• 제목/요약/키워드: Crystallinity and Electrical Properties

검색결과 345건 처리시간 0.023초

증착온도에 따른 SBN 박막의 미세구조 및 특성 (Microstructure and Properties of SBN Thin film with Deposition Temperature)

  • 김진사;최운식;김충혁
    • 전기학회논문지
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    • 제58권3호
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    • pp.544-547
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    • 2009
  • The $Sr_{0.7}Bi_{2.3}Nb_{2}O_{9}$(SBN) thin films are deposited on Pt-coated electrode(Pt/Ti/$SiO_2$/Si) using RF sputtering method at various deposition temperature. The optimum conditions of RF power and Ar/$O_2$ ratio were 60[W] and 70/30, respectively. Deposition rate of SBN thin films was about 4.17[nm/min]. The crystallinity of SBN thin films were increased with increase of deposition temperature in the temperature range of $100{\sim}400[^{\circ}C]$, the surface rougness showed about 4.33[nm]. The capacitance of SBN thin films were increased with the increase of deposition temperature.

다중벽 카본나노튜브가 보강된 고분자 나노복합체의 기계적, 열적, 전기적 특성 (Mechanical, Thermal and Electrical Properties of Polymer Nanocomposites Reinforced with Multiwalled Carbon Nanotubes)

  • 국정호;허몽영;양훈;신동훈;박대희;나창운
    • 폴리머
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    • 제31권5호
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    • pp.422-427
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    • 2007
  • 반도전층은 전력케이블의 도선과 고분자 절연층 사이에 위치하고 전기저항이 약 ${\sim}10^2{\Omega}cm$인 얇은 고분자층이다. 현재 일반적으로 사용되는 반도전층 소재는 카본블랙이 30 wt% 이상 보강된 고분자 복합체이다. 본 연구에서는 카본나노튜브(CNT)가 보강된 새로운 반도전층 재료를 제시하였다. 여러 가지 고분자 형태와 이중충전제 시스템을 적용하여 용액혼합 및 침전법으로 CNT가 보강된 고분자 나노복합체를 제조하였다. 기계적, 열적, 전기적 특성을 고분자 형태와 CNT와 카본블랙의 첨가비를 달리한 이중충전제 시스템의 함수로 조사하였다. 복합체의 전기저항특성은 고분자 매트릭스의 결정화도와 밀접한 관련이 있었다. 즉, 결정화도가 감소함에 따라 일정한 수준의 결정화도까지 전기저항이 선형적으로 감소하였고, 그 이하에서는 일정한 값을 나타내었다. 이중충전제 시스템 역시 전기적 저항에 영향을 미쳤다. CNT만으로 보강된 나노복합체가 가장 낮은 전기적 저항특성을 보였다. 소량의 카본블랙이 첨가되면 결정화도가 급격히 증가하고 결국 전기저항의 증가를 초래하였다.

Bi4Ti3O12 박막의 구조적 특성과 유전 특성에 미치는 산소 열처리 효과 (Effects of Oxygen Annealing on the Structural Properties and Dielectric Properties Of Bi4Ti3O12 Thin Films)

  • 차유정;성태근;남산;정영훈;이영진;백종후
    • 한국전기전자재료학회논문지
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    • 제22권4호
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    • pp.290-296
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    • 2009
  • $Bi_{4}Ti_{3}O_{12}$ (BiT) thin films were grown on the Pt/Ti/$SiO_2$/si substrate using a metal organic decomposition (MOD) method. Effects of oxygen annealing on the structural properties and dielectric properties of the BiT thin films were investigated. The BiT films were well developed when rapid thermal annealed at $>500^{\circ}C$ in oxygen ambient. For the film annealed at $700^{\circ}C$, no crystalline phase was observed under oxygen free annealing atmosphere while its crystallinity was significantly enhanced as the oxygen pressure increased. The BiT film also exhibited a smooth surface with defect free grains. A high dielectric constant and a low dielectric loss were achieved satisfactory in the frequency range from 75 kHz to 1 MHz. Especially, the BiT film, annealed at $700^{\circ}C$ and 10 torr oxygen pressure, showed good dielectric properties: dielectric constant of 51 and dielectric loss of 0.2 % at 100 kHz. Its leakage current was also considerably improved, being as $0.62\;nA/cm^2$ at 1 V. Therefore, it is considered that the oxygen annealing has effects on an enhancement of crystallinity and dielectric properties of the BiT films.

엑시머 레이저를 이용하여 결정화한 PECVD 및 LPCVD 비정질 실리콘 박막의 특성 분석 (An Analysis of Characteristics of PECVD and LPCVD a-Si Films Crystallized by Excimer Laser)

  • 장근호;이성규;전명철;한민구
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1994년도 하계학술대회 논문집 C
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    • pp.1239-1242
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    • 1994
  • We have characterized XeCl excimer-laser-induced crystallization of thin amorphous silicon films deposited by PECVD (${\alpha}-Si:H$) and LPCVD(${\alpha}-Si$). The electrical and optical properties and surface roughness of crystallized thin films have been measured. The dc conductivities, crystallinity and surface roughness of the films increased as the laser energy density and shot density were increased. Also, we have investigated the effects of 2-step annealing employing SPC and ELA. The properties of 2-step annealed films were better than those of films annealed by ELA only.

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Effects of Oxygen Pressure on the Crystallization Behavior and Electrical Properties of YMnO3 Thin Films

  • Cheon, Chae-Il;Yun, Kwi-Young;Kim, Jeong-Seog;Kim, Jin-Hyeok
    • 한국세라믹학회지
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    • 제40권4호
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    • pp.398-400
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    • 2003
  • The YMnO$_3$ thin films were prepared on platinized-silicon substrates by chemical solution deposition and annealed at 750 to 85$0^{\circ}C$ for 1 h under various oxygen pressures, from 2 mTorr to 760 Torr. Effects of annealing oxygen pressures on the crystallization behavior and electrical properties of YMnO$_3$ thin films were investigated. Crystallinity and c-axis preferred orientation of YMnO$_3$ thin film were improved by decreasing the oxygen pressure but were deteriorated at extremely low oxygen pressure, 2 mTorr. Leakage current density of the YMn03 thin film decreased as the oxygen pressure decreased. The film annealed at 80$0^{\circ}C$ under 2 Torr, which had the best crystallinity and the highest c-axis preferred orientation. showed the best-developed ferroelectric C-V hysteresis.

Ferroelectric 캐패시터의 하부전극에의 응용을 위한 IrO2 박막 증착 및 특성분석 (Growth and Characteristics of IrO2 Thin Films for Application as Bottom Electrodes of Ferroelectric Capacitors)

  • 허재성;최훈상;김도영;장유민;이장혁;최인훈
    • 한국재료학회지
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    • 제13권2호
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    • pp.69-73
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    • 2003
  • In this work, $IrO_2$thin films as bottom electrode of ferroelectric capacitors were deposited and characterized. The $IrO_2$films deposited in the conditions of 25, 40 and 50% oxygen ambient by sputtering method were annealed at 600, 700 and $800^{\circ}C$, respectively. It was found that the crystallinity and the surface morphology of $IrO_2$films affected the surface properties and electrical properties of SBT thin films prepared by the MOD method. With increasing temperature, the crystallinity and the roughness of $IrO_2$films were also increasing. This increasing of roughness degraded the surface properties and electrical properties of SBT films. We found an optimum condition of $IrO_2$films as bottom electrode for ferroelectric capacitor at 50% oxygen ambient and $600^{\circ}C$ annealing temperature. Electrical characterizations were performed by using$ IrO_2$bottom electrodes grown at an optimum conditions. The remanent polarization ($P_{r}$) of the Pt/SBT/$IrO_2$/$SiO_2$/Si structure was 2.75 $\mu$C/$\textrm{cm}^2$ at an applied voltage of 3 V. The leakage current density was $1.06${\times}$10^{-3}$ A/$\textrm{cm}^2$ at an applied voltage of 3 V.

Properites of transparent conductive ZnO:Al film prepared by co-sputtering

  • Ma, Hong-Chan;Lee, Hee-Young
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 추계학술대회 논문집
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    • pp.106-106
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    • 2009
  • Al-doped ZnO (AZO) thin films were grown on glass substrates by co-sputtering at room temperature. We made ZnO and Al target and ZnO:Al film is deposited with sputter which has two RF gun source. The Al content was controlled by varying Al RF power and effect of Al contents on the properties of ZnO:Al film was investigated. Crystallinity and orientation of the ZnO:Al films were investigated by X-ray diffraction (XRD), surface morphology of the ZnO:Al films was observed by atomic force microscope. Electrical properties of the ZnO:Al films were measured at room temperature by van der Pauw method and hall measurement. Optrical properties of ZnO:Al films were measured by UV-vis-NIR spectrometer.

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PECVD법에 의해 제조된 Sb-doped $SnO_2$ 박막의 증착거동 및 전기적 특성 (Deposition Behaviors and Electrical Properties of Sb-doped $SnO_2$ Films by Plasma Enhanced Chemical Vapor Deposition)

  • 김근수;서지윤;이희영;김광호
    • 한국세라믹학회지
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    • 제37권2호
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    • pp.194-200
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    • 2000
  • Sb-doped tin oxide films were deposited on Corning glass 1737 substrate by plasma enhanced chemical vapor deposition(PECVD) technique using a gas mixture of SnCl4/SbCl5/O2/Ar. The deposition behaviors of tin oxide films by PECVD were compared with those by thermal CVD, and effects of deposition temperature, r.f. power and Sb doping on the electrical properties of tin oxide films were investigated. PECVD technique largely increased the deposition rate and smoothed the surface of tin oxide films compared with thermal CVD. Electrical resistivity decreased with doping of Sb due to the increase of carrier concentration. However, large doping of Sb diminished carrier concentration and mobility due to the decrease of crystallinity, which resulted in the increase of electrical resistivity. As the deposition temperature and r.f. power increased, Cl content in the film decreased.

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A Study on the Thermal Properties of CNT reinforced Semiconductive Shield Materials Used in Power Cables

  • Yang, Hoon;Bang, Jeong-Hwan;Chang, Hong-Soon;Nah, Chang-Woon;Park, Dae-Hee
    • Journal of Electrical Engineering and Technology
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    • 제3권1호
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    • pp.115-120
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    • 2008
  • Use of the carbon nanotube is superior to general powder state materials of mechanical and electrical properties. Because its ratio of diameter and length (aspect ratio) is very large, it has been known as a type of ideal nano-reinforcement material. Based on this advantage, the existing carbon black of semiconductive shield materials used in power cables can acquire excellent properties by using a small amount of carbon nanotubes. Thus, we investigated the thermal properties of the carbon nanotube, such as thermal conductivity, specific heat, and DSC (Differential Scanning Calorimetry). We found that a high thermal resistance level is demonstrated by using a small amount of carbon nanotubes. As a result, this tendency confirms high cross-linking density in a new network in which the carbon nanotube between carbon black constitute molecules shows a bond by similar constructive properties.

초음파분무법으로 제조한 ZnO막의 PL특성 (PL Properties of ZnO Films Prepared by Ultrasonic Spray Pyrolysis)

  • 최무희;천영덕;마대영
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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    • pp.195-198
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    • 2004
  • ZnO films were Prepared by ultrasonic spray Pyrolysis on MgO substrates. The surface morphology and crystallinity were observed as a function of substrate temperature by SEM and XRD, respectively. PL properties of the ZnO films were studied by using Cd-He laser. UV light around 3.37 eV was pronounced in the PL spectra. The origin of the PL peak was discussed.

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