• 제목/요약/키워드: Crystal transition

검색결과 630건 처리시간 0.031초

압전성 $KAlSiO_4$ 단결정 육성 및 상변화 (Crystal Growth and Phase Transition of Piezoelectric $KAlSiO_4$)

  • 오광석;박봉모;정수진;이태근;박병규;김호성
    • 한국세라믹학회지
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    • 제33권3호
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    • pp.362-370
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    • 1996
  • Kalsilite (KAlSiO4) system undergoes a displacive phase transition from hexagonal phase with p63 space group to the phase with P63mc at 886$^{\circ}C$. The flux composition having kalsilite :K2O:B2O3=1:2:2 has enabled the growth of hexagonal kalsilite with the size of 0.5~1 mm at a slow cooling rate (0.3$^{\circ}C$/hr). On decreasing the cooling rate the size has increased and pyramidal (1011) faces are newly developed with the shape of (0001) and (1010) faces. Upon stirring (1011) faces are degraded. The space group of O1 and O2 are P21221 and C2221 respectively. Their orthorombic modification O1 and O2 are synthesized at relatively low and high temperature respectively.

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Existence of a vortex-glass phase transition in an optimally doped BaFe1.8Co0.2As2 single crystal

  • Choi, Ki-Young;Kim, Kee Hoon
    • 한국초전도ㆍ저온공학회논문지
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    • 제15권2호
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    • pp.16-19
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    • 2013
  • The magneto-resistivity and electric field-current density (E-J) curves were investigated up to a magnetic field 9 T in the optimally doped $BaFe_{1.8}Co_{0.2}As_2$ single crystal with a superconducting temperature ($T_c$) of 24.6 K. The E-J Scaling behaviors below and above vortex glass transition temperature ($T_g$) were found, confirming the existence of the vortex glass phase transition. The critical exponents for the diverging spatial and time correlations at $T_g$, were obtained as v = $1.1{\pm}0.1$ and z = $4.5{\pm}0.3$, respectively. The obtained critical exponents are in good agreement with the predicted values of v ~ 1 - 2 and z > 4 within the 3D vortex glass theory.

Rietveld 해석법에의한 YBCO 초전도체의 결정 구조 전이 연구 (The crystal structure transition in YBCO superconductor by Rietveld analysis Method)

  • 채기병;전용우;소대화
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 춘계학술대회 논문집
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    • pp.239-243
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    • 1996
  • In this paper, we have tried to focus on the optimum conditions of crystal structure parameters on YBCO high Tc oxide-superconductor as an excel lent electronic parts. When we verify the characteristic improvement of superconductance and accurate reproduction and so forth, we have made use of RIETAN. We have varied the lattice constant with oxygen content from 6.0 to 7.0 as for transition of orthogonal structure and tetragonal structure for the superconductor. As the result of above, we have preyed that transition from orthogonal structure to tetragonal structure is made at the point of 6.6(oxygen content) by using the simulation.

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Improving switching time from homeotropic state to planar state in cholesteric liquid crystal by olymer stabilization

  • Kim, Tae-Jin;Lim, Tong-Kun
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.I
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    • pp.437-438
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    • 2005
  • A polymer stabilization method is employed to reduce the transition time from field-induced homeotropic(H) state to reflecting planar(P) state in the cholesteric liquid crystal(ChLC) display. To stabilize ChLC by polymer, we mixed ChLC with diacrylate of 2 $wt%{\sim}6$ wt%. Two samples were made with different method of stabilization. For one sample the diacrylate of 2 wt% was polymerized with the ChLC in P state, while for the other sample diacrylate of 16 wt% was polymerized with ChLC in H state. In the former case, the transition time was 1000 times faster then those in the pure sample. In the latter sample, the transition time was 1700 times faster than those in pure ChLC sample.

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SiC 단결정의 TSSG 공정을 위한 전이금속 특성 연구 (Study on the characteristics of transition metals for TSSG process of SiC single crystal)

  • 이승준;유용재;정성민;배시영;이원재;신윤지
    • 한국결정성장학회지
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    • 제32권2호
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    • pp.55-60
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    • 2022
  • 본 연구에서는 SiC 단결정의 TSSG 공정중 결정 품질을 저하시키지 않으면서도 의도하지 않은 질소 도핑(N-UID)을 쉽게 제어하기 위해 지금까지 Co 또는 Sc 전이금속을 첨가한 신규 용융조성을 제안한다. Co 또는 Sc의 특성을 파악하기 위해 Ar 분위기에서 1900℃ 온도에서 약 2시간 동안 열처리 실험을 수행했다. 용융조성은 Si-Ti 10 at% 또는 Si-Cr 30 at%를 비롯하여, 탄소 용해도에 효과적이라고 알려진 Co 또는 Sc을 각각 3 at% 첨가하였다. 열처리 후 도가니 단면을 가공하여 도가니-용융물 계면에서 발생한 Si-C 반응층을 관찰하고, 탄소황분석을 통해 조성에 따른 탄소 용해도를 간접적으로 분석하였다. 그 결과, Si-Sc 기반 용융조성이 TSSG 공정에 적합한 특성을 갖는 Si-C반응층을 형성하고 있었다. 또한 탄소황분석 결과에서도 Cr 다음으로 높은 탄소량이 갖는 것으로 분석되었다. Sc는 Cr에 비해 질소와의 반응성이 낮은 이점을 가지므로 TSSG 공정에 Si-Sc 용융조성을 적용하면, 본 연구에서 의도한 대로 SiC 단결정 성장속도와 질소 UID를 모두 제어할 수 있는 것으로 고려된다.

Changing the Surface-Liquid Crystal Interaction through the Adsorption of Silica Nanoparticles

  • Finotello, Daniele;Jin, Tao
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.847-848
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    • 2004
  • We studied a low density 8CB liquid crystal-hydrophobic aerosil dispersions imbedded in submicron-size cylindrical pores. The nanosize spherical aerosil particles are adsorbed at the pore wall and hinder the planar anchoring. The adsorption is temperature dependent, and an axial to radial molecular configuration transition occurs within the cylindrical pores.

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효소반응에 의한 견피브로인의 전이 (Transition of Silk Fibroin by Enzymatic Reaction)

  • 김동건;최진협;소서효
    • 한국잠사곤충학회지
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    • 제39권1호
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    • pp.73-78
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    • 1997
  • 분자량 약 7000의 Fcp는 효소분해역반응을 이용하는 것에 의해 분자량 약 17000과 약 24000까지 고분자량화된 PIFcp가 얻어졌다. 또, 효소분해의 역반응에 의해 고분자량화되는 것은 일부의 Fcp이며 Silk II형결정으로부터 Silk I형결정으로 전이하는 것은 대부분의 Fcp에서 나타났다. 이 PIFcp는 X선회절과 시차열분석(DTA)의 결과로부터 어느정도 안정한 Silk I형의 결정구조를 가지는 것이 확인되었다.

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열전도 측정에 의한 Pb5Ge3O11 단결정의 상전이 (The Phase Transition of Pb5Ge3O11 Single Crystal by the Thermal Conduction Measurement)

  • 정맹식
    • 한국안광학회지
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    • 제4권2호
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    • pp.165-169
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    • 1999
  • 시료의 한 부분에 순간적으로 가열하여 시료의 특정 부분의 온도변화를 조사함으로써 시료의 열 확산도를 측정하였다. $Pb_5Ge_3O_{11}$ 단결정의 환산 열 확산도는 trigonal 구조인 $30^{\circ}C$에서는 $0.0117cm^2/^{\circ}C$, curie point 근방인 $178^{\circ}C$에서는 $0.0105cm^2/^{\circ}C$이며 hexagonal 구조인 $180^{\circ}C$에서는 0.0112cm로 각각 나타났다. 이는 $Pb_5Ge_3O_{11}$ 단결정을 같은 열량으로 가열하였을 때, 실온에서 curie 온도쪽으로 갈 때 가열 효과가 적었으며 curie point에서 최소가 되었다가 curie 온도 이상에서는 갑자기 증가하여 일정하게 되었다. 따라서 $Pb_5Ge_3O_{11}$ 단결정의 상전이 용도가 1m 근방임을 확인하였다.

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Cocrystallization of Poly(1,4-cyclohexylenedimethylene terephthalate-co-hexamethylene terephthalate) Copolymers

  • Jeong, Young-Gyu;Jo, Won-Ho;Lee, Sang-Cheol
    • Macromolecular Research
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    • 제12권5호
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    • pp.459-465
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    • 2004
  • We have synthesized poly(l,4-cyclohexylenedimethylene terephthalate-co-hexamethylene terephthalate) [P(CT-co-HT)] random copolymers having various comonomer contents, from 0 to 100 mol% HT, by melt-condensation and have investigated their crystallization behavior by using differential scanning calorimetry (DSC) and wide-angle X-ray diffraction (WAXD). We observed that P(CT-co-HT)s exhibit clear melting and crystallization peaks in their DSC thermograms and sharp diffraction peaks in their WAXD patterns for all of their copolymer compositions as a result of cocrystallization of the CT and HT units, even though the copolymers are statistically random copolymers. When we plotted the melting and crystallization temperatures of P(CT-co-HT)s and the d-spacings of all the reflections against the copolymer composition, we observed a eutectic point at ca. 80 mol% HT, which suggests that a crystal transition occured from a PCT-type crystal to a PHT-type crystal. Both the DSC and WAXD results support the notion that P(CT-co-HT) copolymers undergo an isodimorphic cocrystallization.