• Title/Summary/Keyword: Crystal Size

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Effects of Crystal Grain Size and Particle Size on Core Loss For Fe-Si Compressed Cores

  • Takemoto, Satoshi;Saito, Takanobu
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1183-1184
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    • 2006
  • Core loss of soft magnetic powder cores have been focused on to achieve high efficiency of power supplies. In this study the effects of crystal grain size on core loss were investigated by changing heat treatment conditions. It was found that core loss is influenced by crystal grain size because eddy current loss decreased and hysteresis loss increased by making crystal grain size smaller, and it is also influenced by particle size.

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Change of Calcium Carbonate Crystal Size at steady state in CMSMPR(Continuous Mixed Suspension Mixed Produce Removal) Crystallizer (연속식결정화기 정상상태에서 탄산칼슘 결정크기 변화)

  • Han, Hyun Kak
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.7
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    • pp.714-719
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    • 2017
  • The controlled synthesis of inorganic materials with a specific size and morphology is an important factor in the development of new materials in many fields, such as nanoparticles, medicine, electronics, semiconductors, pharmaceutical sand cosmetics. Solution crystallization is one of the most widely used separation processes in the chemical and pharmaceutical industries. Calcium carbonate has attracted a great deal of attention in industry because of its numerous applications. The mean crystal size, crystal size distribution and morphology are important factors in the continuous crystallization process. In this study, the continuous crystallization of calcium carbonate by the calcium chloride process was investigated. The mean crystal size and crystal size distribution data were obtained by a particle size analyzer. The morphological imaging of the crystalswasper formed by SEM. Under steady state operation, the mean crystal size change was small, but increasing the input concentration and mixing rate increased the crystal size. In this operation, some aragonite was found, but the main crystal phase was calcite.

Effect of Titanium Sulfate Addition on Crystal Growth of the Flaky α-Al2O3 (황산티타늄의 첨가가 판상 α-Al2O3의 결정성장에 미치는 영향)

  • Park, Byung-Ki;Cho, Sun-Mi;Lee, Jung-Min
    • Journal of the Korean Ceramic Society
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    • v.42 no.5 s.276
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    • pp.338-345
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    • 2005
  • To prepare the complex gel of flux and pseudo-boehmite used in precursor of the flaky ${\alpha}-A1_2O_3$ crystal, aqueous solution of the mixture of sodium carbonate and sodium phosphate was added with stirring in aqueous solution of the mixture of sodium sulfate, potassium sulfate and titanium sulfate. The complex gel was dried at $110^{\circ}C$ and was crystallized above $1,050^{\circ}C$, and then the effect of the amount of titanium sulfate on size, morphology, thickness and crystal size distribution of the flaky ${\alpha}-A1_2O_3$ crystal was investigated. Addition of titanium sulfate was prevented the aggregation and generation of twin crystal, and had an effect on the crystal size and the thickness during crystal growth. When the amount of titanium sulfate was more than 6 g, particle size was decreased but was free from crystal twining and aggregation. On the other hand, when the amount of titanium sulfate was lower than 6 g, crystal size was increased but crystal twinning and aggregation were noticed.

Analysis of Stress-Strain Relationship of Nano Structures According to the Size and Crystal Orientation by Using the Molecular Dynamics Simulation (분자동역학을 이용한 나노구조물의 크기와 결정방향에 따른 응력-변형률 관계 해석)

  • Kang, Yong-Soo;Kim, Hyun-Gyu
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.12
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    • pp.1047-1054
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    • 2008
  • In this paper, the molecular dynamics (MD) simulations are performed with single-crystal copper blocks under simple shear and simple tension to investigate the effect of size and crystal orientation. There are many variances to give influences such as deformation path, temperature, specimen size and crystal orientation. Among them, the crystal orientation has a primary influence on the volume averaged stress. The numerical results show that the volume averaged shear stress decreases as the specimen size increases and as the crystal orientation changes from single to octal. Furthermore, the Schmid factor and yield stress for crystal orientation are evaluated by using the MD simulation on the standard triangle of stereographic projection.

Crystallization of High Purity Ammonium Meta-Tungstate for production of Ultrapure Tungsten Metal

  • Choi, Cheong-Song
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1997.10a
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    • pp.1-5
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    • 1997
  • The growth mechanism of AMT(Ammonium Meta-Tungstate) crystal was interpreted as two-step model. The contribution of the diffusion step increased with the increase of temperature, crystal size, and supersaturation. The crystal size distribution from a batch cooling crystallizer was predicted by the numerical solution of a mathematical model which uses the kinetics of nucleation and crystal growth. Temperature control of a batch crystallizer was studied using Learning control algorithm. The purity of AMT crystal producted in this investigation was above 99.99%.

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Effect of droplet size on electro-optical switching properties of polymer dispersed liquid crystals (폴리머 분산 액정의 전기 광학적 스위칭 특성에 대한 액정방울 크기의 효과)

  • Kim, In-Tae;Yu, Yeon-Serk
    • Korean Journal of Optics and Photonics
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    • v.17 no.1
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    • pp.23-30
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    • 2006
  • Effects of liquid-crystal droplets size on electro-optical properties of the polymer dispersed liquid crystals are investigated experimentally The liquid crystal droplets size was varied by controlling the Laser power for phase separation and LC/oligomer composition ratio. Electro-optical switching voltage is dependent on the LC/oligomer composition ratio and liquid crystal droplet size. The experimental results showed droplet size will be small and saturation voltage is increased but rise time will be short at high power illumination laser light for phase separation.

Size Effect of Light Scattering on the Nano-Sized Color Filter Pigment in Liquid Crystal Display

  • Jhun, Chul Gyu;Gwag, Jin Seog
    • Journal of the Optical Society of Korea
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    • v.18 no.2
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    • pp.184-187
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    • 2014
  • This study examined the effects of particle size on the light scattering of a nano-sized color filter pigment used to obtain a range of colors in liquid crystal displays. The contrast ratio is one of the most important characteristics of liquid crystal displays. When a color filter is located between two crossed polarizers, the size of the pigment can give rise to a decrease in the contrast ratio due to Rayleigh scattering by the nanoparticles in the filter. The size effect of the color filter pigment on the contrast ratio was investigated in terms of the depolarization parameter. As an experimental result, the depolarization parameter increased with decreasing pigment size. Therefore, a smaller pigment size can reduce light leakage caused by light scattering in the color filter between two crossed polarizers. The depolarization function was also proposed as a useful function for predicting the decrease in the contrast ratio of the color filter.

Effect of Reaction Conditions on Crystals in the Reaction Crystallization of Lanthanum Oxalate (란타늄 옥살레이트 반응성 결정화에서 반응조건에 따른 결정입자 연구)

  • Kim, Hong-Ju;Kim, Woon-Soo;Kim, Woo-Sik
    • Applied Chemistry for Engineering
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    • v.9 no.7
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    • pp.1004-1010
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    • 1998
  • Effects of reaction conditions such as power input and feeding time and feeding mode of reactants on the reaction crystallization of lanthanum oxalate in semi-batch reactor were investigated experimentally. Even though the crystal size distribution of lanthanum oxalate was always monomodal, its mean crystal size was significantly varied with the reaction conditions. As the power input and reactant feeding rate increased, the mean crystal size was reduced and the relative induction time was prolonged. The mean crystal size produced in oxalic acid feeding mode was smaller than that in lanthanum chloride feeding mode, but the trend of the relative induction time with the feeding mode was reverse to that of the mean crystal size. The crystal morphology of lanthanum oxalate, which was produced within the ranges of the reaction conditions in our experiment, was maintained as a needle shape.

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Particle Size, Morphology and Color Characteristics of C.I. Pigment Red 57:1 : 2. Effect of Salt Milling Process

  • Seo, Hee Sung;Lee, Hyun Kyung;Yoo, Eui Sang
    • Textile Coloration and Finishing
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    • v.27 no.4
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    • pp.245-260
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    • 2015
  • The effect of salt milling process on the crystal size, morphology, and color characteristics of C.I. Pigment Red 57:1 was studied. The primitive morphology and color properties of the pigment after synthesis were studied in the former series work. The size and morphology of primary particles and the second aggregation features should be considered because they are very important to determine pigment quality. We compared the primary morphology of pigment particles before drying with the secondary aggregated morphology of pigment particles after drying and salt milling process. Morphological properties were investigated by particle size analysis, X-ray diffraction, and scanning electron microscopy and color measurement was carried out. Significant reduction in particle size as well as enhanced crystallite size after salt milling process was observed. This result might give a difference in color of the pigment, turning into brighter and more blue-toned red color. It was revealed that synthesis condition affect the morphology and color of the pigment even after milling. Increase in HCl concentration in the synthesis process enhanced crystal size and quality forming bluer-red pigments but an increase in $CaCl_2$ concentration resulted in more amorphous crystals forming darker-red pigments after salt milling.

Controlled Crystallization and its Effects on Some Properties of Ge-Se-Te Chalcogenide Glass (Ge-Se-Te계 Chalcogenide 유리의 결정화 및 결정화가 물성에 미치는 영향)

  • 송순모;최세영;이용근
    • Journal of the Korean Ceramic Society
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    • v.33 no.8
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    • pp.855-862
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    • 1996
  • The nucleation and the crystal growth rates of Ge-Se-Te chalcogenide glass by two step heat-treatment and its effect on the mechanical optical properties and water-resistance were determined. The maximum nuclea-tion and crystal growth rate were 2.1$\times$103/mm3 .min at 28$0^{\circ}C$ and 0.4${\mu}{\textrm}{m}$/min at 33$0^{\circ}C$ respectively. When the crystal volume fraction with crystal size $1.5mutextrm{m}$ was about 4% the (hardness and fracture toughness were about 117kg/mm2 and 6.0 MPa.mm1/2)respectively. The weight loss of crystallized glass in water was lower than parent glass($25^{\circ}C$ for 32 hrs : 0.03% 8$0^{\circ}C$ for 16 hrs : 0.1%) as 0.01% at $25^{\circ}C$, 0.03% at 8$0^{\circ}C$ for 16 hrs : 0.1%) at $25^{\circ}C$ 0.03% at 8$0^{\circ}C$ respectively. The IR-transmittance decreased with increasing crystal size and crystal volume fraction. The IR-transmittance of crystallized glass with the crystal size of $1.5mutextrm{m}$ (crystal volume fraction : 4%) presented 56% which was about 4% lower than that of parent glass.

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