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Determination of Nutrient Contents of Liquid Pig Manure and the Correlation of Components as Fertilizer in Western JeJu Area (제주 서부지역 양돈장에서 생산된 돈분액비의 비료성분과 그 성분간 상관관계)

  • Song Sang-Taek;Kim Mun-Chol;Hwang Kyoung-Jun
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.26 no.1
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    • pp.15-24
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    • 2006
  • This study was conducted to make a rapid and easy determination for the fertility of liquid pig manure as fertilizer by investigating the contents, and correlation coefficients of various nutrients. Samples were collected from 118 local pig farms in the western area of Jeju in Korea. Electrical conductivity(EC), dry matter(DM), $NH_4-N$ and minerals were determined and the relationships among them were examined. The collected liquid manure samples from 118 pig farms were classified according to the level of DM contents ;< 3% (92 farms), $3{\sim}6%$ (18 farms), $6{\sim}9%$ (5 farms) and>9% (3 farms), based on the collected data, most of the liquid manure coming from the local pig farms contain small amount of dry matter. The dry matter contents appeared highly correlated(p<0.01) with EC, $NH_4-N$, T-P, Ca, Mg and Na, except for K. In addition EC was proportional to $NH_4-N$, T-P, Ca, and Na except fer Mg. The fertilizer component ratio of $NH_4-N$, P and K in liquid pig manure were not constant, resulting in low efficiency for fertilizer. However, the toxic heavy metals of Cu etc. were below the criteria of organic fertilizer and soil contamination evaluation. Therefore, we concluded that both dry matter content and electrical conductivity could be used as an indicator for evaluating the fertility of liquid pig manure.

Effects of Surface Finishing Methods on Quality of Kimchi in Stand Vessel During Storage (김치표면 마감 방법이 저장중인 김치의 품질에 미치는 영향)

  • Kim, Joong-Man;Hwang, Shin-Mook;Choi, Yong-Bae;Kim, Hyong-Tae
    • Journal of the Korean Society of Food Culture
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    • v.7 no.4
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    • pp.297-301
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    • 1992
  • To investigate effects of the surface finishing methods (A : conventional press stone, B : enclosing in polyethylene (PE) bag, C : press-tone wrapped with PE film and D : covered with Chinese cabbage leaves 4cm in thickness on Kimchi) on Kimchi quality, pH-values, redness, film forming yeast growth, hardness and sensory quality of Kimchi during storage (for 60 days, at $10{\pm}5^{\circ}C$) in glass vessel $(11{\times}30cm)$ were investigated. pH of the top layer of A, C and D sample were higher than the optimum pH (4.2) of Kimchi, film forming yeast occurred on the surface of Kimchi, color of top layer Kimchi juice was darkened, and panel score of freshness and firmness was significantly worse (p<0.01) than that of sample B. However, in the case of Kimchi stored in PE bag (B), film forming yeast were can't detected visually in the surface of Kimchi, pH values were low as good quality Kimchi, freshness and firmness panel scores and hardness were significantly better (p<0.01) than A, C and D, and redness of juice of top layer of B was also preserved clearly for 60 days. Accordingly among the four surface finishing methods, the B-method was most effective in preserving of y of Kimchi.

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Peel strengths of the Composite Structure of Metal and Metal Oxide Laminate (Metal과 Metal Oxidefh 구성된 복합구조의 Peel Strength)

  • Shin, Hyeong-Won;Jung, Taek-Kyun;Lee, Hyo-Soo;Jung, Seung-Boo
    • Journal of the Microelectronics and Packaging Society
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    • v.20 no.4
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    • pp.13-16
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    • 2013
  • A lot of various researches have been going on to use heat spreader for LED module. Nano porous aluminum anodic oxide (AAO) applied LED, which is produced from anodization, is easy and economically advantageous. Convensional LED module is consist of aluminum/adhesive/copper circuit. The polymer adhesive in this module is used as heat spreader. However the thermal emission of LED component is degraded because of low heat conductivity of polymer and also reliability of LED component is reduced. Therefore, AAO in this work was applied to heat spreader of LED module which has higher heat conductivity compare to polymer. Bonding strength between AAO and copper circuit was improved with Ti/Cu seed layer by copper sputtering process (DBC) before the bonding. And this copper circuit has been fabricated by electro plating method. Peel strength of AAO and copper circuit in this work showed range between 1.18~1.45 kgf/cm with anodizing process which is very suitable for high power LED application.

Re-evaluation of Genetic Environments of Zinc-lead Deposits to Predict Hidden Skarn Orebody (스카른 잠두 광체 예측을 위한 아연-연 광상 성인의 재검토)

  • Choi, Seon-Gyu;Choi, Bu-Kap;Ahn, Yong-Hwan;Kim, Tae-Hyeong
    • Economic and Environmental Geology
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    • v.42 no.4
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    • pp.301-314
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    • 2009
  • The Taebaeksan mineralized province, which is the most important one in South Korea, is rich in zinc-lead-tungsten-iron-copper-molybdenum-silver-gold mineral resources and has a diversity of deposit styles. These deposits principally coexist in time and space with porphyry-related epigenetic deposit such as skarn, hydrothermal replacement, mesothermal vein, and Carlin-like deposits. The magmatic-hydrothermal systems in the Taebaek fold belt is genetically characterized by the Bulguksa subvolcanic rocks(ca. $110{\sim}50\;Ma$) related to northwestward subduction of the paleo-Pacific Plate. The most important zinc-lead deposits in the area are the Uljin, Yeonhwa II and Shinyemi skarn, the Janggun hydrothermal replacement, and the Yeonhwa I intermediate-mixed (skarn/hydrothermal replacement) ones. In the present study, we present a compilation of metal production and mineral assemblage of the zinc-lead deposits. The metal difference of deposit styles in the area indicates a cooling path from intermediate-sulfidation to low-sulfidation state in the polymetallic hydrothermal system, reflecting spatial proximity to a magmatic source.

Magmatism and Metamorphism of the Proterozoic in the Northeastern Part of Korea : Petrogenetic and Geochemical Characteristics of the Okbang Amphibolites (한국(韓國) 북동부지역(北東部地域) 원생대(原生代)의 화성활동(火成活動)과 변성작용(變成作用) : 옥방(玉房) 앰피볼라이트의 암석성인(岩石成因)과 지구화학적(地球化學的) 특징(特徵))

  • Chang, Ho-Wan;Lee, Dong-Hwa;Park, Kye-Hun
    • Economic and Environmental Geology
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    • v.26 no.4
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    • pp.489-498
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    • 1993
  • The Okbang amphibolites occurring as sill-shaped bodies within the Precambrian Wonnam Group have been studied in terms of geochemical characteristics for their tectonomagmatic environments. The amphibolites fall in the ortho-amphibolite fields in Ni and Cr versus Cu diagrams. They belong to subalkaline and tholeiitic series in total alkali versus silica and ternary AFM diagrams, respectively. They show the compositional variation corresponding to the differentiation trend of tholeiitic suites. In discrimination diagrams using high-field-strength elements such as Ti, Zr, Nb and Y, the amphibolites show geochemical affinities to both of volcanic-arc tholeiites and normal (depleted) mid-oceanic ridge tholeiites. The REE patterns of the amphibolites are nearly flat and extremely similar to those of back-arc tholeiites. $(La/Yb)_{CN}$ ratios vary from 0.89 to 2.02 with an average value of 1.23. Such low light-REE abundances in the amphibolites suggest that they were derived from the upper mantle source depleted in these elements. In view of geochemical characteristics showing strong enrichments of incompatible elements such as K and Rb, distinctive negative Nb anomalies, depletions of light-REE observed also in normal (depleted) mid-oceanic ridge tholeiites, and unfractionated immobile elements such as Y and Yb, the tholeiitic magmas, from which the parent rocks of the amphibolites were formed, would be generated from a depleted upper mantle source and contaminated by continental crustal materials en route to surface. Tectonomagmatic environment for the amphibolites can be assumed to be continental back-arc basin.

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Study on Geochemical Behavior of Heavy Metals by Indigenous Bacteria in Contaminated Soil and Sediment (국내 일부 오염 토양 및 퇴적물 내 토착 미생물에 의한 중금속의 지구화학적 거동 연구)

  • Song, Dae-Sung;Lee, Jong-Un;Ko, Il-Won;Kim, Kyoung-Woong
    • Economic and Environmental Geology
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    • v.40 no.5
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    • pp.575-585
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    • 2007
  • Microbial control of the geochemical behavior of heavy metals (Cd, Cu, Pb, and Zn) and As in contaminated subsurface soil and sediment was investigated through activation of indigenous bacteria with lactate under anaerobic condition for 25 days. The results indicated that dissolved Cd, Pb and Zn were microbially removed from solutions, which was likely due to the formation of metal sulfides after reduction of sulfate by indigenous sulfate-reducing bacteria. Soils from the Dukeum mine containing a large amount of sulfate resulted in complete removal of dissolved As after 25 days by microbial activities, while there were gradual increases in dissolved As concentration in soils from the Hwabuk mine and sediments from the Dongducheon industrial area which showed low $SO_4{^2-}$ concentrations. Addition of appropriate carbon sources and sulfate to contaminated geological media may lead to activation of indigenous bacteria and thus in situ stabilization of the heavy metals; however, potential of As release into solution after the amendment should be preferentially investigated.

Mineralogy and the Behavior of Heavy Metals at Different Depths in Tailing Impoundment of the Samsanjeil mine (삼산제일광산 광미 매립지의 매립 심도에 따른 광물 변화 및 중금속의 거동)

  • Kim, Heong-Jung;Kim, Yeong-Kyoo;Choo, Chang-Oh
    • Journal of the Mineralogical Society of Korea
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    • v.22 no.3
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    • pp.229-240
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    • 2009
  • In Gosung, the symptoms similar to itai-itai disease from neighboring residents of the Samsanjeil mine have been social issues. Therefore, various researches on the behavior of heavy metals of the tailings impoundment of 280,000 ton in the Samsanjeil mine are required. In this paper, mineralogical and geochemical studies on the tailings at different depths in the Samsanjeil mine were investigated and the factors on the behavior of heavy metals were also studied. At two sampling sites (NN and SN), samples were collected at different depths down to 1 m. At NN sites, pH values decreased with depth, while those at SN sites did not show significant changes. XRD analysis showed that the main minerals in the tailings were quartz, microcline, muscovite, and chlorite with minor amount of gypsum. There were no noticeable changes in the mineral composition with depth. At NN sites, the amount of calcite was negligible, and jarosite, which usually occurs at acid soil or acid mine drainage at pH lower than 4, was identified. However, the samples at SN site contained relatively high contents of calcite with pyrite. Therefore, calcite seemed to buffer the acid and control pH at SN site. The contents of heavy metals in tailings were in the order of Cu > As > Zn > Pb > Co > Cr > Ni > Cd. The heavy metal concentrations in the tailings were closely related with pH changes. The concentrations of Cd and Co were much lower at NN site at which pH values are low than those at SN sites. Contrary to that, Cr and As which exist as oxyanions showed higher concentrations at SN sites. This result showed that the behaviors of heavy metals in our study area were controlled by pH which is influenced by the contents of calcite.

Distribution of Total Mercury in Korean Coastal Sediments (한반도 연안역 표층퇴적물 내 총 수은 분포 특성)

  • JOE, DONGJIN;CHOI, MANSIK;KIM, CHANKOOK
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.23 no.2
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    • pp.76-90
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    • 2018
  • To determine the distribution of mercury (Hg) in the coastal surface sediments around the Korean peninsula, the baseline concentration of Hg was estimated, the extent of contamination was assessed, and the factors controlling the distribution were discussed. The concentrations of Hg in surface sediments were significantly high in Jinhae-Masan Bay in the South Sea, Ulsan-Onsan Bay and Yeongil Bay in the East Sea, but Hg in other sediments showed a similar distribution to Cs and relatively very low concentration between 0.21 and $39.5{\mu}g/kg$ ($13.6{\pm}7.80{\mu}g/kg$). Compared to the sediment quality guidelines in Korea, 8 % of the surface sediments (n=282) analyzed in this study exceeded the values of the threshold effects level (TEL), and six sediments collected around Onsan Port were higher than the value of the probable effects level (PEL). The contamination levels of Hg were assessed by the enrichment factors using the baseline concentration (2.06Cs+1.75) based on the residual analysis from the linear regression line for Cs, and further, factors controlling the distribution of Hg were discussed by the comparison with geochemical substances depending upon the Hg enrichment level. Hg concentrations were correlated well with Cs concentration in the range of less than 1.69 of EF implying grain size control, while in the range of 1.69 and 4.03 Hg concentrations were correlated well with Fe oxyhyroxide and organic carbon contents, which indicates Hg was enriched by superior sorption capability. On the meanwhile, samples with higher EFs (4.03 to 74.9) showed fairly positive correlations with other metals (Cu, Zn, Pb) rather than geochemical substances. For samples in Youngil Bay and Ulsan-Onsan Bay (n=30), Hg concentrations were correlated only with other metals rather than geochemical substances implying simultaneous supply of metal particles from metal refineries. But samples at Gosung, Sokcho and Uljin coast were correlated well with organic carbon even though they had high EFs. In addition, samples in Jinhae-Masan Bay with high contents of S were enriched by relatively high sulfide formation.

The Optimal Combination of Major Nutrients Computed by the Homès Systematic Variation Technique II. Determination of the Optimal Combination of Cations K:Ca:Mg in Fertilization on the Various Grassland Soils (Homes 방법(方法)에 의(依)한 다량요소(多量要素)의 적정시용(適正施用) 비율(比率) 결정(決定)에 관(關)한 연구(硏究) II. 초지토양별(草地土壤別) 음(陰)이온 N : Ca : Mg 적정시용(適正施用) 비율(比率))

  • Jung, Yeun-Kyu;Yoon, Sang-Gi;Weinberger, P.
    • Korean Journal of Soil Science and Fertilizer
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    • v.14 no.1
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    • pp.37-43
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    • 1981
  • This pot experiment was conducted to find out the optimal fertilization ratio of the cations(K: Ca: Mg) in various soil conditions. Soil samples were collected from uncultivated mountains and hills where development for grass lands is under consideration. The optimum ratios were computed by the Homes systematic variation technique. The results were summarized as follows : 1. The optimum fertilization ratios of the cations (K : Ca : Mg) for the high yields of grass-clover mixed sward at various areas were obtained (Table 4) 2. The relatively high optimum fertilization ratios of K in Daegu and Taegwalryong, Ca in Unbong, and Mg in Cheju district gave the high yields of clover in mixed sward. They were positively related to the low contents of the above cations in the soils or the relatively low content ratio comparing with other cations. 3. The yields of clover in mixed sward were seriously affected by the changes in both the fertilization ratio and total concentration of cations comparing to those of the grass yields. As a consequence, total yields, quality, and botanical composition of the mixed sward were also affected. 4. The antagonis among the cations K, Ca, and Mg was known from the point of mineral contents of grass and clover. 5. The equivalent ratio K/(Ca+Mg) or grass was greatly increased by the range of 2.4 and 3.3 in the K-group treatment, which was higher than the critical level 2.2 of grass tetany, otherwise that. of clover by the range of 0.9 and 1.2. Therfore, it may be concluded that if the botanical composition of grass/legume sward is optimum, the incidence of grass tetany can be eliminated.

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Distribution and properties of intertidal Surface Sediments of Kyeonggi Bay, West Coast of Korea (경기만 조간대 표층퇴적물의 분포와 특성)

  • LEE, CHANG-BOK;YOO, HONG-RHYONG;PARK, KYUNG-SOO
    • 한국해양학회지
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    • v.27 no.4
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    • pp.277-289
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    • 1992
  • Kyeonggi Bay, a macrotidal coastal embayment in the Yellow Sea coast of central korea, is fringed by vastly developed tidal flats. About 400 surface sediment samples were collected from the intertidal and subtidal zones of Kyeonggi Bay for a study of the sediment distribution pattern and the surface sediment characteristics of this environment. The kyeonggi Bay surface sediment becomes progressively finer in the shoreward direction, from offshore sand to shoreward silty sand and sandy silt. This shoreward-fining trend is repeated again on the tidal flat and, as a consequence, a grain-size break occurs near the low-water line which separates the intertidal area from the subtidal one. The intertidal and subtidal sediments differ from each other in textural characteristics such as mean grain size and skewness and this can be interpreted to result from differences in hydraulic energy and morphology between the two environments. The mineral and chemical compositions of the Kyeonggi Bay sediments are largely controlled by the sediment grain size. Smectite was nearly absent in the clay mineral assemblage of Kyeonggi Bay sediment. The contents of Co, Cu and Ni were high in the Banweol tidal flat, which suggests a continuous process of accumulation of these metals. the intertidal environment appears to respond rapidly to artificial coastal modifications, the effects of which should be taken into consideration when planning a dam construction or coastal reclamation.

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