• Korean Chemical Engineering Research
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• v.62 no.1
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• pp.70-79
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• 2024

Raman analyzer is an analytical technique that utilizes the "Raman effect", which occurs when light is scattered by the inherent vibrations of molecules. It is used for molecular identification and composition analysis. In the natural gas industry, it is widely used in bunkering and tank lorry fields in addition to LNG export and import terminals. In this study, a LNG-specific Raman analyzer was installed and operated under actual field conditions to analyze the composition and principal properties (calorific value, reference density, etc.) of LNG. The measured LNG composition and calorific value were compared with those obtained by conventional gas chromatograph that are currently in operation and validated. The test results showed that the Raman analyzer provided rapid and stable measurements of LNG composition and calorific value. When comparing the calorific value, which serves as the basis for LNG transactions, with the results from conventional gas chromatograph, the Raman analyzer met the acceptable error criteria. Furthermore, the measurement results obtained in this study satisfied the accuracy criteria of relevant international standards (ASTM D7940-14) and demonstrated similar outcomes compared to large-scale international demonstration cases.

• 한국가스학회:학술대회논문집
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• 2001.10a
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• pp.35-44
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• 2001

Analytical and experimental studies have been performed to investigate the strength of the membrane and the reaction force at the anchor point. Using nonlinear FEM code and experiments, the stress analysis of the corrugated membrane related the cryogenic liquid pressure and thermal loading is performed to ensure the stability and fatigue strength of the membrane. This paper reports on the FEM results of membrane.

• Journal of Environmental Science International
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• v.14 no.1
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• pp.53-60
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• 2005

The concentrations of volatile organic compounds(VOCs) in the ambient air were measured at various point(Source, source boundary) in Seongseo industrial complex during May to November 2003. Air samples were collected in Silcocan canister $(1{\ell},\;6{\ell})$ and analyzed using a cryogenic preconcentration system and GC/MSD. We identified 37 species by the US EPA(TO-14 method). The result showed a variety distribution of the con­centration, Higher concentrations of BTX, Styrene, 1,3,5-Trimethylbenzene, 1,2,4-Trimethylbenzene were observed at the sampling sites. They seemed to be emitted from the facility of wastewater treatment, reaction tank of chemistry factory and facility of Tenter. The concentrations of VOCs contents in Seongseo industrial complex were generally higher than those in Yeosu complex and Ulsan complex, although those were similar in Sihwa­Banwol complex.

• Proceedings of the KWS Conference
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• 2010.05a
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• pp.28-28
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• 2010

The secondary barrier of cargo containment for membrane LNG tank is composed of composite materials such as rigid triplex (rigid secondary barrier, RSB) and flexible triplex (flexible secondary barrier, FSB). RSB and FSB are adhered to each other using an epoxy adherent and the quality of the secondary barrier depends on the bonding strength between them. The bonding strength between RSB and FSB is greatly influenced by the surface condition of RSB prior to joining. In this study, the effect of surface condition prior to joining on the joint strength and the fracture mode occurred between RSB and FSB have been examined in order to establish a proper surface treatment method for improving the bonding strength at the temperature of $-170^{\circ}C$.

• Journal of Aerospace System Engineering
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• v.14 no.5
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• pp.26-32
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• 2020

In this study, a facility was constructed to supply liquid nitrogen to simulate combustion instability in a liquid rocket combustor. The pressurization and supply performances were predicted and verified through different experiments. The liquid nitrogen supply system was composed of a pressurized supply system, and a dome regulator was used to adjust the pressure of the pressurant. A cavitation venturi was used to control the mass flow rate of liquid nitrogen. The condition of liquid nitrogen supply was a mass flow rate of 2.55 kg/s and the venturi inlet pressure was above 100 bar. Based on the initial experiment, it was observed that the predicted amount of the pressurant was not sufficiently supplied and the target pressure was not supplied due to a drop in tank pressure. Through the modification of the established facilities, the target mass flow rate was successfully supplied and the cryogenic liquid nitrogen supply facility was verified.

• Progress in Superconductivity and Cryogenics
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• v.19 no.4
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• pp.45-50
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• 2017

This paper presents a conceptual design and analysis for a 1-kW-class high-temperature superconducting rotating machine (HTSRM) rotor. The designed prototype is a small-scale integration system of a HTSRM and a HTS contactless rotary excitation device (CRED). Technically, CRED and HTSRM are connected in the same shaft, and it effectively charges the HTS coils of the rotor field winding by pumping fluxes via a non-contact method. HTS coils in rotor pole body and toroidal HTS wire in CRED rotor are cooled and operated by liquid nitrogen in cryogen tank located in inner-most of rotor. Therefore, it is crucial to securely maintain the thermal stability of cryogenic environment inside rotor. Especially, we critically consider not only on mechanical characteristics of the rotor but also on cryogenic thermal characteristics. In this paper, we conduct two main tasks covering optimizing a conceptual design and performing operational characteristics. First, rotor parameters are conceptually designed by analytical design codes. These parameters consider to mechanical and thermal performances such as mechanical strength, mechanical rigidity, and thermal heat losses of the rotor. Second, mechanical and thermal characteristics of rotor for 1-kW-class HTSRM are analyzed to verify the feasible operation conditions. Hence, three-dimensional finite element analysis (3D-FEA) method is used to perform these analyses in ANSYS-Workbench platform.

• Journal of the Society of Naval Architects of Korea
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• v.56 no.4
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• pp.335-342
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• 2019

The objective of this study is to analyze the mechanical properties of plywood used as a thermal insulating material for LNG CCS (Liquefied Natural Gas, Cargo Containment System). It is created by bonding an odd number of parallel and perpendicular direction for preventing contraction and expansion of wood. Also plywood is widely used as LNG CCS insulating material because of its durability, light weight and high stiffness. Since LNG CCS is loaded with liquid cargo, the impact load by sloshing during operation and the wide temperature range (room temperature, low temperature, cryogenic temperature) exposed during loading, unloading should be considered. The thickness of the plywood which is used for the membrane type MARKIII was selected as the thickness of the test specimen. In this present study, plywood is analyzed by the fracture behavior and mechanical properties of plywood by temperature and grain direction. In addition, it is necessary to analyze the fracture shape and predict the fracture strain by using regression model because the critical load may cause cracks inside the tank, which may affect the leakage of cryogenic liquid.

• Journal of the Korea institute for structural maintenance and inspection
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• v.14 no.4
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• pp.141-147
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• 2010

Liquefied natural gas(LNG) is natural gas that has been converted temporarily to liquid form for ease of storage and transport it. Natural gas is the worlds cleanest burning fossil fuel and it has emerged as the environmentally preferred fuel of choice. In Korea, the demand of this has been increased since the first import from the Indonesia in 1986. LNG takes up about 1/600th the volume of natural gas in the gaseous state by cooling it to approximately $-162^{\circ}C(-260^{\circ}F)$. The reduction in volume therefore makes it much more cost efficient to transport and store it. Modern LNG storage tanks are typically the full containment type, which is a double-wall construction with reinforced concrete outer wall and a high-nickel steel inner tank, with extremely efficient insulation between the walls. The insulation will be installed to LNG outer tank for the isolation of cryogenic temperature. The insulation will be installed in the base slab, wall and at the roof. According to the insulation's arrangement, the different aspects of temperature transmission is shown around the outer tank. As the result of the thermal & stress analysis, by the installing cellular glass underneath the perlite concrete, the temperature difference is greatly reduced between the ambient temperature and inside of concrete wall, also reducing section force according to temperature load.

• Journal of the Korean Society of Propulsion Engineers
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• v.9 no.3
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• pp.25-37
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• 2005

For pump-fed rocket propulsion system, the temperature of LOX to be supplied to turbopump inlet should be satisfied with pump inlet temperature requirement during all operating stages, as excessive temperatures can result in cavitation due to reduction in NPSH, thus either damaging the pump or adversely affecting pump performance rise. So exact estimation of LOX temperature rise is absolutely needed for developing reliable propulsion system. This paper presents systematic analysis scheme for estimating inner process of cryogenic propellant tank which is needed for LOX temperature rise. And this paper presents LOX temperature rise and thermal stratification for all rocket operating stages including cooling, filling, waiting, pre-pressurization and firing, with the application of buoyancy driven boundary layer theory.

• Journal of the Korean Society of Propulsion Engineers
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• v.27 no.1
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• pp.49-57
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• 2023

The autogenous pressurization has been widely adopted for propulsion systems of next-generation reusable rockets due to its low cost and high reliability. The autogenous pressurization has a simple structure, but an understanding of the heat and mass transfer occurring inside the tank is essential. For this reason, a simulation test of the autogenous pressurization was conceived. The experiment equipment was constructed based on overseas pressurization test facilities cases and expert advice. Unlike the actual autogenous pressurization system, the propellant tank was insulated to exclude external influences. The pressurized gas supply line and the propellant pipe were separated. Using the manufactured autogenous pressure experiment equipment, it is possible to evaluate the condensation phenomenon of pressurants in cryogenic propellants, comparison of the efficiency of pressurization using helium and evaporated gas and the pressurization capacity according to the temperature of pressurant.