}$K, which is a little lower than the compound sintered at 96$0^{\circ}C$. HIP treatment also increased the critical current density of as-sintered compound. However, its value was low, which may be ascribed to the many pores of starting-sintered compact and partially to the second phase along grain boundaries.

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Electromagnetic Characteristics of Superconducting Ceramics for Electrical Power Devices (전력기기 적용을 위한 초전도 세라믹의 전기자기적 특성)

  • Lee, Sang-Heon
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.2
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    • pp.349-351
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    • 2011
  • The formation of oxide superconducting phase fabrication of superconducting wire materials and fabrication of precise superconducting material were studied for developing superconductor application technique. The $ZrO_2$ addition reduced the particle size $BaZrO_3$ trapped in the matrix after the sintering growth. The added $ZrO_2$ was converted to fine particles of $BaZrO_3$ which is the conventional sintering temperature for YBaCuO, $Y_2Ba_1Cu_1O_5$ and CuO are formed as by products of the reaction between $ZrO_2$ and YBaCuO phase. The formation of highly $BaZrO_3$ particle appears to be responsible for the refinement of $BaZrO_3$ phase after the citric acid sintering process.

Photocurrent Multiplication Process in OLEDs Due to a Crystalline of Hole Injection Layer of Copper(II)-phthalocyanine and a Light Irradiation (유기발광소자내 정공주입층 Copper(II)-phthalocyanine의 결정 및 광원에 따른 Photocurrent 증폭 연구)

  • 임은주;박미화;윤순일;이기진;차덕준;김진태
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.7
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    • pp.622-626
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    • 2003
  • We report the electrical properties of organic light emitting diodes (OLEDs) depending on the crystal structure of hole injection layer of copper(II)-phthalocyanine(CuPc) and the light irradiation the carrier mobility of copper(II)-phthalocyanine(CuPc) of light source. OLEDs were constructed with indium tin oxide(ITO)/CuPc/triphenyl-diamin(TPD)/tris-(8-hydroxyquinoline)aluminum(Alq$_3$)/Al.Photocurrent multiplication of OLEDs was varied by the heat-treatment condition of CuPc thin film and the light irradiation.

Effects of Substrate and Sintering Conditions on the Properties of Screen Printed Bi-Pb-Sr-Ca-Cu-O Superconduction Thick Films (Screen printing 방법에 의한 후막형 Bi-Pb-Sr-Ca-Cu-O 초전도체의 소결조건과 기판의 초전도성에 미치는 영향)

  • 김혜동;임호빈
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1990.10a
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    • pp.26-30
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    • 1990
  • Bi$\_$0.7/Pb$\_$0.3/Sr$_1$Ca$_1$Cu$\_$1.8/Ox thick films were screen printed on magnesia(MgO), silver and yttrium stabilized zirconia (YSZ) substrates and were sintered in a boat with cover to prevent the evaporation. The high-Tc phase increase and the low-Tc phase and Ca$_2$PbO$_4$ decrease with an increase in sintering temperature from 835$^{\circ}C$ to 860$^{\circ}C$. YSZ substrate interact strongly with the oxide resulting in poor superconductor, while the Ag and MgO substrates were satisfactory to make screen printed superconductors. The Bi$\_$0.7/Pb$\_$0.3/Sr$_1$Ca$_1$Cu$\_$1.8/Ox thick films screen printed both on Ag and MgO substrates show high Tc phase of ~85% and Tc of 96K.