• Title/Summary/Keyword: Cr-activator

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Luminescence Characteristics of ZnGa2O4:Mn2+,Cr3+ Phosphor and Thick Film

  • Cha, Jae-Hyeok;Choi, Hyung-Wook
    • Transactions on Electrical and Electronic Materials
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    • v.12 no.1
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    • pp.11-15
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    • 2011
  • In this study, $ZnGa_2O_4$ phosphors in its application to field emission displays and electroluminescence were synthesized through the precipitation method and $Mn^{2+}$ ions. A green luminescence activator, $Cr^{3+}$ ions, and a red luminescence activator were separately doped into $ZnGa_2O_4$, which was then screen printed to an indium tin oxide substrate. The thick films of the $ZnGa_2O_4$ were deposited with the various thicknesses using nano-sized powder. The best luminescence characteristics were shown at a thickness of 60 ${\mu}m$. Additionally, green-emission $ZnGa_2O_4:Mn^{2+}$ and red-emission $ZnGa_2O_4:Cr^{3+}$ phosphor thick films, which have superior characteristics, were manufactured through the screen-printing method. These results indicate that $ZnGa_2O_4$ phosphors prepared through the precipitation method have wide application as phosphor of the full color emission.

Photoluminescence of Al2O3:xCr2O3 Solid Solution and Application as the Additive for Improving CRI of Red Phosphor (Al2O3:xCr2O3 고용상의 발광특성과 적색형광체의 연색성 향상을 위한 첨가제로의 응용)

  • Chae, Ki-Woong;Cheon, Chae-Il;Kim, Jeong-Seog
    • Journal of the Korean Ceramic Society
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    • v.47 no.2
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    • pp.122-126
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    • 2010
  • In this article photoluminescence of the $Al_2O_3:xCr_2O_3$ solid solutions prepared by solid state reaction method are represented. The effect of $Cr_2O_3$-activator concentration and heat treatment time on the PL characteristics have been discussed in conjunction with microstructure of phosphor samples. The $Al_2O_3:xCr_2O_3$ phosphors show the highest PL intensity at x=0.003 mole when the samples are reacted at $1600^{\circ}C$ for 5 h. The PL emission and absorption spectra show the maximum peaks at 698 nm and at 398 nm respectively. The CIE color coordinate is (x=0.646, y=0.316) at 0.003 mole $Cr_2O_3$, which value is very close to the NTSC coordinate of red color. This characteristic feature of $Al_2O_3:xCr_2O_3$ has been applied for an additive to improve the color characteristic of other red phosphor $LiEuW_2O_8$ which has a relatively poor color purity with an emission peak centered at 615 nm and with a CIE coordinate (x=0.530, y=0.280). The $Al_2O_3:0.003Cr_2O_3$ phosphor has been mixed with the $LiEuW_2O_8$ phosphor powder and the PL characteristics and CIE color coordinates are characterized. The $Al_2O_3:xCr_2O_3$ phosphor was found effective for improving the CRI (color rendering index) of $LiEuW_2O_8$ phosphor.

Thermodynamics of Simultaneous Chromizing and Aluminizing of the Mild Steel (연강에 Cr과 Al의 동시 확산 침투 피복의 열역학적 연구)

  • 김선규;신원순
    • Journal of the Korean institute of surface engineering
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    • v.25 no.4
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    • pp.161-164
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    • 1992
  • Thermodynamic calculations were made to find an optimum condition of simultaneous chromizing and aluminizing of mild steel. Results of calculations showed that Cr-Al alloy powder should be used and the optimum composition was 90~95wt% Cr and 5~10wt% Al. Simultaneous chromizing and aluminizing of a mild steel was achieved using 95Cr-5Al wt% alloy powders as a masteralloy, NH4Cl as an activator at $1273^{\circ}$K under Ar atmosphere.

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Photoluminescence Characteristics of ZnGa2O4 Nano-phosphors by Combustion Method (연소합성법으로 제작한 ZnGa2O4 나노형광체의 광학적 특성)

  • Kim, Se-Jun;Choi, Hyung-Wook
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.1
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    • pp.14-17
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    • 2010
  • $ZnGa_2O_4$ powder were prepared by combustion method and $Mn^{2+}$ ions, a green luminescence activator, and $Cr^{3+}$ ions, a red luminescence activator were separately doped into $ZnGa_2O_4$. The characteristics of the synthesized nano powder were investigated by means of X-ray diffraction (XRD), Scanning Electron Microscope (SEM), and photoluminescence (PL). The various $ZnGa_2O_4$ peaks, with the (311) main peak, appeared at all sintering temperature XRD patterns. The PL specctrums of $ZnGa_2O_4$ powder showed main peak of 425 nm, and maximum intensity at the sintering temperature of $1200^{\circ}C$. SEM images shown that nano sized particles(about 200 nm) were of spherical shape. The characteristics of $ZnGa_2O_4$ containing 0.004 mol $Mn^{2+}$(505 nm, green) and $ZnGa_2O_4$ containg 0.002 mol $Cr^{3+}$ (696 nm, red) were shown to be the best.

Protein Kinase CK2 Is Upregulated by Calorie Restriction and Induces Autophagy

  • Park, Jeong-Woo;Jeong, Jihyeon;Bae, Young-Seuk
    • Molecules and Cells
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    • v.45 no.3
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    • pp.112-121
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    • 2022
  • Calorie restriction (CR) and the activation of autophagy extend healthspan by delaying the onset of age-associated diseases in most living organisms. Because protein kinase CK2 (CK2) downregulation induces cellular senescence and nematode aging, we investigated CK2's role in CR and autophagy. This study indicated that CR upregulated CK2's expression, thereby causing SIRT1 and AMP-activated protein kinase (AMPK) activation. CK2α overexpression, including antisense inhibitors of miR-186, miR-216b, miR-337-3p, and miR-760, stimulated autophagy initiation and nucleation markers (increase in ATG5, ATG7, LC3BII, beclin-1, and Ulk1, and decrease in SQSTM1/p62). The SIRT1 deacetylase, AKT, mammalian target of rapamycin (mTOR), AMPK, and forkhead homeobox type O (FoxO) 3a were involved in CK2-mediated autophagy. The treatment with the AKT inhibitor triciribine, the AMPK activator AICAR, or the SIRT1 activator resveratrol rescued a reduction in the expression of lgg-1 (the Caenorhabditis elegans ortholog of LC3B), bec1 (the C. elegans ortholog of beclin-1), and unc-51 (the C. elegans ortholog of Ulk1), mediated by kin-10 (the C. elegans ortholog of CK2β) knockdown in nematodes. Thus, this study indicated that CK2 acted as a positive regulator in CR and autophagy, thereby suggesting that these four miRs' antisense inhibitors can be used as CR mimetics or autophagy inducers.

Nanofiller as Crosslinker for Halogen-Containing Elastomers

  • Sahoo, N.G.;Kumar, E.Shiva;Das, C.K.;Panda, A.B.;Pramanik, P.
    • Macromolecular Research
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    • v.11 no.6
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    • pp.506-510
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    • 2003
  • A Zn ion-coated nanosilica filler has been developed and tested, in chlorosulfonated polyethylene (CSPE) and polychloroprene (CR), as a vulcanizing activator, cum was reinforcing filler. In this study, ZnO was replaced by the Zn ion-coated nanosilica filler with an aim of studying the dual role of this nanofiller in CSPE and CR. In the case of CSPE vulcanizates, the presence of MgO deteriorated the state and rate of cure when the Zn ion-coated nanosilica filler was used, but in the case of CR it improved the state of cure and enhanced the modulus and tensile strength. The Zn ion-coated filler proved to be a better reinforcing-cum-curing agent than was externally added ZnO and NA-22 also proved to be a better curative in the presence of the Zn ion-coated nanosilica filler for both CSPE and CR.

A Study on the Stabilization/ Solidification Process Using Blast Furnace Slag (슬래그를 이용한 중금속 이온의 고정화)

  • 강성근;방완근;이승헌;김창은
    • Journal of the Korean Ceramic Society
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    • v.36 no.7
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    • pp.725-733
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    • 1999
  • It is a fundamental experiment to use blast-furnace slag in solidification/stabilization process. The compressive strength and leaching test of Pb and Cr doped samples were evaluated and the effects of heavy-metal ions on the hydration of slag was investigated. Sodium silicates(5wt%) was added as alkali-activator and the effects of replacing a part of slag with flyash or gypsum was also discussed. Pb ion was solidified by encapsulation of matrix. In of slag${\pm}$gypsum binder microstructure was densified by accelerating to form AFt/AFm phase and compressive strength was improved resulting in reducing leaching amount of Pb ion. Cr ion was solidified by substituting with Al ion in aluminate product. Slag+fly ash binder improved compressive strength and decreased leaching amount of Cr ion.

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Cathode Luminescence Characteristics of $ZnGa_2O_4$ Phosphors with the doped activator (활성제 첨가에 따른 $ZnGa_2O_4$ 형광체의 발광특성)

  • Hong, Beom-Joo;Lee, Seung-Kyu;Kim, Kyung-Hwan;Park, Yong-Seo;Choi, Hyung-Wook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.301-302
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    • 2005
  • The $ZnGa_2O_4$:Cr phosphor was synthesized through solid-state reactions at the various molar ratio of Cr from 0.002 % to 0.01 %. The XRD patterns show that the Cr-doped $ZnGa_2O_4$ has a (311) main peak and a spinel phase. Also the emission wavelength shills from 510 to 705 nm in comparison with $ZnGa_2O_4$:Mn when Cr is doped in $ZnGa_2O_4$. These results indicate that $ZnGa_2O_4$ phosphors hold promise for potential applications in field-emission display devices with high brightness operating in full color regions.

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