• Title/Summary/Keyword: Cross diffusion

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Study on Shear Bond Strength of Ni-Cr Alloy for Porcelain Fused to Metal Crown at the Temperature of Degassing (치과 도재용착용 Ni-Cr 합금의 열처리에 따른 결합력 연구)

  • Joo, Kyu-Ji;Shin, Jae-Woo;Cho, Hong-Kyu
    • Journal of Technologic Dentistry
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    • v.38 no.2
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    • pp.69-77
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    • 2016
  • Purpose: This study was to evaluate the shear bond strength of ceramic fused to Ni-Cr alloy(Alophaloy) by heat treatment. Methods: The specimens were divided into 5 groups according to heat treatment conditions prior to porcelain application. Eighteen specimens from each group were subjected to the shear load a universal testing machine using a 0.1mm/min cross-head speed and two specimens from each group were observed with SEM and EDX line profile. Results: The observation of the oxide film on the metal surface by SEM photograph showed a coarsening with an increasing degassing hold time. The diffusion of metal oxide was observed farther from the opaque layer in the heat treated specimen than no heat treated specimen. The shear bond strength measured highest to A5(55.23MPa) in the 10min holding group and measured lowest from A1(24.38MPa) in the no heat treated group, and there was a significant difference(p<0.05). Conclusion: The shear bond strength of Ni-Cr alloy improved in the heat treatment compared to the no heat treatment specimen.

Fabrication of coated conductor stacked multi-filamentary wire (적층형 초전도 다심 선재 제조)

  • Yun, K.S.;Ha, H.S.;Oh, S.S.;Moon, S.H.;Kim, C.J.
    • Progress in Superconductivity and Cryogenics
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    • v.14 no.1
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    • pp.4-7
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    • 2012
  • Coated conductors have been developed to increase piece length and critical current for electric power applications. Otherwise, Many efforts were carried out to reduce AC loss of coated conductor for AC applications. Twisting and cabling processes are effective to reduce AC loss but, these processes can not be applied for tape shaped coated conductor. It is inevitable to have thin rectangular shape because coated conductor is fabricated by thin film deposition process on metal substrate. In this study, round shape superconducting wire was first fabricated using coated conductors. First of all, Ag coated conductor was used. coated conductor was slitted to several wires with narrow width below 1mm. 12ea slitted wires were parallel stacked on top of another until making up the square cross-section. The bundle of coated conductors was heat treated to stick on each other by diffusion bonding and then copper plated to make round shape wire. Critical current of round wire was measured 185A at 77K, self field.

Synthesis and Swelling Kinetics of a Cross-Linked pH-Sensitive Ternary Copolymer Gel System (pH-민감성 삼성분계 공중합체 젤의 합성 및 팽윤 속도론)

  • Zafar, Zafar Iqbal;Malana, M.A.;Pervez, H.;Shad, M.A.;Momma, K.
    • Polymer(Korea)
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    • v.32 no.3
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    • pp.219-229
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    • 2008
  • A pH sensitive ternary copolymer gel was synthesized in the presence of ethylene glycol dimethacrylate (EGDMA) as a crosslinking agent through radical polymerization of vinyl acetate (VA), acrylic acid (AA) and methyl acrylate(MA) with a weight ratio of 1 : 1.3 : 1. A number of experiments were carried out to determine the swelling behavior of the gel under a variety of pH conditions of the swelling medium. As the pH of the swelling medium was changed from 1.0 to 8.0 at $37^{\circ}C$, the gel showed a shift in the pH-dependent swelling behavior from Fickian (n=0.3447) to non-Fickian (n=0.9125). The resulting swelling parameters were analyzed using graphical and statistical methods. The results showed that the swelling of the gel was controlled by the pH of the medium, i.e. $n=n_o{\exp}(S_{C}pH)$, where n is the diffusion exponent, $n_o(=28.9645{\times}10^{-2})$ is the pre-exponential factor and $S_C$(=0.1417) is pH sensitivity coefficient. The swelling behavior of the gel was also examined in aliphatic alcohols. The results showed that the rate of swelling increased with increasing number of carbon atoms in the alcoholic molecular chain.

MEMBRANES FOR GAS AND LIQUID SEPARATIONS

  • Golemme, Giovanni;Bove, Lucia;Clarizia, Gabriele;Muzzalupo, Rita;Ranieri, Giuseppe;Nam, Sang-Yong;Drioli, Enrico
    • Proceedings of the Membrane Society of Korea Conference
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    • 1999.07a
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    • pp.27-30
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    • 1999
  • Poly(phenylene oxide)s were used to prepare flat, integrally skinned self-supporthed asymmetric membranes by dry-wet phase separption. The intrinsic ideal gas selectivity of poly- (2,6-dimethy-1,4-phenylene oxide) (PMPO) was retained in the membranes, and improved by a coating with silicone rubber. Polymers of the same class were coated of UF supports with a silicon rubber gutter layer, yielding composite membranes with high flux but lower selectivity. The effect of th glutaraldehyde cross-linking of sodium alginate (SA) membranes on the mobility of water and ethanol has been studied with pfg nmr. Crosslinking reduces water self-diffusion, and does not seem to be stable on the timescale of weeks.

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Iontophoretic Transport of Ketoprofen (이온토포레시스를 이용한 케토프로펜의 경피전달)

  • Kim, Jung-Ae;Oh, Seaung-Youl
    • Journal of Pharmaceutical Investigation
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    • v.34 no.4
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    • pp.275-281
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    • 2004
  • We have studied the effect of polarity, current density, current duration, crosslinking density, swelling ratio, and permeation enhancers on the transdermal flux of ketoprofen from acrylamide hydrogel. Hydrogel was prepared by free radical crosslinking polymerization of acrylamide. Drug loading was made just before transport experiment by soaking the hydrogel in solution containing drug. In vitro flux study using hairless mouse skin was performed at $36.5^{\circ}C$ using side-by-side diffusion cell, and the drug was analysed using HPLC/UV system. The result showed that, compared to passive flux, the total amount of drug transported increased about 18 folds by the application of $0.4\;mA/cm^2$ cathodal current. Anodal delivery with same current density also increased the total amount of drug transported about 13 folds. It seemed that the increase in flux was due to the electrorepulsion and the increase in passive permeability of the skin by the current application. Flux increased as current density, the duration of current application and loading amount (swelling duration) increased. As the cross linking density of the hydrogel increased, flux clearly decreased. The effect of hydrophilic enhancers (urea, N-methyl pyrrolidone, Tween 20) and some hydrophobic enhancers (propylene glycol monolaurate and isopropyl myristate) was minimal. However, about 3 folds increase in flux was observed when 5% oleic acid was used. Overall, these results provide some useful information on the design of an optimized iontophoretic delivery system of ketoprofen.

Numerical modelling for evaluating the TMD performance in an industrial chimney

  • Iban, A.L.;Brownjohn, J.M.W.;Belver, A.V.;Lopez-Reyes, P.M.;Koo, K.
    • Wind and Structures
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    • v.17 no.3
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    • pp.263-274
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    • 2013
  • A numerical technique for fluid-structure interaction, which is based on the finite element method (FEM) and computational fluid dynamics (CFD), was developed for application to an industrial chimney equipped with a pendulum tuned mass damper (TMD). In order to solve the structural problem, a one-dimensional beam model (Navier-Bernoulli) was considered and, for the dynamical problem, the standard second-order Newmark method was used. Navier-Stokes equations for incompressible flow are solved in several horizontal planes to determine the pressure in the boundary of the corresponding cross-section of the chimney. Forces per unit length were obtained by integrating the pressure and are introduced in the structure using standard FEM interpolation techniques. For the fluid problem, a fractional step scheme based on a second order pressure splitting has been used. In each fluid plane, the displacements have been taken into account considering an Arbitrary Lagrangian Eulerian approach. The stabilization of convection and diffusion terms is achieved by means of quasi-static orthogonal subscales. For each period of time, the fluid problem was solved and the geometry of the mesh of each fluid plane is updated according to the structure displacements. Using this technique, along-wind and across-wind effects have been properly explained. The method was applied to an industrial chimney in three scenarios (with or without TMD and for different damping values) and for two wind speeds, showing different responses.

Factors Affecting the Purchase Intention of Mobile Advertising : Focusing on the Comparison between Korea and Russia (모바일 광고특성이 구매의도에 미치는 영향: 한국과 러시아를 중심으로)

  • Kim, Seung-Gweon;Yoon, Jong-Soo
    • Journal of the Korea Society of Computer and Information
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    • v.19 no.11
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    • pp.183-192
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    • 2014
  • With the rapid mobile phones and global diffusion of mobile marketing it is very important to understand cross-national consumer attitude and behavioral intentions toward mobile marketing as a promotional channel. Some areas of mobile advertising still need more investigation. Especially, the topic about consumer attitude toward mobile advertising has been received a considerable amount of attention. Based on the Technology Acceptance Model (TAM), this study investigates the relationship between characteristic of mobile advertising and purchase intention toward mobile advertising, and analyzes moderating effect of country type. The result of this study could help researchers and practitioners to understand which factors should be managed to increase the effectiveness of mobile advertising.

FE-SEM Image Analysis of Junction Interface of Cu Direct Bonding for Semiconductor 3D Chip Stacking

  • Byun, Jaeduk;Hyun, June Won
    • Journal of the Korean institute of surface engineering
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    • v.54 no.5
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    • pp.207-212
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    • 2021
  • The mechanical and electrical characteristics can be improved in 3D stacked IC technology which can accomplish the ultra-high integration by stacking more semiconductor chips within the limited package area through the Cu direct bonding method minimizing the performance degradation to the bonding surface to the inorganic compound or the oxide film etc. The surface was treated in a ultrasonic washer using a diamond abrasive to remove other component substances from the prepared cast plate substrate surface. FE-SEM was used to analyze the bonding characteristics of the bonded copper substrates, and the cross section of the bonded Cu conjugates at the sintering junction temperature of 100 ℃, 150 ℃, 200 ℃, 350 ℃ and the pressure of 2303 N/cm2 and 3087 N/cm2. At 2303 N/cm2, the good bonding of copper substrate was confirmed at 350 ℃, and at the increased pressure of 3087 N/cm2, the bonding condition of Cu was confirmed at low temperature junction temperature of 200 ℃. However, the recrystallization of Cu particles was observed due to increased pressure of 3087 N/cm2 and diffusion of Cu atoms at high temperature of 350 ℃, which can lead to degradation in semiconductor manufacturing.

Detection of Inducible Clindamycin Resistance Genes (ermA, ermB, and ermC) in Staphylococcus aureus and Staphylococcus epidermidis

  • Mazloumi, Mohammad Javad;Akbari, Reza;Yousefi, Saber
    • Microbiology and Biotechnology Letters
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    • v.49 no.3
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    • pp.449-457
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    • 2021
  • The aim of the present study was to survey the frequency of inducible and constitutive phenotypes and inducible cross-resistant genes by regulating the methylation of 23S rRNA (ermA, ermB, and ermC) and macrolide efflux-related msrA gene in Staphylococcus aureus and S. epidermidis strains. A total of 172 bacterial isolates (identified based on standard tests), were examined in this study. Antibiotic susceptibility was determined by the disk diffusion method, and all isolates were evaluated with respect to inducible and constitutive phenotypes. The presence of ermA, ermB, ermC, and msrA genes was investigated by a PCR assay. The constitutive resistance phenotypes showed a higher distribution among the isolates. R phenotype was detected more among S. epidermidis isolates (46.25%). ermB, ermC, and msrA genes were detected more in methicillin-resistant S. aureus (MRSA) and methicillin-resistant S. epidermidis (MRSE) isolates that had R and HD phenotypes (>77% strains). The ermA gene had the lowest frequency among MRSA, MRSE, MSSA, and MSSE strains (<14% isolates). Distribution of inducible resistance genes in MRSA and MRSE strains, and possibly other species, leads to increased constitutive resistance to erythromycin, clindamycin, and other similar antibiotics. Therefore, it can be challenging to treat infections caused by these resistant strains.

The Relationship Between Islamic Microfinance and Women Entrepreneurship: A Case Study in Malaysia

  • ISLAM, Md Amirul;THAMBIAH, Seethaletchumy;AHMED, Elsadig Musa
    • The Journal of Asian Finance, Economics and Business
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    • v.8 no.5
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    • pp.817-828
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    • 2021
  • This article aims to examine the intention to use Islamic microfinance by women entrepreneurs in Malaysia. Microfinance plays a significant role in developing the modern economy in the world by alleviating poverty, creating employment, and empowering women in society. The framework was built on Innovation and Diffusion Theory and Planned Behaviour Theory. The present study has adopted a quantitative research method, which focused on cross-sectional research design to address this problem. Primary data was collected and processed by using a 5-point Likert scale. For this research, a total of 178 questionnaires were distributed among women owners of micro-enterprises in Malaysia by using area collection sampling. To analyze the data, the SmartPLS 3 software package was used. This study developed seven hypotheses, all which have been supported both directly, indirectly, and mediated. This result will be beneficial in assisting policymakers, academics and future researchers who must consider the supported variables. Thus, the study contributes to developing a unique framework to assist women-owned micro-enterprise to success. It will be beneficial for practitioners to enhance women micro-enterprise success rate as well. Indeed, all of the grounded methods have implications both in theory and their main application for the business in SMEs.