• 제목/요약/키워드: Crowding-in

검색결과 361건 처리시간 0.026초

AM1 Studies on the Gas-Phase Pyrolysis of Iminoethers, 2-Alkoxypyridines, 2-N-Alkylated Pyridones and N-Alkylated Acetamides

  • Bon-Su Lee;Chang Kon Kim;Ikchoon Lee
    • Bulletin of the Korean Chemical Society
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    • 제12권5호
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    • pp.560-564
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    • 1991
  • The gas-phase pyrolysis reactions of iminoethers (Ⅱ), 2-alkoxypyridines (Ⅲ), 2-N-alkylated pyridones (Ⅳ) and N-alkylated acetamides (Ⅴ) have been studied MO theoretically with the AM1 method. The decomposition of these compounds proceeds by a concerted retro-ene process through a six-membered cyclic transition state. The reactivity decreases in the order (Ⅱ) > (Ⅲ) > (Ⅳ) > (Ⅴ), with a greater reactivity for the imine series, (Ⅱ) and (Ⅲ), compared to the amide series, (Ⅳ) and (Ⅴ), and a difference in basicity between the N and O atoms. Within a given series, however, the reactivity is dictated mainly by the aromaticity in the transition state. The reactivity order with respect to side alkyl chain of a species was found to increase as the steric crowding effect increases. The AM1 reactivity in this work agree well with the experimental results.

관악기연주군과 비관악기군의 치열궁 및 Crowding에 관한 비교연구 (COMPARISONS OF DENTAL ARCHES AND CROWDINGS BETWEEN MUSICAL WIND-INSTRUMENT PLAYERS GROUPS AND NON-WIND INSTRUMENT PLAYERS GROUP)

  • 이원유
    • 대한치과교정학회지
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    • 제17권2호
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    • pp.289-297
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    • 1987
  • For the comparisons of dental archs and crowdings between musical wind instrument players groups and non-wind instrument players groups, 64 male wind instrument players and 31 non-wind instrument players group were selected. The results of the measurements were as follow. 1 Upper intercanine widths, upper basal arch widths, lower basal arch widths were statistically significant between musical wind instrument players groups (Class A, Class B) and non-wind musical instrument players group. 2 The mean value of upper intercanine width m Class A ($373{\pm}2.3mm$) was greater than than in Class B ($362{\pm}17mm$) and non-wind musical instrument players group($360{\pm}16mm$) 3 The mean value of lower basal arch width m Class B ($422{\pm}25mm$) was greater than that in non wind instrument players group ($395{\pm}28mm$). 4 The differences in the mean values of crowdings between Class A and Class Band non-wind instrument players group were not statistically significant.

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Single -portal Subscapualrs tendon repair

  • 최창혁;김신근;장호진;채성범
    • 대한견주관절학회:학술대회논문집
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    • 대한견주관절학회 2008년도 제16차 학술대회
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    • pp.179-179
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    • 2008
  • For a partial tear of the subscapularis tendon, the presenting technique requires only the anterior portal for preparing the footprint and suture management, as well as the subclavian portal for placing the suture anchor and suture hook without inserting a cannula. It provides both a good angle for anchor placement and sufficient space for managing the upper portion of a subscapularis tendon tear. A spinal needle was inserted through the subclavian portal in order to identify the appropriate angle for placing the suture anchor. A 3-mm incision was made for the subclavian portal and a biosuture anchor was placed on the footprint portion of the subscapularis tendon. In order to avoid crowding, each limb of both strands of the biosuture anchor were passed through the tendon- posteromedial side first, and anterolateral side second, using a switching technique with suture hook embedded with no.1 PDS. A suture tie was applied in a reverse sequence (the lateral strand first and the medial strand second) through the anterior cannula using a sliding technique.

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혼합 유전 알고리즘을 이용한 GDP/MINLP로 표현된 공정 최적화 (Process Optimization Formulated in GDP/MINLP Using Hybrid Genetic Algorithm)

  • 송상옥;장영중;김구회;윤인섭
    • 제어로봇시스템학회논문지
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    • 제9권2호
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    • pp.168-175
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    • 2003
  • A new algorithm based on Genetic Algorithms is proposed f3r solving process optimization problems formulated in MINLP, GDP and hybrid MINLP/GDP. This work is focused especially on the design of the Genetic Algorithm suitable to handle disjunctive programming with the same level of MINLP handling capability. Hybridization with the Simulated Annealing is experimented and many heuristics are adopted. Real and binary coded Genetic Algorithm initiates the global search in the entire search space and at every stage Simulated Annealing makes the candidates to climb up the local hills. Multi-Niche Crowding method is adopted as the multimodal function optimization technique. and the adaptation of probabilistic parameters and dynamic penalty systems are also implemented. New strategies to take the logical variables and constraints into consideration are proposed, as well. Various test problems selected from many fields of process systems engineering are tried and satisfactory results are obtained.

Theoretical Studies on the Gas-Phase Pyrolysis of 2-Alkoxypyrimidines, 2-Alkoxypyrazines, 4-Ethoxypyrimidine and 3-Ethoxypyridazine

  • Kim, Chang-Kon;Lee, Bon-Su;Lee, Ik-Choon
    • Bulletin of the Korean Chemical Society
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    • 제13권1호
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    • pp.32-36
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    • 1992
  • The gas-phase pyrolysis reactions of 2-alkoxypyrimidines(II), 2-alkoxypyrazines(III), 4-ethoxypyrimidine(IV) and 3-ethoxypyridazine(V) are investigated theoretically using the AM1 MO method. These compounds pyrolyze in a concerted retro-ene process with a six-membered cyclic transition state (TS). The relative order of reactivity if (IV)>(II)>(III)>(V), which can be rationalized by the two effects arising from electron-withdrawing power of the aza-substituent: (ⅰ) Electron withdrawal from the C-O bond accelerates the rate and (ⅱ) electron withdrawal from the $N^1$-atom, that is participating in the six-membered TS, deactivates the reaction. We are unable to explain the experimental result of the greatest reactivity for pyridazine, (V), with our AM1 results. The reactivity increase accompanied by successive methylation of the ethoxy group, ethoxytert-butoxy, is due to a release of steric crowding in the activation process.

Bone-borne type distractor를 사용한 하악골 정중부 골신장술 (DISTRACTION OSTEOGENESIS ON MANDIBLE SYMPHYSIS WIDENING WITH A BONE-BORNE TYPE DISTRACTOR)

  • 조진형;지영덕
    • Maxillofacial Plastic and Reconstructive Surgery
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    • 제28권4호
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    • pp.356-364
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    • 2006
  • Transverse mandibular deficiency has a many problem in growing patients. Therefore, Mandible symphysis widening is recommended. A new surgical technique has been developed to widen the mandible. The purpose of this study is to report the effect of mandibluar symphyseal distraction osteogenesis by use of bone-borne type distractor. The surgical procedure was accomplished under general anaesthesia with step-line osteotomy. Bone-borne type distractor was used to generally widen the mandible. The expansion achieved in the mandible was 8.31mm at the device, 6.32mm at the canines, 4.06mm at the first molars. The symphyseal distraction gaps were bridged by new bony regeneration. Mandibular symphseal distraction osteogenesis increased mandibular arch width, stabilized occlusion, and corrected dental crowding.

하악골의 측방운동 및 전방운동 형태와 이에 따른 치아 동요도에 관한 통계학적 연구 (The Statistical Study of Tooth Mobility on the Occlusion Patterns)

  • 이명호
    • 대한치과보철학회지
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    • 제22권1호
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    • pp.79-84
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    • 1984
  • The stability of teeth is an important measure of the periodontal health. This study was designed to determine if there was a relation between the patterns of disclusion and a tooth mobility. An evaluation was made on 117 persons with Angle's class I occlusion who were free from histories of orthodontics, removable or fixed prosthesis, and anterior crowding or open contacts. The results were as follows: 1. In this study, 17.52% of the subjects were exhibited canine protected occlusion. 2. In protrusive movements, 75.21% of the subjects were exhibited incisor guided occlusion and the subjects of canine guided occlusion was the smallest. 3. The canine tooth of mouths having canine-protected occlusions had slightly lower mean tooth mobility scores than the canine of mouths having group function occlsion, but there was no significances. 4. The tooth mobility score of central incisor had higher than that of lateral incisor.

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INTRODUCTION TO DIFFUSIVE LOGISTIC EQUATIONS IN POPULATION DYNAMICS

  • Taira, Kazuaki
    • Journal of applied mathematics & informatics
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    • 제9권2호
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    • pp.459-517
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    • 2002
  • The purpose of this paper is to provide a careful and accessible exposition of diffusive logistic equations with indefinite weights which model population dynamics in environments with strong spatial heterogeneity. We prove that the most favorable situations will occur if there is a relatively large favorable region (with good resources and without crowding effects) located some distance away from the boundary of the environment. Moreover we prove that a population will grow exponentially until limited by lack of available resources if the diffusion rate is below some critical value; this idea is generally credited to Thomas Malthus. On the other hand, if the diffusion rate is above this critical value, then the model obeys the logistic equation introduced by P. F. Verhulst .

대구치의 자가이식을 동반한 골격성 II급 부정교합의 악교정수술 치험례 (Autotransplantation of a Third Molar as a Lower Second Molar Combined with Orthognathic Surgery)

  • 최윤정;김경호;정주령
    • 대한구순구개열학회지
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    • 제16권1호
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    • pp.25-35
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    • 2013
  • We report the treatment of an adult Class II malocclusion with severe crowding and a hopeless lower second molar. According to the treatment plan, 4 premolars and 4 third molars were to be extracted for 2-jaw surgery. To replace the hopeless lower second molar, one upper third molar was successfully autotransplanted during the pre-surgical orthodontic treatment. Multiple teeth are frequently extracted for treatment purposes in adult surgical cases. Under precise diagnosis, the reuse of extracted teeth to replace missing teeth can be a successful alternative even in adult surgical patients.

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High-performance InGaN/GaN-based Light-emitting Diodes Using Advanced Technical Approaches

  • Jang, Ja-Soon
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.108-108
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    • 2012
  • High-performance GaN-based light emitting diodes (LEDs) with high efficiency and excellent reliability have been of technological importance forapplications in full color display, automotive lighting, and solid state lighting. To realize high-performance and excellent-reliability LEDs, various technologies such as surface texturing, transparent conducting oxide, surface Plasmon, highly p-conduction layer, current blocking layer, photon-enhanced layer, and nanostructures have been extensively investigated. Among them, advanced core technologies based on how to suppress surface leakage and current crowding, how to enhance current injection efficiency and output power, and how to resist electrostatic damage will be displayed and discussed using our reported and preliminary results. New approaches like integrated LEDs will be also introduced and discussed.

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