• Korean Journal of Optics and Photonics
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• v.13 no.4
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• pp.275-282
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• 2002

We derived analytic formulae for the correction of spherical aberration, coma, and axial color of a two-components lens system consisted of a cemented doublet and a singlet by using the thin lens approximation. The correction formulae were applied to design a telephoto lens system. We examined two kinds of glass combinations in the design, one was crown-flint-crown combination and the other was flint-crown-flint combination. We found two kinds of achromatic aplanat solutions in the crown-flint-crown combination. For the case of flint-crown-flint combination, there were also two kinds of solutions, but their configurations are not useful in practice.

• Journal of the Korean Applied Science and Technology
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• v.22 no.1
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• pp.50-55
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• 2005

A comparison of alkali metal cation and alkaline earth cation solvent extraction was made for three additional monoionizable crown ethers and one diionizable crown ether. sym-(n-Octyldibenzo)-16-crown-5-oxyacetic acid $\underline{1}$ exhibited high efficiency and selecvity in solvent extraction of alkali metal cations with respect to that observed with alkaline earth cations. Sizes of $Na^+$ and $Ca^{2+}$ appropriately match with the cavity size of monoethyl sym-bis[4(5)-tert-butylbenzo]-16-crown-5-oxymethylphosphonic acid $\underline{3}$. As the result, $Na^+$ and $Ca^{2+}$ are the best extracted. sym-(n-Octyldibenzo)-16-crown-5-oxymethyldiphosphonic acid $\underline{4}$was found to be somewhat selective for $Na^+$ over $Li^+$ and other alkaline earth metal cations. In the complexation of alklaine earth cations by crown ether diphosphonic acid $\underline{4}$, $Ca^{2+}$ and $Sr^{2+}$ are the appropriate sizes, but lager $Ba^{2+}$ may be due to favorable formation of a sandwich type complex between the crown ether cavity and the dianion of the deprotonated crown ether phoaphonic acid moiety.

• Journal of the Korean Chemical Society
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• v.32 no.1
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• pp.71-78
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• 1988

The crown ether ring of 20, 21, 24, 25-tetranitrodibenzo-18-crown-6(TNDB-18-C-6) was cleaved by various alcoholic bases to give 2,4,5-trialkoxynitrobenzene derivatives and 4,5-dialkoxy-1,2-dinitrobenzene derivatives as the major products, and bis[(alkoxynitrophenoxy)ethyl]ether derivatives from partially cleaved crown ether ring as the minor products. The ring cleavage reaction of TNDB-18-C-6 with ethylene glycolic base resulted ring contraction through intramolecular nucleophilic cyclization of the initially formed ring cleavage product to give nitro derivatives of DB-14-C-4.

• The Journal of Korean Academy of Prosthodontics
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• v.30 no.1
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• pp.103-124
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• 1992

The purpose of this study was to investigate the effect on the fracture strength and color of ceramic by the design of the metal coping in ceramo metal crown. In this study, four types of ceramic crowns were made for fracture strength : standard ceramo metal crown, collariess ceramo metal crown, modified ceramo metal crown, and ceramic jacket crown. And three types of disk formed-specimens were made to compare the dentin shade owing to aluminous opaque powder and palladium alloy. Fracture strength was measured by universal testing machine(Instron Co. Ltd., U.S.A) and color was measured by color and color difference meter(Yasuda Seiki Seisakusho, Ltd., Japan). The results were as follows : 1. The fracture strength of ceramic was affected significantly by the design of metal coping in ceramo metal crown. The mean fracture strength(192.0 Kg) of standard ceramo metal crown was about 1.7 times higher than that(111.5 Kg) of collarless ceramo metal crown, and about 2.8 times higher than that(67.8 Kg) of ceramic jacket crown. 2. Modified ceramo metal crown that has metal band in the labio cervical had the lowest fracture strength. 3. Lightness, yellowness and redness of the dentin fired were decreased by the metal coping.

• Journal of Technologic Dentistry
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• v.29 no.2
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• pp.79-85
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• 2007

In this study, We tried to find out the fracture strength of zirconia coping all ceramic crown and collarless porcelain fused gold alloy crown as the compared group. Each of the collarless porcelain fused gold crown and zirconia all ceramic crown has been produced specimen 10 each. And after pasting them on the steel jig, it had load given at porcelain incisal edge by 130$^{\circ}$ and measured fracture strength by Universal Testing Machine and then We have results from that. 1. The average value of fracture strength suggested 950.49 N at collarless porcelain fused gold alloy crown, 656.81 N at zirconia coping all ceramic crown. 2. Fractured pattern showed that the whole of labial part was exposed in collarless porcelain fused gold crown, but porcelain of margin part did not show fracture in advance. In the practice, the concern that collarless might cause fracture strength to be weaken does not matter, we concluded zirconia all ceramic crown made fracture that only a part of labial porcelain was fractured. The combination of zirconia all ceramic crown and turned out to be excellent.

• The korean journal of orthodontics
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• v.16 no.2
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• pp.123-133
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• 1986

The purpose of this study was to collect the information of the straight-wire appliance and to determine the amount of second-order bends in clinical orthodontics. The author analysed the study model of 50 individuals with normal occlusion and results were obtained as follows. 1. The crown angulation was 4 degree in upper central incisor, 7 degree in upper lateral incisor, and 0 degree in lower central incisor and lateral incisor. 2. The crown angulation was 8 degree in upper cuspid and 2 degree in lower cuspid. 3. The crown angulations were 4 degree in upper first bicuspid, upper second bicuspid and lower second bicuspid and 1 degree in lower first bicuspid. 4. The crown angulation was 3 degree in upper first molar, 0 degree in upper second molar, 5 degree in lower first molar and 8 degree in lower second molar. 5. The crown angulations in lower arch were progressively increased from first premolar to second molar. 6. In upper arch, as the crown angulation of one tooth was increased, those of adjacent teeth were increased, too. 7. In the case of lower arch, the crown angulation of cuspid was increased as that of lateral incisor was increased, the crown angulation of second premolar was increased as that of first premolar was increased, and similarity the crown angulation of second molar was increased as that of first molar was increased.

• Journal of Dental Rehabilitation and Applied Science
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• v.31 no.1
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• pp.45-49
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• 2015

In this clinical report, a simple and convenient conversion of a fractured metal-ceramic surveyed crown into a complete contour zirconia surveyed crown by using computer-aided design and computer-aided manufacturing technology for an existing partial removable dental prosthesis is described. The duplication of the original contours, morphology, and the rest seat of the existing metal-ceramic surveyed crown, into a complete contour zirconia surveyed crown under anticancer treatments were reported.

• Journal of Dental Rehabilitation and Applied Science
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• v.18 no.2
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• pp.101-111
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• 2002

The purpose of this study was to evaluate the fracture strength of porcelain fused to gold crown and gold electroformed crown according to incisal and incisal under 3mm. In this study, 28 gold electroformed crown and 28 porcelain fused to gold crown were fabricated. Fracture strength testing was carried out using an Instron 8871(Instron Corporation, U.S.A) at a cross head speed of 5mm/min. All of the measurements were statistically analyzed by Independent t-testing, and k-s testing. Statistical significance was set in advance at the probability level of less than 0.05. All measurements were analized with Windows $SPSS^{(R)}$ Version 10.0 software for the personal computer. The results of this study were as follows; 1. Comparison by location (1) A compared fracture strength of incisal and incisal under 3 mm, there was statistical significant difference between gold electro -formed crown and porcelain fused to gold crown (p<0.05). 2. Comparison by loading (1) When compared fracture strength of incisal, there was no significant difference between gold electroformed crown ($619.90{\pm}53.54N$)and porcelain fused to gold crown($674.68{\pm}87.42N$). (2) When compared fracture strength of incisal under 3 mm, there was significant difference between gold electroformed crown($688.29{\pm}14.88N$) and porcelain fused to gold crown($1931.81{\pm}29.64N$) (p<0.05). 3. Mode of fracture When compared of fracture mode, gold electroformed crown showed mode of fracture and fracture line reaching coping region and porcelain fused to gold crown showed only in porcelain region.

• Membrane Journal
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• v.6 no.4
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• pp.265-272
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• 1996

The (polymer/carrier) composite membranes for separating the metallic ion have been prepared by the water cast-method. The morphology of these membranes was affected by the physical properties of the spreading solution. The surface tension of the (polymer/18-crown-6) composite solution was decreased with increasing the concentration of 18-crown-6 compound and the surface tension of polymer solution decreased the following order PVC>PS>CA. The viscosity of CA solution decreased with increasing the contents of the 18-crown-6 compound, but PVC and PS solutions showed no significance changes according as the concentration of 18-crown-6 compound. In the composite solutions, the spreading ability was improved by' the cyclic 18-crown-6 molecules which acted as an electric buffer and diminished the intermolecular force between the polymer chains. The (polymer/18-crown-6) composite membrane was more uniform than that of the mono polymer membrane on the coagulation state of polymer, and the top and bottom sides of membrane showed also the more smooth structure according as the concentration increment of 18-crown-6 molecule.

• Journal of the Korean Applied Science and Technology
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• v.22 no.3
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• pp.219-227
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• 2005

Competitive solvent extraction of the mixure of alkali metal and alkaline earth cation from water into organic solvent containing the crown ether carboxylic acid and anlogous crown ether phosphonic acid was investigated as follows. The lipophilic group is found to strongly influence to the selective extraction in the mixed systems from only alkali metal cation for sym-(n-decyldibenzo)-16-crown-5-oxyacetic acid $\underline{1}$ to mostly alkaline earth metal cation for sym-bis[4(5)-tert-butylbenzo]-16-crown-5-oxyacetic acid $\underline{3}$. Monoethyl sym-(n-decyldibenzo)-16-crown-5-oxymethylphosphonic acid $\underline{2}$. and monoethyl-sym- bis]4(5)-tert-butylbenzo]-16-crown-5-oxymethylphosphonic acid $\underline{4}$ showed good selectivity for $Na^+$ over $Mg^{2+}$, the second extracted ion. Structural variation in the crown ether phosphonic acid somewhat was influenced to the extraction selectivity in the mixed systems. when variation of the ionized group is influenced in the mixed systems, the selectivity of $Na^+$ as the second extracted ion was much better crown ether carboxylic acid $\underline{1}$ than crown ether phosphonic acid $\underline{2}$, while the efficiency of $Na^+$ extraction was better $\underline{2}$ (83% total loading) than $\underline{1}$ (32%).