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Photoluminescence Characteristics of ZnGa2O4 Nano-phosphors by Combustion Method

연소합성법으로 제작한 ZnGa2O4 나노형광체의 광학적 특성

  • 김세준 (경원대학교 전기공학과) ;
  • 최형욱 (경원대학교 전기공학과)
  • Published : 2010.01.01

Abstract

$ZnGa_2O_4$ powder were prepared by combustion method and $Mn^{2+}$ ions, a green luminescence activator, and $Cr^{3+}$ ions, a red luminescence activator were separately doped into $ZnGa_2O_4$. The characteristics of the synthesized nano powder were investigated by means of X-ray diffraction (XRD), Scanning Electron Microscope (SEM), and photoluminescence (PL). The various $ZnGa_2O_4$ peaks, with the (311) main peak, appeared at all sintering temperature XRD patterns. The PL specctrums of $ZnGa_2O_4$ powder showed main peak of 425 nm, and maximum intensity at the sintering temperature of $1200^{\circ}C$. SEM images shown that nano sized particles(about 200 nm) were of spherical shape. The characteristics of $ZnGa_2O_4$ containing 0.004 mol $Mn^{2+}$(505 nm, green) and $ZnGa_2O_4$ containg 0.002 mol $Cr^{3+}$ (696 nm, red) were shown to be the best.

Keywords

References

  1. C. H. Lu, B. Bhattacharjee, and S. Y. Chen, “Microwave synthesis of manganese-ion-doped zinc sulfide nano-phosphors using a novel monomer”, J. Alloys Compd., Vol. 475, Issue 1-2, p. 121, 2009.
  2. J. S. Kim, J. S. Kim, and H. L. Park, “Optical and structural properties of nanosized $ZnGa_2O_4:Cr^{3+}$ phosphor”, Solid State Commun., Vol. 131, p. 735, 2004. https://doi.org/10.1016/j.ssc.2004.07.026
  3. S. K. Lee, Y. S. Park, and H. W. Choi, "Luminescence characteristics of $ZnGa_2O_4$ phosphor thick films prepared by screen printing method", J. of KIEEME(in Korean), Vol. 19, No. 8, p. 749, 2006. https://doi.org/10.4313/JKEM.2006.19.8.749
  4. J. H. Cha, K. H. Kim, Y. S. Park, S. J. Kwon, and H. W. Choi, "Luminescence characteristics of $ZnGa_2O_4$ thick film doped with $Mn^{2+}$ and $Cr^{3+}$ at various sintering temperatures", Jpn. J. Appl. Phys., Vol. 46, 6702, 2007. https://doi.org/10.1143/JJAP.46.6702
  5. J. H. Lee, H. J. Park, K. Yoo, and B. W. Kim, “Characteristics of nano-sized $ZnGa_2O_4$ phosphor prepared by solution combustion method and solid state reaction method”, J. Eur. Ceram. Soc., Vol. 27, p. 965, 2007. https://doi.org/10.1016/j.jeurceramsoc.2006.04.153
  6. T. Ohtake, N. Sonoyama, and T. Sakata, "Photoluminescence dependence on imposing bias for $ZnGa_2O_4$ and $ZnGa_2O_4$ activated with $Mn^{2+}$ or $Cr^{3+}$ n-type semiconductor electrodes", Electrochemistry communications, Vol. 7, p. 1389, 2005. https://doi.org/10.1016/j.elecom.2005.09.024