• 제목/요약/키워드: Critical properties

검색결과 2,261건 처리시간 0.031초

복합화약 원료들간의 표면특성 해석 (Analysis of surface interaction between filler and binder of PBXs)

  • 심정섭
    • 한국군사과학기술학회지
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    • 제4권1호
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    • pp.207-215
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    • 2001
  • Plastic bonded explosive(PBX) is mainly composed of the nitramine-ploymer compositions. PBX is characterized by high velocity and pressure of detonation, low vulnerability and good thermal stability. Many important applications of PBX require the good adhesion between nitramine crystals and the binder. For PBXs as well as propellants, where good mechanical properties are of great importance, dewetting therefore must be prevented by strong adhesion between filler-binder. Adhesion depends on surface characteristics of filler and binder. In order to design for better adhesion, an understanding of the surface properties of explosive and binder is required. The surface free energies are calculated from contact angle values by the method of Kaelble. Critical surface tension of solids are calculated by Zisman plot. Critical surface tension is a useful parameter for characterizing the wettability of solid surface. In this study, HMX and 3 kinds of copolymers are selected, since they are widely used in many plastic bonded explosives. The technical objective of this investigation is to predict the interaction between filler and binder from their surface free energies.

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인장-굽힘모드에서 Bi-2223 초전도 테이프의 임계전류 열화거동 (Degradation Behavior of Critical Current in Bi-2223 Superconducting Tape in Bending-Tension Mixed Mode)

  • 신형섭;김병수;최호연;오상수;하동우;하홍수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.1
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    • pp.573-576
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    • 2003
  • HTS superconducting tapes are now commercially available for practical applications such as magnets and cables. Since superconductors in such applications are subjected to high mechanical loads that can significantly degrade the superconducting properties, mechanical properties and the strain tolerance known as the strain effect on superconducting properties are needed to be estimated for developing superconducting devices. Influences of loading mode on the Ic degradation and the interaction on strain effect were discussed in this study.

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Influence of MWCNTs on Fracture Toughness of MWCNTs/Nickel-Pitch Fiber/Epoxy Composites

  • Yim, Yoon-Ji;Park, Soo-Jin
    • Composites Research
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    • 제28권6호
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    • pp.361-365
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    • 2015
  • The influence of MWCNTs on fracture toughness properties of MWCNTs/Nickel-Pitch Fibers/epoxy composites (MWCNTs/Ni-PFs/epoxy) was investigated according to MWCNTs content. Nickel-Pitch-based carbon fibers (Ni-PFs) were prepared by electroless nickel-plating. The surface properties of Ni-PFs were determined by scanning electron microscopy (SEM) and X-ray photoelectron spectrometry (XPS). The fracture toughness of MWCNTs/Ni-PFs/epoxy was assessed by critical stress intensity factor ($K_{IC}$) and critical strain energy release rate ($G_{IC}$). From the results, it was found that the fracture toughness properties of MWCNTs/Ni-PFs/epoxy were enhanced with increasing MWCNTs content, whereas the value decreased above 5 wt.%. MWCNTs content. This was probably considered that the MWCNTs entangled with each other in epoxy due to an excess of MWCNTs.

무기충전재가 PAN의 수화용융특성에 미치는 영향에 관한 연구(I) -PAN 수화응용체의 유변학적 특성- (Effect of Inorganic Fillers on the Properties of Hydrated PAN Melt(I) -Rheological Properties of Hydrated PAN Melt-)

  • 민병길;손태원
    • 한국염색가공학회지
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    • 제12권5호
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    • pp.295-300
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    • 2000
  • The melting behavior of hydrated polyacrylonitrile (PAN) and the rheological properties of hydrated PAN melt were investigated using DSC md modified capillary rheometer. With increasing the water content, Tm of the hydrated PAN was rapidly decreased and finally levelled off above a critical water content. However, the melt viscosity was further decreased even above the critical water content. The hydrated PAN melt showed a typical shear thinning behavior. In arrhenius plot, when the hydrated PAN melt was supercooled, it exhibited a different dependency on temperature from that above melting temperature.

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Studies on Cure Behaviors, Dielectric Characteristics and Mechanical Properties of DGEBA/Poly(ethylene terephthalate) Blends

  • Park, Soo-Jin
    • Macromolecular Research
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    • 제17권8호
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    • pp.585-590
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    • 2009
  • The cure behaviors, dielectric characteristics and fracture toughness of diglycidylether of bisphenol-A (DGEBA)/poly(ethylene terephthalate) (PET) blend system were investigated. The degree of conversion for the DGEBA/PET blend system was measured using Fourier transform infrared (FTIR) spectroscopy. The cure kinetics were investigated by measuring the cure activation energies ($E_a$) with dynamic differential scanning calorimetry (DSC). The dielectric characteristic was examined by dielectric analysis (DEA). The mechanical properties were investigated by measuring the critical stress intensity factor ($K_{IC}$), critical strain energy release rate ($G_{IC}$), and impact strength test. As a result, DGEBAIPET was successfully blended. The Ea of the blend system was increased with increasing PET content to a maximum at 10 phr PET. The dielectric constant was decreased with increasing PET content. The mechanical properties of the blend system were also superior to those of the neat DGEBA. These results were attributed to the increased cross-linking density of the blend system, resulting from the interaction between the epoxy group of DGEBA and the carboxyl group of PET.

Bending, buckling, and free vibration analyses of carbon nanotube reinforced composite beams and experimental tensile test to obtain the mechanical properties of nanocomposite

  • Mohammadimehr, M.;Mohammadi-Dehabadi, A.A.;Akhavan Alavi, S.M.;Alambeigi, K.;Bamdad, M.;Yazdani, R.;Hanifehlou, S.
    • Steel and Composite Structures
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    • 제29권3호
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    • pp.405-422
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    • 2018
  • In this research, experimental tensile test and manufacturing of carbon nanotube reinforced composite beam (CNTRC) is presented. Also, bending, buckling, and vibration analysis of CNTRC based on various beam theories such as Euler-Bernoulli, Timoshenko and Reddy beams are considered. At first, the experimental tensile tests are carried out for CNTRC and composite beams in order to obtain mechanical properties and then using Hamilton's principle the governing equations of motion are derived for Euler Bernoulli, Timoshenko and Reddy theories. The results have a good agreement with the obtained results by similar researches and it is shown that adding just two percent of carbon nanotubes increases dimensionless fundamental frequency and critical buckling load as well as decreases transverse deflection of composite beams. Also, the influences of different manufacturing processes such as hand layup and industrial methods using vacuum pump on composite properties are investigated. In these composite beams, glass fibers used in an epoxy matrix and for producing CNTRC, CNTs are applied as reinforcement particles. Applying two percent of CNTs leads to increase the mechanical properties and increases natural frequencies and critical buckling load and decreases deflection. The obtained natural frequencies and critical buckling load by theoretical method are higher than other methods, because there are some inevitable errors in industrial and hand layup method. Also, the minimum deflection occurs for theoretical methods, in bending analysis. In this study, Young's and shear modulli as well as density are obtained by experimental test and have not been used from the results of other researches. Then the theoretical analysis such as bending, buckling and vibration are considered by using the obtained mechanical properties of this research.

A simplified approach for fire-resistance design of steel-concrete composite beams

  • Li, Guo-Qiang;Wang, Wei-Yong
    • Steel and Composite Structures
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    • 제14권3호
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    • pp.295-312
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    • 2013
  • In this paper, a simplified approach based on critical temperature for fire resistance design of steel-concrete composite beams is proposed. The method for determining the critical temperature and fire protection of the composite beams is developed on the basis of load-bearing limit state method employed in current Chinese Technical Code for Fire safety of Steel Structure in Buildings. Parameters affecting the critical temperature of the composite beams are analysed. The results show that at a definite load level, section shape of steel beams, material properties, effective width of concrete slab and concrete property model have little influence on the critical temperature of composite beams. However, the fire duration and depth of concrete slab have significant influence on the critical temperature. The critical temperatures for commonly used composite beams, at various depth of concrete and fire duration, are given to provide a reference for engineers. The validity of the practical approach for predicting the critical temperature of the composite beams is conducted by comparing the prediction of a composite beam with the results from some fire design codes and full scale fire resistance tests on the composite beam.

수평 직사각 덕트 내 임계점 부근 물의 대류열전달 특성 (Convective Heat Transfer to Water near the Critical Region in Horizontal Rectangular Ducts)

  • 이상호
    • 대한기계학회논문집B
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    • 제36권5호
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    • pp.477-485
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    • 2012
  • 수평 덕트 내 임계점부근의 유체 유동 및 열전달특성은 중력과 함께 임계영역에서의 열역학 및 전달 물성치의 많은 변화와 직접적으로 연관되어 있다. 본 연구에서는 수평 직사각 덕트 내 임계점부근의 물에 대한 대류열전달특성을 전산해석을 통하여 분석하였다. 이를 통해 국부적인 열전달계수와 유속, 온도, 그리고 물성치분포를 포함한 대류열전달특성에 대해 임계점 근접효과와 함께 비교하였다. 벽으로부터의 열전달에 따른 유체 밀도감소로 덕트 내 유동방향으로의 유속증가와 함께 유체가 액체에서 기체 같은 상태로 천이하는 형태의 유동장특성을 보여준다. 덕트의 윗면, 옆면, 그리고 아래면 각각의 국부적인 열전달계수분포에 큰 차이가 있으며 준임계점 온도부근에서 난류전달특성의 향상으로 열전달계수의 최대치에 이르게 된다. Nu 수는 덕트 내 압력과 종횡비에 영향을 받으며 임계압에 가까워질수록 최대 Nu 수는 급격히 증가하게 된다. 이와 함께 기존의 열전달상관식을 통한 결과와 예측된 Nu 수 분포를 비교하였다.

TFA-MOD법을 이용한 YBCO 박막의 열처리 온도와 두께의 영향 (Effects of the Heat Treatment Temperature and Thickness of YBCO Film Fabricated by TFA-MOD Method)

  • 장석헌;임준형;이진성;윤경민;김규태;주진호;김찬중;나완수
    • 한국전기전자재료학회논문지
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    • 제19권5호
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    • pp.467-476
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    • 2006
  • We fabricated the YBCO films on LAO substrate using the TFA-MOD method and evaluated the effects of heat treatment temperature and film thickness on the microstructure, degree of texture, and critical properties. The calcining and firing were peformed at the temperature range of $370^{\circ}C-460^{\circ}C\;and\;750^{\circ}C-800^{\circ}C$, respectively. For the films fired at $775^{\circ}C$ after calcining at $400^{\circ}C-430^{\circ}C$showed highest critical temperature (Tc-onset) of 89.5 K and critical current (Ic) of 40A/cm-width which corresponds to critical current density (Jc) of $1.8MA/cm^2$. The highest critical properties are probably attributed to the formation of purer YBCO phase, stronger biaxial texture, and higher oxygen content, according to the XRD, pole-figure, SEM, Raman analysis. From the multi-coated films, the Ic increased from 39 to 169 A/cm-width as the coating repeated to four times, while the corresponding Jc was measured from once to be in the range of $0.8-1.2MA/cm^2$. Both Ic and Jc degraded as the coating repeated further, indicating that the optimum thickness is in the range of $1.0{\mu}m-1.7{\mu}m$.

Kevlar-29 섬유강화 복합재료의 기계적 계면 특성 연구 (Studies on Mechanical Interfacial Properties of Kevlar-29 Fibers Reinforced Composites)

  • Park, Soo-Jin;Seo, Min-Kang;Ma, Tae-Jun;Lee, Jae-Rock
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2001년도 추계학술발표대회 논문집
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    • pp.158-162
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    • 2001
  • The effects of chemical treatment on Kevlar-29 fibers have been studied in a composite system. The surface characteristics of the Kevlar-29 fibers were characterized by pH, acid-base value and X-ray photoelectron spectroscopy (XPS). The mechanical interfacial properties of final composites were studied by interlaminar shear strength (ILSS) and critical stress intensity factor ($K_{IC}$). Also, the impact properties of the composites were investigated in the differentiating studies between initiation and propagation energies, and ductile index (DI) along with maximum farce and total energy. It was found that the chemical treatment with phosphoric acid ($H_3PO_4$) solution significantly affected the degree of adhesion at interfaces between fibers and resin matrix, resulting in improving the mechanical interfacial strength of the composites. This was probably due to the presence of chemical polar groups on Kevlar surfaces, leading to an increment of interfacial binding force in a composite system.

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