• Corrosion Science and Technology
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• 제9권5호
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• pp.187-195
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• 2010

Hyper duplex stainless steels have been developed in Korea for the purpose of application to the seawater system of Korean nuclear power plants. This system supplies seawater to cooling water heat exchanger tubes, related pipes and chlorine injection system. In normal operation, seawater is supplied to heat exchanger through the exit of circulating water pump headers, and the heat exchanged sea water is extracted to the discharge pipes in circulating water system connected to the circulating water discharge lines. The high flow velocity of some part of seawater system in nuclear power plants accelerates damages of components. Therefore, high strength and high corrosion resistant steels need to be applied for this environment. Hyper duplex stainless steel (27Cr-7.0Ni-2.5Mo-3.2W-0.35N) has been newly developed in Korea and is being improved for applying to nuclear power plants. In this study, the physical & mechanical properties and corrosion resistance of newly developed materials are quantitatively evaluated in comparative to commercial stainless steels in other countries. The properties of weld & HAZ (heat affected zone) are analyzed and the best compositions are suggested. The optimum conditions in welding process are derived for ensuring the volume fraction of ferrite(${\alpha}$) and austenite(${\gamma}$) in HAZ and controlling weld cracks. For applying these materials to the seawater heat exchanger, CCT and CPT in weldments are measured. As a result of all experiments, it was found that the newly developed hyper duplex stainless steel WREMBA has higher corrosion resistance and mechanical properties than those of super austenitic stainless steels including welded area. It is expected to be a promising material for seawater systems of Korean nuclear power plants.

• 한국산업보건학회지
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• 제9권1호
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• pp.56-72
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• 1999

Airborne concentrations of welding fumes in which 13 different metals such as Al, Cd, Cr, Cu, Fe, Mn, Mo, Ni, Pb, Si, Sn, Ti, and Zn were analyzed were measured at 18 factories including automobile assembly and manufactures, steel heavy industries and shipyards. Air samples were collected by personal sampler at each worker's worksite(n=339). Blood levels of Cd, Cu, Fe, Mn, Pb and Zn were also measured from samples taken from 447 welders by atomic absorption spectrometry and compared with control values obtained from 127 non-exposed workers. The results were as follows ; 1. Among various welding types, $CO_2$ welding 70.2 % were widely used, shielded metal arc welding(SMAW) 22.1 % came next, and rest of them were metal inert gas(MIG) welding, submerged arc welding(SAW), spot welding(SPOT) and tungsten inert gas(TIG) welding. 2. Welding fume concentration was $0.92mg/m^3$($0.02{\sim}15.33mg/m^3$) at automobile assembly and manufactures, $4.10mg/m^3$($0.02{\sim}70.75mg/m^3$) at steel heavy industries and $5.59mg/m^3$($0.30{\sim}91.16mg/m^3$) at shipyards, respectively, showing significant difference among industry types. Workers exposed to high concentration of welding fumes above Korean Permissible Exposure Limit(KPEL) amounted to 7.9 % and 12.5 %, in $CO_2$ welding and in SMAW at automobile assembly and manufactures and 62.7 % in $CO_2$ welding, and 12.5 % in SMAW at shipyards, and 66.2 % in $CO_2$ welding and 70.6 % in SMAW at steel heavy industries. 3. Geometric mean of airborne concentration of each metal released from welding fumes was below one 10th of KPEL in all welding types. Percentage of workers, however, exposed to airborne concentration of metals above KPEL amounted to 16.8 % in Mn and 7.6 % in Fe in $CO_2$ welding; 37.5 % in Cu in SAW, 30 % in Cu in TIG; and 25 % in Pb in SPOT welding. As a whole, 76 Workers(22.4%) were exposed to high concentration of any of the metals above KPEL. 4. There were differences in airborne concentration of metals such as Al, Cd, Cr, Cu. Fe. Mn, Mo, Ni, Pb, Si, Sn, Ti and Zn by industry types. These concentrations were higher in shipyards and steel heavy industries than in automobile assembly and manufactures. Workers exposed to higher concentration of Pb above KPEI amounted to 7.4 % of workers(7/94) in automobile assembly and manufactures. In shipyards, 19.2 % of workers(19/99) were over-exposed to Mn and 7.1 % (7/99) to Fe above KPEL. In steel heavy industries, 14.4 %(21/146), 7.5 %(11/146) and 13 %(19/146) were over-exposed to Mn, Fe and Cu, respectively. As a whole, 76 out of 339 workers(22.4%) were exposed to any of the metals above KPEL. 5. Blood levels of Cd, Cu, Fe, Mn, Pb, and Zn in welders were $0.11{\mu}g/100m{\ell}$, $0.84{\mu}g/m{\ell}$, $424.4{\mu}g/m{\ell}$, $1.26{\mu}g/100m{\ell}$, $5.01{\mu}g/100m{\ell}$ and $5.68{\mu}g/m{\ell}$, respectively, in contrast to $0.09{\mu}g/100m{\ell}$, $0.70{\mu}g/m{\ell}$, $477.2{\mu}g/m{\ell}$, $0.73{\mu}g/100m{\ell}$, $3.14{\mu}g/100m{\ell}$ and $6.15{\mu}g/m{\ell}$ in non-exposed control groups, showing significantly higher values in welders but Fe and Zn.

• Tribology and Lubricants
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• 제33권1호
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• pp.15-22
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• 2017

Because the running speed of vehicles is increasing and a shorter braking distance is required, high heat-resistant brake pads are needed to satisfy the requirements of customers and car makers. In the near future, hazardous materials such as Cu, Cr, Zn, and Sb will be restricted from use in friction materials. Ceramic composites reinforced by carbon fibers are good candidates for eco-friendly friction materials. In this study, we develop ceramic composite friction materials. The friction materials are composed of carbon fibers, Si, SiC, graphite, and phenol resin and are prepared by hot forming and heat treatment at high temperatures. The density, void ratio, and compressive strength are $1.59-1.66g/cm^3$, 16.6-20, and 70-90 MPa, respectively. Friction and wear tests are performed using a pin-on-plate-type reciprocating friction tester at 25, 100, and $200^{\circ}C$. The counterpart material is a CrMoV steel extracted from a KTX brake disc. Friction coefficient, wear amount, and wear mechanism are measured and examined. We determine that the friction coefficients depend on the temperature and the fluctuation of the friction coefficients is larger at higher temperatures. The amount of wear increases with the surface temperatures of the specimens. The tribological properties of the developed composites are similar to those of a Cu-based sintered friction material. Through this study, it is confirmed that ceramic composite materials can be used as friction materials.

• Journal of Welding and Joining
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• 제10권3호
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• pp.63-72
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• 1992

The joining methods of ceramics to metals which can be expected to obtain high temperature strength are mainly classified into the solid-state diffusion bonding method and the active brazing method. Between these two, the solid-state diffusion bonding method is given attentions as substituting method for active brazing method due to being capable of obtaining higher bonding strength at high temperature and accurate bonding. In this paper, the solid-state diffusion bonding of $Al_{2}$O$_{3}$ ceramics to Ni-Cr-Mo alloy steel (SNCM21) using insert metal was carried out. The insert metal employed in this study was experimentally home-made, Ag-Cu-Ti alloy. Influence of several bonding parameters of $Al_{2}$O$_{3}$SNCM21 joint was quantitatively evaluated by bonding strength test, and microstructural analyses at the interlayer were performed by SEM/EDX. From above experiments, the optimum bonding condition of the solid-state diffusion bonding of $Al_{2}$O$_{3}$/SNCM21 using Ag-Cu-Ti insert metal was determined. Futhermore, high temperature strength and thermal-shock properties of $Al_{2}$O$_{3}$/SNCM21 joint were also examined. The results obtained are as follows. 1. The maximum bonding strength was obtained at the temperature of 95% melting point of insert metal. 2. The high temperature strength of $Al_{2}$O$_{3}$/SNCM21 joint appeared to bemaximum value at test temperature 500.deg.C and the bonding strength with increasingtemperature showed parabolic curve. 3. The strength of thermal-shocked specimens was far deteriorated than those of as-bonded specimens. Especially, water-quenched specimen after heated up to 600.deg. C was directly fractured in quenching.

• 대한기계학회논문집A
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• 제26권6호
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• pp.1069-1076
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• 2002

The high temperature creep behavior of heat machine systems such as aircraft engines, boilers and turbines in power plants and nuclear reactor components have been considered as an important and needful fact. There are considerable research results available for the design of high temperature tube materials in power plants. However, few studies on the Initial Strain Method (ISM) capable of securing repair, maintenance, cost loss and life loss have been made. In this method, 3 long time prediction Of high temperature creep characteristics can be dramatically induced through a short time experiment. The purpose of present study is to investigate the high temperature creep lift of Udimet 720, SCM 440-STD61 and 1Cr-0.5Mo steel using the ISM. The creep test was performed at 40$0^{\circ}C$ to $700^{\circ}C$ under a pure loading. In the prediction of creep life for each materials, the equation of ISM was superior of Larson-Miller Parameter(LMP). Especially, the long time prediction of creep life was identified to improve the reliability.

• 열처리공학회지
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• 제29권2호
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• pp.66-74
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• 2016

In this study, characteristics of TiAl alloy and SCM440 (Cr-Mo steel) have been investigated with the various joining condition by servo motor type friction welder. The experimental factors of friction welder used in this study are spindle revolution, friction speed, and distance, upset speed and distance, respectively. Servo motor type friction welder could be controlled by the level of oil pressure, and it could be performed by position control dependence of electrical energy. Mechanical properties and morphology of welded interface were characterized by various joining condition. This aroused due to the bond strength dependence on friction heat and size of the heat affected zone. Therefore, it is necessary to have enough friction heat and decreased heat affected zone for good friction welding between dissimilar metals. An optimum bond was obtained between TiAl alloy and SCM440 by controlling friction speed and distance. At the spindle revolution 4,000 rpm, friction speed 120 mm/min, friction distance 15 mm, the bond strength was found to be 312 MPa.

• 한국주조공학회지
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• 제18권6호
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• pp.563-569
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• 1998

A Study on microstructure and elevated temperature strength of 18Cr-2Mo ferritic stainless steel castings strengthened by alloying small amounts of titanium and carbon, has been conducted. The morphology of titanium carbides showed spherical in shape and their distribution depended on the amount of alloying elements. Maximum density ($7{\times}10^5/cm^2$) of titanium carbides has been formed in the alloy containing 2.0 wt.% titanium and 0.5 wt.% carbon as alloying elements and the size of carbide particles is in the range of 0.5 to $3.0\;{\mu}m$. High temperature tensile and fatigue strength of this alloy were the highest among the alloys tested in this research. The fracture mode of the alloys containing alloying elements less that 2.0 wt.% titanium and 0.5 wt.% carbon showed intercrystalline fracture at room temperature, while the alloys containing higher amounts of alloying elements showed transcrystalline fracture. All of the alloys showed creep or ductile rupture mode at elevated temperature.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2000년도 추계학술대회 논문집 학회본부 A
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• pp.265-268
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• 2000

In this study, a small punch creep (SP-Creep) test using miniaturized specimen has been described for the development of the new creep test method for high temperature structural components such as headers and tubes of boiler, turbine casing and rotor, and reactor vessel. The SP-Creep testing technique has been applied to 1Cr-0.5Mo steel used widely as boiler header material and the creep test temperature are varied at $550^{\circ}C{\sim}600^{\circ}C$. From the experimental results, e.g. SP-Creep curve behaviors, the creep rate in steady state and creep rupture life with test temperature and load, the load exponential value(n, m), the activation energy($Q_{spc}$), the Monkman-Grant relation and the creep life assessment equation etc., it can be summarized that the SP-Creep test may be a useful test method to evaluate the creep properties of the heat resisting material such as boiler header.

• 대한기계학회논문집A
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• 제23권7호
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• pp.1120-1128
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• 1999

An elastic-viscoplastic finite element analysis is performed to investigate detailed growth behavior of creep cracks and the numerical results are compared with experimental results. In Cr-Mo steel stress fields obtained from the crack growth method by mesh translation were compared with both cases that the secondary creep rate is only used as creep material property and the primary creep rate is included. Analytical stress fields, Riedel-Rice(RR) field, Hart-Hui-Riedel(HR) field and Prime(named in here) field, and the results obtained by numerical method were evaluated in details. Time vs. stress at crack tip was showed and crack tip stress fields were plotted. These results were compared with analytical stress fields. There is no difference of stress distribution at remote region between the case of 1st creep rate+2nd creep rate and the case of 2nd creep rate only. In case of slow velocity of crack growth, the effect of 1st creep rate is larger than the one of fast crack growth rate. Stress fields at crack tip region we, in order, Prime field, HR field and RR field from crack tip.

• 대한기계학회논문집
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• 제9권2호
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• pp.135-139
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• 1985

본 논문에서는 이러한 점을 감안하여 SCM4(KS규격)재에 대해서 Unloading Co- mpliance법 및 초음파법에 의한 크랙개시점검출을 시도한 결과로부터 파괴인성시험에 있어서 초음파법의 유요성을 밝히고저 한다.