• Title/Summary/Keyword: Crosslinking coagent

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Water Tree Characteristics of XLPE/EnBA Blends as a function of Crosslinking Coagent Contents (XLPE/EnBA에서의 가교조제에 따른 수트리 특성)

  • 오우정;서광석;김종은
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.219-222
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    • 1998
  • In this study, The water tree characteristics were investigated when crosslinking coagent was added in XLPE/EnBA blends. When XLPE was blended with EnBA, there was a decrease of water tree length as an increase of nBA contents in XLPE/EnBA20 blends. The effect of crosslinking coagent. A was better than those of other crosslinking coagents B, C and D in water tree retardation. In case of XLPE/EnBA/Crosslinking coagent blends, water tree length was increased as the crosslinking coagents were increased from 0.2 to 2 phr in 2.0 phr DCP content. To clarify the effects of crosslinking coagent, the DCP contents were changed from 1.5 to 2.0 par in the same crosslinking coagent contents. Then, there was a decrease of water tree length as an increase of crosslinking coagent contents in 1.5 and 1.8 phr DCP contents.

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Space Charge Behaviors of New Insulating Materials for URD cables (새로운 지중배전케이블용 절연재료의 공간전하 거동)

  • 고정우;서광석;김종은;남윤선;김덕주
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.11a
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    • pp.207-210
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    • 1998
  • Electrical properties such as space charge distribution and electrical conduction of XLPE/VLDPE blends were studied. When the VLDPE is blended, residual charge inside XLPE increases. In case of electrical conduction characteristics, there were no changes in electrical conduction mechanism, space charge limited conduction. XLPE/VLDPE blend including crosslinking coagent showed relatively small current density. It might be due to the carbonyl group in crosslinking coagent.

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Space charge characteristics of XLPE/EPDM laminate with interfacial condition (XLPE/EPDM laminate의 계면조건에 따른 전하형성 특성)

  • Nam, Jin-Ho;Suh, Kwang-S.
    • Proceedings of the KIEE Conference
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    • 1997.11a
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    • pp.299-301
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    • 1997
  • It was investigated that space charge characteristics of EPDM/XLPE laminates as a function of interfacial condition. There were no effects in charge accumulation characteristics at EPDM/XLPE laminate samples pasted treated silicone oil and silicone grease. But when the crosslinking coagent (TMPTA) was pasted in laminate samples, there was no space charge in interface of EPDM/XLPE laminate. There were no effects in the laminate sample pasted silicone grease dissolved crosslinking coagent. In the coupling agent pasted EPDM/ XLPE laminate sample, space charge was accumulated in XLPE side caused by coupling agent.

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Space charge characteristics of XLPE/EPDM laminate with interfacial condition (계면조건에 따른 XLPE/EPDM laminate의 공간전하 특성)

  • 남진호;서광석
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.140-143
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    • 1997
  • It was investigated that space charge characteristics of EPDX/LPE laminates as a function of interfacial condition. There were no effects in charge accumulation characteristics at EPDM/XLPE laminate samples which were pasted with silicone oil and silicone grease. But when the crosslinking coagent (TMPTA) was pasted in laminate samples, there was no space charge in interface of EPDE/XLPE laminate and no effects in the laminate sample pasted with silicone grease dissolved crosslinking coagent. In the coupling agent pasted EPDhyXLPE laminate sample, space charge was accunlulated in XLPE side caused by coupling agent.

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Effects of Interfacial Conditions on Breakdown Strength of XLPE/EPDM Laminates (XLPE/EPDM의 계면조건이 절연파괴강도에 미치는 영향)

  • Choi, W.C.;Lee, C.J.;Jo, D.S.;Park, K.S.;Kim, J.S.;Han, S.O.
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1273-1275
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    • 1998
  • The main faults at cable joint are mainly originate from double layered structure, which is composed of different kinds of materials such as XLPE/EPDM laminatest. In this paper, to investigate the effect of interfacial condition and coagents on dielectric strength of XLPE/EPDM, we prepared XLPE/grease/EPDM, XLPE/grease + coagent/EPDM laminates. Dielectric strength of the XLPE/EPDM laminates pasted with the grease compounded crosslinking coagent (TMPTA, TMPTMA) is higher than that of the laminates paseted with the grease without coagent.

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Interfacial phenomena of XLPE/EPDM laminates (XLPE/EPDM laminates의 계면현상)

  • 남진호;서광석;김지환;고광철
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.11a
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    • pp.211-214
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    • 1998
  • DC breakdown characteristics and formation of space charge at the interfaces of crosslinked polyethylene (XLPE) /ethylene propylene diene terpolymer (EPDM) laminates were studied. Effects of silicone grease and some chemicals such as crosslinking coagent on the interfacial charge were also studied. Interfacial charge develops at the interface of XLPE/EPDM laminates, which changes depending on heat treatment conditions and types of chemicals coated at the interface. Some chemicals such as maleic anhydride reduce the accumulation of interfacial charge in the XLPE/EPDM laminates. Breakdown strength of EPDM/XLPE laminate through the interface was highest when silicone oil was pasted in the interfaces. Interfacial breakdown strength decreased with the increase of MAH content.

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Electrical and Physical Properties of XLPE/EnBA Blends (XLPE/EnBA 블렌드의 전기 및 물리적 성질)

  • 서광석;오우정;이승형
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.12
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    • pp.1060-1069
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    • 1998
  • Electrical properties such as space charge accumulation and water tree length and physical properties such as tensile strength, elongation and degree of crosslinked polyethylene (XLPE)/ethylene n-butyl acrylate copolymer (EnBA) blends were investigated. It was found that electrical properties such as water tree length grown at a specific condition and AC breakdown strength are improved by blending the XLPE with EnBA. The EnBA having higher nBA content showed the better electrical properties in XLPE/EnBA blends. A further improvement of these properties was achieved when a small amount of crosslinking coagent was used in the preparation of XLPE/EnBA blends.

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