• 제목/요약/키워드: Crystal field

검색결과 1,132건 처리시간 0.031초

A new laser pulse atom-probe 제작 및 $H_2$ 가스와 He 가스의 time-of-flight mass spectrum (An extension of new laser pulse atom-probe construction and time-of-flight mass spectrum of $H_2$ and He gas)

  • 송순달;홍남관
    • 한국결정성장학회지
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    • 제7권3호
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    • pp.465-472
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    • 1997
  • 본 연구는 전기 장에서 광여기 탈착과 이온화에 근거한 표면연구의 새로운 장치를 개발하고 시험한 결과를 보고한다. 실험장치의 분해능을 테스트 하기 위해 텡스텐(110)면에서 흡착기체 $H_2$ 와 He 가스를 조사하였으며, 팁의 온도는 80 K이었다. 장세기가 10 V/nm에서 50 V/nm사이에서 사용한 파장은 193 nm이였으며, 텡스텐(110)면에 가스가 흡착되었을때 레이저빔의 전자적인 여기로 부터 흡착가스와 팁에서 여러종류의 이온들이 형성되었다($H_2^+, CO^+, H_2O^+, He^+, W^{3+}$ 그리고 $W^{2+}$). 전체 mass spectrum의 기록은 Transient recorder가 가능하게 한다.

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Measurement of Effective Refractive Index of Nematic Liquid Crystal in Fabry-Perot Etalon

  • Ko, Myeong Ock;Kim, Sung-Jo;Kim, Jong-Hyun;Lee, Bong Wan;Jeon, Min Yong
    • Journal of the Optical Society of Korea
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    • 제19권4호
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    • pp.346-350
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    • 2015
  • We report a measurement of the effective refractive index of a nematic liquid crystal (NLC) inside a Fabry-Perot (FP) etalon according to the applied electric fields. The effective refractive index of the NLC depends on the intensity of the applied electric field. A wavelength-swept laser with a polygon-scanner-based wavelength filter is used as a wide-band optical source to measure the effective refractive index of the NLC. The bandwidth of the optical source is greater than 90 nm around 1300 nm. The fabricated NLC FP etalon consists of glass substrates, gold layers as the electrodes with highly reflective surfaces, polyimide layers as the planar alignment layers, and an LC layer. Furthermore, we measured the Freedericksz transition voltages for three types of NLC FP etalons having thicknesses of $30.6{\mu}m$, $55.4{\mu}m$, and $108.8{\mu}m$. The Freedericksz transition voltages in the three cases are nearly equal. The measured effective refractive indices in the three cases decreased from 1.67 to 1.51 as the applied electric field intensity was increased. Beyond the threshold electric field, the effective refractive indices quickly decreased and eventually saturated at a value of 1.51 for all cases.

카본나노튜브가 액정의 물성과 in-plane switching 셀의 전기광학 특성에 미치는 영향 (Carbon nanotube effects on physical properties of liquid crystal and electro-optic characteristics of in-plane switching liquid crystal cell)

  • 전상연;정석진;정석호;신승환;안계혁;강훈;김경진;이승희;이영희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
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    • pp.47-48
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    • 2006
  • Carbon nanotubes (CNTs)-doped homogeneously aligned nematic liquid crystal (LC) cells driven by in-plane field were fabricated and their electro-optic characteristics were investigated. Effective cell retardation values in an absence of an electric field between doped and undoped LC were the same each other. In the presence of an electric field, however, measured effective cell retardation value was smaller in the CNT-doped cell than in the undoped cell so that the transmittance was slightly smaller in the CNT-doped cell than in the undoped cell. In addition, the CNT-doped cell exhibited slight increase in driving voltage and decrease in response time compared to the undoped cell. The CNT effects on electro-optic characteristics of the cell were discussed.

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카본나노튜브가 프린즈 필드 스위칭 액정 셀의 전기 광학적 특성에 미치는 영향 (Effects of carbon nanotubes on electro-optic characteristics of fringe-field switching liquid crystal cell)

  • 최정훈;조은미;김미영;;이승희;배정준;이규;이영희;이희규;이승은
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.435-436
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    • 2008
  • In this paper, the electro-optical characteristics of carbon nano tubes (CNTs) doped liquid crystal (LC), in fringe-field switching cell have been investigated and compared with pure LC. The electro-optical characteristics of CNTs doped LC were found to be improved than that of pure LC. The CNTs doped LC exhibits faster response time and lower driving voltage than that of pure LC.

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The NMR Chemical Shift for 4d$^n$ Systems(Ⅲ). Calculation of the NMR Shift for a 4d$^1$ System in a Strong Crystal Field Enviroment of Tetragonal Symmetry

  • Ahn, Sang-Woon;Park, Eui-Suh;Oh, Se-Woung
    • Bulletin of the Korean Chemical Society
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    • 제5권2호
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    • pp.55-60
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    • 1984
  • The NMR shift arising from the electron angular momentum and electron spin dipolar-nuclear spin angular momentum interactions has been investigated for a $4d^1$system in a strong crystal field environment of tetragonal symmetry. A general formula for NMR shift is used to compute the NMR shifts along the (100), (010), (001), (110) and (111) axes. We find that from the computed results, the NMR shift along the (100) and (010) axes is consistent with each other in a strong crystal field environment of tetragonal symmetry, but the NMR shift along the (001) axis is about triply greater in magnitude than those along the (100) and (010) axes and is opposite in sign to those along (100) and (010) axes. In this work, we express the expansion coefficients $a_1^{(i)}$ and $b_1^{(i)}$ of $A_i$ and $B_i$ in terms of $g_m^{(i)}$ and $h_m^{(i)}$ and two matrices $c_{lm}$ and $d_{lm}$ of radial dependence. The NMR shift is also separated into the contributions of multipolar terms. We find that $1/R^3$ term contributes dominantly to the NMR shift along the (100), (010), (001) and (110) axes while along the (111) axis $1/R^5$ term dominantly contributes. However, the contribtions of the other terms may not be negligible.

광경화성 고분자를 이용한 단일 갭 반투과형 액정디스플레이 연구 (Study on single gap transflective liquid crystal display using the UV Curable Reactive Mesogen)

  • 허정화;김진호;진미형;임영진;이승희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 하계학술대회 논문집
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    • pp.293-294
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    • 2009
  • We proposed a novel single gap transflective liquid crystal display (LCD) using liquid crystal with negative dielectric anisotropy. We designed cell structure driven by fringe electric field in the transmissive (T) part and vertical electric field in the reflective (R) part. In the device, high surface pretilt angle of the LC in the R-part is achieved through polymerization of an UV curable reactive mesogen (RM) monomer at surfaces. By optimizing the parameters, a newly developed transflective display has characteristics such as single gap and single gamma curve.

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다구찌 실험계획법을 이용한 액정 전계 프레넬 렌즈의 최적 설계 (Optimal Design of Electric Field Driven Liquid Crystal Fresnel Lens Using Taguchi's Method)

  • 김봉식;김종운;박우상
    • 한국전기전자재료학회논문지
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    • 제25권3호
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    • pp.218-223
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    • 2012
  • A rigorous electro-optical simulation and ray tracing for an electric field driven liquid crystal Fresnel lens was proposed to obtain design parameters of the electrode pattern of the Fresnel lens. The optimal design was carried out using Taguchi's experimental method for 17.1"($368{\times}229.5$ mm) wide LCD panels with 9 views. For the calculation of the distribution of liquid crystal molecules and the optical transmission of the panel, finite difference method and extended Jones matrix method were used to deal effectively with highly nonlinear and complicated motional equations of the liquid crystal molecules and to obtain the oblique transmission characteristics of the LCD panel. As simulation results, the optimal lengths of the 3 electrodes of the Fresnel lens are 4.0 ${\mu}m$, 30 ${\mu}m$ and 83 ${\mu}m$, respectively, and the locations of the second and third electrodes are 32.9-33.0 ${\mu}m$ and 45.9-46.0 ${\mu}m$, respectively. The optimal applied voltage of the 3 electrodes are found to be 5.75 V, 7.80 V and 11.9 V, respectively.

Domain Switching and Crack Propagation of $BaTiO_3$ Single Crystal in Different Environments

  • Gao, Kewei;Zhao, Xianwu;Wang, Ruimin;Qiao, Lijie;Chu, Wuyang
    • Corrosion Science and Technology
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    • 제7권6호
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    • pp.307-314
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    • 2008
  • The influence of a moist atmosphere on $90^{\circ}$ domain switching under a sustained electric field, stress corrosion cracking of an indentation crack in water and an aggressive solution, and the relation between penetrating crack propagation and domain switching were studied using $BaTiO_3$ single crystal. The results indicate that enlarging the domain switching zone and crack propagation could be facilitated by a moist atmosphere or an aggressive solution due to the indentation residual stress. A moist atmosphere exerts remarkable influence upon the polarization of $BaTiO_3$ single crystal under a sustained electric field, and the surface energy of the c domain was much lower than that of the a domain. Domain switching ahead of a penetrating indentation crack tip was an essential requirement for crack propagation under constant stress.

$Cd_{1-x}Mn_{x}Te$단결정의 Faraday 회전에 관한 연구 (A study of faraday rotation for $Cd_{1-x}Mn_{x}Te$ single crystals)

  • 박효열
    • 한국결정성장학회지
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    • 제10권4호
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    • pp.286-291
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    • 2000
  • 수직 Bridgman법으로 $Cd_{1-x}Mn_{x}Te$ 단결정을 성장시켜 자기장과 파장을 변화시키면서 Faraday회전을 측정하였다. Verdet 상수값은 포톤의 에너지가 높은 쪽으로 이동함에 따라 흡수단 근처에서 최대였고, 조성비 x에 따라 증가하다가 x=0.40 이상에서 감소하였다. $Cd_{1-x}Mn_{x}Te$ 단결정을 Faraday 소자로 이용할 경우, 흡수단 근처에서 Faraday 회전이 가장 크게 일어나는 $Cd_{0.60}Mn_{0.38Te}$ 단결정이 적합하고,광원으로 He-Ne레이저를 사용할 경우에는 $Cd_{0.62}Mn_{0.40}Te$ 단결정이 유용함을 알 수 있었다.

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$Zn_4$$ GeSe_6$$Co^{2+}$를 첨가한 $Zn_4$$ GeSe_6$:$Co^{2+}$단결정의 광학적 특성 (Optical properties of undoped and $Co^{2+}$-doped $Zn_4$$ GeSe_6$ single crystals)

  • 김덕태
    • E2M - 전기 전자와 첨단 소재
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    • 제10권2호
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    • pp.105-112
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    • 1997
  • Undoped and Co$^{2+}$-doped Zn$_{4}$GeSe$_{6}$ single crystals were grown by the Chemical Transport Reaction method using iodine as a transporting agent. The crystal structure of these compounds determined by X-ray diffraction analysis was monoclinic structure. The direct energy gaps of these compounds were measured and the temperature dependence of the optical energy gap were closely investigated over the temperature range 10-290K. The temperature dependence of the optical energy gap is well presented by the Varshni equation. Also the optical absorption peaks of Zn$_{4}$GeSe$_{6}$ :Co$^{2+}$ single crystal observed, centered at 5437, 6079, 7142, 12950, 13462, 14786 and 15735 $cm^{-1}$ /, can be explained in terms of the electronic transitions of Co$^{2+}$ ions located at Td symmetry of the host materials. According to the crystal-field theory, the crystal-field, Racah and spin-orbit coupling parameters obtained from the absorption bands are given by Dq = 361$cm^{-1}$ /, B = 655$cm^{-1}$ / and .lambda. = 284$cm^{-1}$ / respectively.ively.

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