• Title/Summary/Keyword: Crystalization

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An Investigation on Mitigation of Crystalization Fouling by Physical Water Treatment using Catalytic Material (촉매물질을 이용한 수처리 기법의 결정화 화울링의 저감에 관한 연구)

  • Kim, Sun-Do;Park, Bock-Choon;Baek, Byung-Joon;Kim, Cheol-Sang
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.1582-1588
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    • 2004
  • The present experimental study aimed to investigate the feasibility of physical water treatment (PWT) devices using catalytic materials to mitigation of crystalization fouling. Two PWT devices having different shape and material were used. The results from microscopic observation and SEM photographs demonstrate that the crystal structure of $CaCO_3$ is Argonite type without water treatment while Calcite type with water treatment, which clearly shows the feasibility of PWT techinque using catalytic materials to mitigate crystalization fouling. For 500 ppm solution, the fouling resistance decreased up to about 23% due to physical water treatment using catalytic materials. The results also reveal that if two more techniques are used simultaneously the additional effects could be expected.

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인공치아용 결정화 유리의 제조(I)

  • 한복섭;이준희
    • Journal of Biomedical Engineering Research
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    • v.11 no.2
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    • pp.295-304
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    • 1990
  • In order to use for artificial dental tooth (dental crowens) , new glass-ceramics material has been studied. Its basic composition and the condition of heat treatment for crystalization, mechanical and chemical properties were investigated. Adding of the LAS system composition in the basic glass, time and temperature for crystalization were shortened. Fracture toughness (kic)of samples heat treated at 90$0^{\circ}C$ for 2 hours is 2.5-2.6MN/m3/2, the optimum condition of heat treatment for artificial tooth is A and B samples heating to 75$0^{\circ}C$ for 2 hours, raising to 90$0^{\circ}C$ and maintaining at 90$0^{\circ}C$ for 2 hours and C sample heating to 75$0^{\circ}C$ maintaining at 75$0^{\circ}C$ for 2 hours. In acid and'alkali solution, chemical durability is excellent.

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Estimation of the Optimum Factor of the Struvite Crystalization for the Nitrogen and Phosphorus Removal in WWTP (폐수내 질소 및 인 제거를 위한 struvite 결정화 최적조건 도출)

  • Kim, Ji Yeon;Moon, Yong Taik;Seo, In Seok;Kim, Byung Goon
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.6
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    • pp.745-753
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    • 2007
  • By struvite and hydroxyapatite crystallization, was high concentration of nitrogen and phosphorus in wastewater simultaneously. Particularly, removal of nitrogen and phosphate for crystallization have been applied to landfill leachates and animal wastewater. The purpose of this study is to decide the optimum struvite crystallization factors, sequence of $Mg^{2+}$ addition, pH control and the molar ratio of $Mg^{2+}$ over $PO_4^{3-}$. In conclusion, dosage of the magnesium followed by pH control formed magnesium hydroxide, so pH was decreased. Therefore, pH adjustment should followed by after magnesium dosage and then pH should be adjusted to 11. Over pH 10, it was not good for struvite crystallization efficiency by side reaction. Following of the $Mg^{2+}$ and the $PO_4^{3-}$ are dosed excessively, the removal efficiency of the $NH_4^+$ increased. A molar ratio of $Mg^{2+}:NH_4^+:PO_4^{3-}$, 1.3:1:1.3 was the most on effective for $NH_4^+$ removal at pH 9.5. But for the perfect removal $NH_4^+$, it is thought to be that molar ratio should be 2:1:2.

Inhibition Effects of $Ca^{2+}$ and $F^-$ Ion on Struvite Crystallization ($Ca^{2+}$$F^-$ 이온이 Struvite 결정화 반응에 미치는 영향)

  • Kim, Seung-Ha;Kim, Keum-Yong;Ryu, Hong-Duck;Lee, Sang-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.7
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    • pp.730-737
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    • 2010
  • It is very important to remove fluoride ion before treating semiconductor wastewater containing high concentration of ammonia, phosphates, and fluoride ions by struvite formation. Calcium ion was generally added for the removal of fluoride ion. However, calcium ions remained after removal of fluoride ion can deteriorate the performance of struvite crystalization. It should be removed completely before struvite formation. In this study, the effect of fluoride and calcium ion concentration on the struvite crystalization was investigated. Removal efficiencies of ortho-phosphate with struvite formation were more abruptly decreased than those of ammonium nitrogen, as increase of fluoride ion concentration in synthetic wastewater. The structures of struvite formed in synthetic wastewater containing calcium ion of up to 500 mg/L were identical. Purity of struvite was deteriorated as increase of calcium ion over 500 mg/L. Removal efficiencies of ammonium nitrogen were more decreased than those of phosphate ions as increase of cacium ion in synthetic wastewater.

The Effects of Bottom Extremity on the Magnetic Properties of Iron and Cobalt-Iron Electrodeposited Anodic Oxided Films. (철 및 코발트-철합금석출 양극산화피막의 초기석출부가 자기특성에 미치는 영향)

  • ;Ken-Ichi Arai
    • Journal of the Korean Magnetics Society
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    • v.5 no.6
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    • pp.921-927
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    • 1995
  • The micro particle,s shapes of the magnetic films obtained by electrode position of Iron ions and Cobalt-Iron mixed ions in aluminum anodic oxidized films are dependent on the size of particle diameter. When the diameter of deposited particles is larger than $300\AA$, the film plane anisotropy caused by bottom extremity increases, and the crystalization orientation of FeC deposited unusually in the part of the bottom extremities affects on the coercive force Hc and the magnetic anisotropy energy Ku. It was confirmed that the shape anisotropy of particle affects on the both Hc and Ku because the FeC did not deposit in the Iron deposited samples entirely, but in the Cobalt-Iron alloy deposited samples, the effects by the very strong crystalization orientation of the FeC is larger than that of the shape anisotropy. From these results, the Cobalt-Iron alloyed films could switchover the film plane magnetic anisotropy to the perpendicular magnetic anisotropy energy by using the constrainting method of FeC deposition with Cu deposition instead of Cobalt-Iron alloy in the bottom extremities.

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A Cytochemical Study on the Acid Phosphatase of Neurons of Developing Chick Embryo Brain (계배 뇌 발생에 있어서 신경세포의 Acid Phosphatase 변화에 관한 효소화학적 연구)

  • Koh, Ki-Seok;Shin, Chu-Og;Yoo, Chang-Kyu;Choe, Rim-Soon
    • Applied Microscopy
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    • v.18 no.2
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    • pp.119-131
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    • 1988
  • The purpose of this study was to investigate the differentiation and degeneration of neurons in developing chick embryo. The activity of acid phosphatase(ACP) was measured and cytochemical study of ACP and ultrastructural changes were observed in prosencephalon, mesencephalon and rhombencephalon from day 4 to day 19 of incubation. As a result, the activity of ACP of all brain region was tend to increase from day 4 to day 19. On day 13, activities of ACP of mesencephalon and rhombencephalon were increased greatly and activity of ACP was decreased each region on day 17. On electron microscopic examination, the reaction product of ACP were localized at GERL complex, lysosome, Golgi body and vacuoles of neurons. Morphologically, disrupted nuclear envelope, mitochondrial destruction, vacuolization and ribosomal crystalization were observed.

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The Microstructure and Mechanical Properties of Fiber Reinforced Calcium Silicate Hydrates (섬유보강 규산칼슘수화물 경화체의 미세조직과 기계적 특성)

  • 엄태선;최상흘
    • Journal of the Korean Ceramic Society
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    • v.34 no.5
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    • pp.491-499
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    • 1997
  • High flexible lightweight composites containing tobermorite as a main mineral is produced using various amorphous silicates, lime, cement and fibers. Here, Mechanical properties of the composites were studied by observing microstructures of hydrates and fibers. Amorphous silicates having better hydraulicity retarded the crystallization of tobermorite due to better formation of C-S-H gel in water bath curing, but, difficult conversion from C-S-H gel to tobermorite in hydrothermal reaction. In the low molar ratio of CaO/SiO2 (0.67), faster crystalization was observed dued to more impurities such as Al2O3 alkali, resulting in improving mechanical properties due to small crystal size and many contact points. It was identified that a lot of calcium silicate hydates formed at surface of pulps increase bonding strength and the crack-resistance of matrix in the composites, but decrease hardness and compressive strength. The choice of amorpous silicates having better hydraulicity, low CaO/SiO2 adding each fibers bellow about 5% in the raw mixs and lower molding pressure should be needed at improve mechanical properties of composites.

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The Optical Characteristics of ${Te}_{100-x}{Ge}_{x}$ Thin Film with Phase Change (비정질 ${Te}_{100-x}{Ge}_{x}$박막의 상변화에 의한 광특성)

  • 정홍배;이영종;이현용;김병훈
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.41 no.3
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    • pp.261-266
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    • 1992
  • In this paper, we investigated the stability of TeS1100-xTGeS1xT( x = 15,33,50 at. %) thin films by observing the transmittance and reflectance changes with annealing and exposure of diode laser(780nm). As results of transmittance changes in constant tenperature and humidity atmosphere, it was shown that TeS150TGeS150T thin film has the smallest transmittance change. From the XRD patterns, it was confirmed that the transmittance changes in TeS150TGeS150T thin film before and after annealing are due to crystalization. The transmittance changes in TeS150TGeS150T thin film with annealing are largest at diode laser wavelength and the trasmittance changes with laser exposure are decreased fast.

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Urinary Metabolites of p-Methoxycinnamic Acid (p-Methoxycinnamic Acid의 뇨대사물에 대하여)

  • 우원식
    • YAKHAK HOEJI
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    • v.8 no.3
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    • pp.76-79
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    • 1964
  • The metabolism of p-methoxycinnamic acid (p-MCA) has been studied in man and rabbits. Possible compounds were examined for metabolites by crystalization and by paper chromatography, which excreted after adminstration of p-MCA by stomach tube and intravenous injection. p-Methoxyhippuric acid was isolated from urine. Although pure glucuronide was not crystallized from urine, product was obtained by basic lead salt method, which gave p-methodxybenzoic acid (p-MBA) on hydrolysis and gave an intese naphthoresorcinol reaction. No evidence for the demethylation of p-MCA was found. These results are indicating that p-MCA may be mainly converted to p-MBA by ${\betha}$-oxidationand excreted as its conjugates with glycine and glucuronic acid. Its oxidation does not appear to be dependent on intestinal micro-organisms.

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An Experimental Study on Improving Water Tightness of Concrete Surface Applied High Growth Organic Crystalization Material (고성장 유기결정체의 성장 특성을 이용한 콘크리트 표층부의 수밀성 개선에 관한 연구)

  • Song Je-Young;Kang Hyo-Jin;Oh Sang-Keun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.817-820
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    • 2004
  • Our country was much developments in change of construction environment along with fast economy development. But, various problems that must think in problem of safety and quality were appeared. Constructions which build through rapid economy development are getting many social criticisms to problem of crack and water leakage at use process. Is situation that huge repair expense to cure this is engaged. Safety problem of construction is indicated socially through various media mediums again.

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