Effect of Inorganic Fillers on the Properties of Hydrated PAN Melt(I) -Rheological Properties of Hydrated PAN Melt-

무기충전재가 PAN의 수화용융특성에 미치는 영향에 관한 연구(I) -PAN 수화응용체의 유변학적 특성-

  • 민병길 (금오공과대학교 신소재시스템공학부 섬유패션공학전공) ;
  • 손태원 (영남대학교 섬유패션학부)
  • Published : 2000.10.01

Abstract

The melting behavior of hydrated polyacrylonitrile (PAN) and the rheological properties of hydrated PAN melt were investigated using DSC md modified capillary rheometer. With increasing the water content, Tm of the hydrated PAN was rapidly decreased and finally levelled off above a critical water content. However, the melt viscosity was further decreased even above the critical water content. The hydrated PAN melt showed a typical shear thinning behavior. In arrhenius plot, when the hydrated PAN melt was supercooled, it exhibited a different dependency on temperature from that above melting temperature.

Keywords

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