• 제목/요약/키워드: Critical properties

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가열냉각 온도에 따른 $MgB_2$ 박막의 특성변화 (Effects of the post-annealing temperature on the properties of $MgB_2$ thin films ­)

  • 김형진;강원남;최은미;이성익
    • Progress in Superconductivity
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    • 제3권1호
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    • pp.45-48
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    • 2001
  • We have fabricated $MgB_2$thin films on (1 1 02)$ A1_2$$O_3$substrates by using a two-step method. Amorphous B thin films were deposited by a pulsed laser deposition technique and sintered in Mg vapor at various temperatures from 800 to $950^{\circ}C$. Superconducting properties of the thin films were investigated by temperature dependences of magnetization and critical current density. Structural studies were carried out by an x-ray diffraction and a scanning electron microscope. The films fabricated at $900^{\circ}C$ showed the highest transition temperature of 39 K and critical current density of ~$10^{7}$ A/$\textrm{cm}^2$ at 15 K.

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반응 표면 분석에 의한 생강 분말을 첨가한 쌀 압출 성형물의 이화학적 성질 (Physicochemical Properties of Rice Extrudate with Added Ginger Powder by the Response Surface Regression Analysis)

  • 고광진
    • 한국식품영양학회지
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    • 제6권3호
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    • pp.178-188
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    • 1993
  • This research was attempted to investigate changes in physicochemical properties of rice extrudate with added ginger powder extruded by single screw extruder. Graphic three dimensional analysis on response surface regression was used to evaluate effects of extrusion variables on quality factors of the extrudate according to two independent variables, ginger consent 0∼12%, moisture content 14∼26%. The summarized results are as follows : 1) Regarding proximate composition of rice extrudate with added ginger powder, as ginger powder content of raw material Increased, crude tat, crude protein, crude ash and crude fiber increased, while soluble nitrogen free extract decreased. 2) Graphic three dimensional analysis on response surface regression was conducted for each dependent variable which revealed statistically significant relationship with independent variables, 0∼120A ginger and 14∼26% moisture content. Expansion ratio had a critical point as moisture content changed. As ginger and moisture content Increased, bulk density, break strength and water absorption Index Increased, while water solubility Index decreased. The predicted maximum degree of gelatinization in 6.15% ginger and 15.56% moisture content is 88.27%, and lightness decreased as ginger content Increased. According to the microstructure for the cross section of extrudate obsorbed with image analyzer, air cell number and perimeter revealed saddle point, meanwhile total area and fractarea of air cell had critical points as moisture content changed. In view of the results, quality of rice extrudate with added ginger powder was optimum when rice flour was fed to the extruder with 2∼7% singer powder and 15∼20% moisture content.

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사파이어 기판 위에 펄스-증착법으로 성장한 YBCO/CeO2박막의 초전도성과 표면 모폴러지 (Superconductivity and Surface Morphology of YBCO/CeO$_2$ Thin Films on Sapphire Substrate by Pulsed Laser Deposition)

  • Kang, Kwang-Yong;J. D. Suh
    • 한국초전도저온공학회:학술대회논문집
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    • 한국초전도저온공학회 2003년도 학술대회 논문집
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    • pp.88-91
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    • 2003
  • The crystal structure and properties of YBa$_2$Cu$_3$$O_{7-x}$(YBCO) and CeO$_2$ thin films deposited on r-plane (1(equation omitted)02) sapphire substrate by pulsed- laser deposition(PLD) have been investigated. C-axis oriented epitaxial YBCO thin films with critical temperature (Tc) of 88 K were routinely grown on (200) oriented CeO$_2$ buffer layers with thickness in the range between 20 to 80 nm. When the thickness of the (200)oriented CeO$_2$ buffer layer increases over than 80 nm, the superconducting properties of YBCO thin films on that were deteriorated. The decrease in Tc of YBCO thin films was explained by the microcrack formation in CeO$_2$ buffer layer. These results indicate that the thickness of the (200) oriented CeO$_2$ buffer layer is critical to the epitaxial YBCO thin nim growth on r-plane (1(equation omitted)02) sapphire substrate.e.

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Effects of α-particle beam irradiation on superconducting properties of thin film MgB2 superconductors

  • Kim, Sangbum;Duong, Pham van;Ha, Donghyup;Oh, Young-Hoon;Kang, Won Nam;Hong, Seung Pyo;Kim, Ranyoung;Chai, Jong Seo
    • 한국초전도ㆍ저온공학회논문지
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    • 제18권2호
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    • pp.8-13
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    • 2016
  • Superconducting properties of thin film MgB2 superconductors irradiated with 45 MeV ${\alpha}$-particle beam were studied. After the irradiation, enhancement of the critical current density and pinning force was observed, scaling close to strong pinning formula. Double logarithmic plots of the maximum pinning force density with irreversible magnetic field show a power law behavior close to carbon-doped MgB2 film or polycrystals. Variation of normalized pinning force density in the reduced magnetic field suggests scaling formulas for strong pinning mechanism like planar defects. We also observed a rapid decay of critical current density as the vortex lattice constant decreases, due to the strong interaction between vortices and increasing magnetic field.

STUDIES ON THE POLY(4,4-TEREPHTHANILIDEALKYLAMIDE)S (II) Rheological properties and Fibre Performance

  • Seung Sang Hwang;Byo
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 1987년도 학술발표초록집
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    • pp.11-11
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    • 1987
  • Among other poly(4,4'-terephthanilidealkylamide)s (PTAA's), poly (4,4'-terephthanilideadipamide) (PTAd) gave clear critical concentration curves. For PTAA's with methylene units more than 6, the critical concentration (C*) seemed to be beyond the solubility limit of H₂SO₄. Under shearing conditions, the nematic domains were easily oriented and stretched in the direction of shear , and a fibrillar structure resulted. At low frequencies, a monotollous reduction of loss tangent (tan) was observed as concentration increased. At high frequencies, however, tan was increased above C* again, and showed maximum at saturation concentration (Cs). With increasing temperature, viscosity of isotropic and anisotropic phases was normally decreased, while viscosity of biphases was increased. Plot of complex viscosity (If) against temperature based on rheological measurements exhibited a good correlation with phase diagram constructed by polarizing microscope observations. Rheological parameters suggested the optimum dope concentration of PTAd with inherent viscosity 2.02 at 30oc is in the vicinity of 19.2 wt%, which seemed to agree well with spinning experiments (around 19.4 wt%). In general, effects of spinning and annealing conditions on the mechanical properties of PTAA fibres were most pronounced in PTAd fibre spun from anisotropic spinning dope .

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Morphology and Charge Transport Properties of Chemically Synthesized Polyaniline-poly(ε-caprolactone) Polymer Films

  • Basavaraja, C.;Kim, Dae-Gun;Kim, Won-Jeong;Kim, Ji-Hyun;Huh, Do-Sung
    • Bulletin of the Korean Chemical Society
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    • 제32권3호
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    • pp.927-933
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    • 2011
  • Conducting polyaniline-poly($\varepsilon$-caprolactone) polymer composites were synthesized via in situ deposition techniques. By dissolving different weight percentages of poly($\varepsilon$-caprolactone) (PCL) (10%, 20%, 30%, 40%, and 50%), the oxidative polymerization of aniline was achieved using ammonium persulfate as an oxidant. FTIR, UV-vis spectra, and X-ray diffraction studies support a strong interaction between polyaniline (PANI) and PCL. Structural morphology of the PANI-PCL polymer composites was studied using scanned electron microscopy (SEM) and transmittance electron microscopy (TEM), and thermal stability was analyzed by thermogravimetric analysis (TGA) technique. The temperature-dependent DC conductivity of PANI-PCL polymer composite films was studied in the range of 305-475 K, which revealed a semiconducting behavior in the transport properties of the polymer films. Conductivity increased with the increase of PCL in below critical level, however conductivity of the polymer film was decreased with increase of PCL concentration higher than the critical value.

Thermal buckling analysis of functionally graded carbon nanotube-reinforced composite sandwich beams

  • Ebrahimi, Farzad;Farazmandnia, Navid
    • Steel and Composite Structures
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    • 제27권2호
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    • pp.149-159
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    • 2018
  • Thermo-mechanical buckling of sandwich beams with a stiff core and face sheets made of functionally graded carbon nanotube-reinforced composite (FG-CNTRC) within the framework of Timoshenko beam theory is presented. The material properties of FG-CNTRC are supposed to vary continuously in the thickness direction and are estimated through the rule of mixture. Also the properties of these materials should be considered temperature dependent. The governing equations and boundary conditions are derived by using Hamilton's principle and solved using an efficient technique called the Differential Transform Method (DTM) to achieve the critical buckling of the sandwich beam in uniform thermal environment. A detailed parametric study is guided to investigate the effects of carbon nanotube volume fraction, slenderness ratio, core-to-face sheet thickness ratio, and clamped-clamped, simply-simply and clamped-simply end supports on the critical buckling behavior of sandwich beams with FG-CNTRC face sheets. Numerical results for comparison of sandwich beams with uniformly distributed carbon nanotube-reinforced composite (UD-CNTRC) face sheets with those with FG-CNTRC face sheets are also presented.

직접수치모사를 이용한 수직원형관내 초임계압 유체의 난류 열전달 특성 연구 (Direct Numerical Simulation of Turbulent Heat Transfer to Fluids at Supercritical Pressure Flowing in Vertical Tubes)

  • 배중헌;유정열;최해천
    • 대한기계학회논문집B
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    • 제28권11호
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    • pp.1302-1314
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    • 2004
  • Turbulent heat transfer to $CO_2$ at supercritical pressure flowing in vertical tubes is investigated using direct numerical simulation (DNS). A conservative space-time discretization scheme for variable-density flows at low Mach numbers is adopted in the present study to treat steep variations of fluid properties at supercritical pressure just above the thermodynamic critical point. The fluid properties at these conditions are obtained using PROPATH and used in the form of tables in the simulations. The buoyancy influence induced by strong variation of density across the pseudo-critical temperature proved to play a major role in turbulent heat transfer at supercritical state. Depending on the degree of buoyancy influence, turbulent heat transfer may be enhanced or significantly deteriorated, resulting in local hot spots along the heated surface. Based on the results of the present DNS combined with theoretical considerations, the physical mechanism of this local heat transfer deterioration is elucidated.

Corrosion Properties of Duplex Stainless Steels - STS329LD and STS329J3L - for the Seawater Systems in Nuclear Power Plant

  • Chang, Hyun-Young;Park, Heung-Bae;Kim, Young-Sik;Ahn, Sang-Kon;Jang, Yoon-Young
    • Corrosion Science and Technology
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    • 제10권2호
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    • pp.60-64
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    • 2011
  • Lean duplex stainless steels have been developed in Korea for the purpose of being used in the seawater systems of industry. There are also many important seawater systems in nuclear power plants. These systems supply seawater to cooling water condenser tubes, heat exchanger tubes, related pipes and chlorine injection systems. The flow velocity of some part of seawater systems in nuclear power plants is high and damages of components from corrosion are severe. The considered lean duplex stainless steels are STS329LD (20.3Cr-2.2Ni-1.4Mo) and STS329J3L (22.4Cr-5.7Ni-3Mo) and PRENs of them are 29.4 and 37.3 respectively. Physical, mechanical and micro-structural properties of them are evaluated, and electrochemical corrosion resistance is measured quantitatively in NaCl solution. Critical Pitting Temperatures (CPT)s are measured on these alloys and pit depths are evaluated using laser microscope. Long period field tests on these alloys are now being performed, and some results are going to be presented in the following study.

Collective effect of hydrogen in argon and Mg as ambiance for the heat treatment on MgB2

  • Sinha, B.B.;Jang, S.H.;Chung, K.C.
    • 한국초전도ㆍ저온공학회논문지
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    • 제16권2호
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    • pp.24-28
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    • 2014
  • Magnesium diboride superconductor is still of considerable interest because of its appealing characteristics towards application mainly at around 20 K. Unlike Nb-based superconductors, $MgB_2$ can be operated by cryogen-free cooler which provides a cost effective alternative at low field of around 2-5 T. To explore this operating field region considerable efforts are necessary to marginally improve the superconducting properties of $MgB_2$. Under this situation, even the heat treatment environment during the synthesis is considered as an important factor. The addition of $H_2$ gas in small amount with Ar as a mixed gas during annealing has an adverse effect on the superconducting properties of $MgB_2$. It is although interesting to find that the presence of Mg vapor along with hydrogen during heat treatment results in the appreciable improvement in the flux pinning and the overall response of the critical current density for the ex-situ $MgB_2$ samples.