• Title/Summary/Keyword: Cr layer

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Physical properties of PU coated fabric with collagen (콜라겐을 첨가한 폴리우레탄 코팅직물의 물성)

  • 백천의;유효선
    • Journal of the Korean Society of Clothing and Textiles
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    • v.23 no.6
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    • pp.800-808
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    • 1999
  • The demand for PU coated synthetic leather is increasing as a high fashion material. But it has some faults of water vapor permeability surface tacky property and static electricity. Therefore the purpose of this study was the produce of PU coated fabric added collagen with hydrophilic property and soft touch. In the PU coated fabric water vapor permeability water vaper absorption and frictional electronic voltage were investigated surface bending and compression properties were also examined by the use of KES-FB System. The followings were the results of this study. 1. There was no Cr in the collagen so that Cr was not treated in the collagen. 2. The surface and cross sectional layer of PU coated fabric with collagen were highly developed by micro porous structure. 3. The water vapor permeability of PU coated fabric was increased as collagen concentration increased. 4. The water vapor absorption of PU coated fabric was increased as collagen concentration increased. 5. The frictional electronic voltage of PU coated fabric was decreased in accordance with the increase of collagen concentration. Especially it effectively decreased by the use of only 5% collagen concentration. 6,. The bending and compression properties of PU coated fabric were increased in accordance with the increase of collagen concentration so that it became stiff. 7. The Value of MIU, SMD was decreased in accordance with the increase of collagen concentration so that the PU coated fabric became smooth.

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Transient Liquid Phase Bonding of Ni-Cr Heat Resisted Cast Steel (Ni-Cr계 내열주강의 천이액상 접합)

  • 권영순;신철균;김현식;김환태;김지순;석명진
    • Journal of Powder Materials
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    • v.9 no.3
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    • pp.189-198
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    • 2002
  • In this work, transient liquid phase (TLP) bonding of Ni-Cr heat resisted cast alloy (HP) was investigated. And also the behaviors of the solid particles distributed in the interlayer during TLP bonding were investigated. The MBF-60 and solid particles (Ni, Fe, and $Al_2O_3$ powders respectively) added MBF-60 which will be a liquid phase coexisting with solid particles at the bonding temperature were used as insert metal. The effective and sound bonding was possible by spark plasma sinter-bonding due to the differences of electric resistance between base metal and liquid insert layer which creates high temperature region. During the isothermal solidification, $Al_2O_3$ particles and solid particles of liquid phase sintered insert metal have shown no growth, while Ni and Fe particles grow rapidly. In this TLP bonding using the MBF-60 and distributed Fe, Ni particles as insert materials, the whole isothermal solidification process was dominated by the growth rate of the solid particles distributed in the interlayer.

Computer-Aided Alloy Design of Insert Metal for Transient Liquid Phase Bonding of High Aluminum Ni-base Superalloys

  • Nishimotd, Kazutoshi;Saida, Kazuyoshi
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.803-808
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    • 2002
  • A computer-aided alloy-designing technique to develop the insert metal for transient liquid phase (TLP) bonding was applied to high aluminum Ni-base superalloys. The main procedure of a mathematical programming method was to obtain the optimal chemical composition through rationally compromising the plural objective performances of insert metal by a grid-search which involved data estimation from the limited experimental data using interpolation method. The objective function Z which was introduced as an index of bonding performance of insert metal involved the melting point, hardness (strength), formability of brittle phases and void ratio (bonding defects) in bond layer as the evaluating factors. The contour maps of objective function Z were also obtained applying the interpolation method. The compositions of Ni-3.0%Cr-4.0%B-0.5%Ce (for ${\gamma}$/${\gamma}$/${\beta}$ type alloy) and Ni3.5%Cr-3.5%B-3%Ti (for ${\gamma}$/${\gamma}$ type alloy) which optimized the objective function were determined as insert metal. SEM observations revealed that the microstructure in bond layers using the newly developed insert metals indicated quite sound morphologies without forming microconstituents and voids. The creep rupture properties of both joints were much improved compared to a commercial insert metal of MBF-80 (Ni-15.5%Cr-3.7%B), and were fairly comparable to those of base metals.

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Effect of Dissolved Oxygen on the Stress Cor rosion Cracking Behavior of 3.5NiCrMoV Steels in High Temperature Water

  • Lee, J.H.;Maeng, W.Y.;Kim, U.C.
    • Corrosion Science and Technology
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    • v.2 no.4
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    • pp.178-182
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    • 2003
  • Slow Strain Rate Tests (SSRT) were carried out to investigate the effect of environmental factors on the Stress Corrosion Cracking (SCC) susceptibility of 3.5NiCrMoV steels used in discs for Low-Pressure (LP) steam turbines in electric power generating plants. The influences of dissolved oxygen on the stress corrosion cracking of turbine steel were studied, For this purpose, specimens were strained at variously oxygenated conditions at $150^{\circ}C$ in pure water. When the specimen was strained with $1{\times}10^{-7}s^{-1}$ at $150^{\circ}C$ in pure water, increasing concentration of dissolved oxygen decreased the elongation and the UTS. The corrosion potential and the corrosion rare increased as the amounts of dissolved oxygen increased. The increase of the SCC susceptibility of the turbine steel in a highly dissolved oxygen environment is due to the non protectiveness of the oxide layer on the turbine steel surface and the increase of the corrosion current. These results clearly indicate that oxygen concentration increases Stress Corrosion Cracking susceptibility in turbine steel at $150^{\circ}C$.

The Properties and Low temperature Preparation of The Backlayer of Co-Cr thin layer by Ferrite Plating Method (페라이트 플레이팅법에 의한 CO-Cr박막 하지층의 저온제작과 그 특성)

  • Kim, M.H.;Kim, T.Y.;Son, I.H.;Park, C.O.;Kim, J.H.;Kim, K.H.
    • Proceedings of the KIEE Conference
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    • 1997.11a
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    • pp.294-295
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    • 1997
  • CO-Cr 수직자기기록 매체의 우수한 하지층을 개발하기 위하여, 스피넬 결점막$(Fe,M)_3O_4$ (M=Ni,Zn)이 스핀스프레이 페라이트 플레이팅 방법으로 유리 기판 위에 제작되었다. 반응액과 산화액은 기판이 회전하는 반응용기로 분사되었다. 반응은 기판의 회전소독, 반응온도, 반응액과 산화액의 유속 그리고 반응액과 산화액의 농도에 의해 영향받았다. 반응액과 산화액의 유속은 60(ml/min)으로 하고, 반응온도는 90[$^{\circ}C$] 그리고 기판의 회전속도는 150[rpm]의 조건하에서, 페라이트 플레이팅 반응에 미치는 반응액과 산화액 농도의 영향이 화학적 조성, 결정학적 및 자기적 특성의 관점에서 연구되었다. $Ni_{0.34}Zn_{0.66}Fe_2O_4$의 조성에서, 우리는 가장 안정한 결정학적 및 자기적 특성을 얻었다.

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Isolation and Proteomic Analysis of a Chlamydomonas reinhardtii Mutant with Enhanced Lipid Production by the Gamma Irradiation Method

  • Baek, Jaewon;Choi, Jong-il;Park, Hyun;Lim, Sangyong;Park, Si Jae
    • Journal of Microbiology and Biotechnology
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    • v.26 no.12
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    • pp.2066-2075
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    • 2016
  • In this study, an enhanced lipid-producing mutant strain of the microalga Chlamydomonas reinhardtii was developed by gamma irradiation. To induce the mutation, C. reinhardtii was gamma irradiated at a dose of 400 Gy. After irradiation, the surviving cells were stained with Nile red. The mutant (Cr-4013) accumulating 20% more lipid than the wild type was selected. Thin-layer chromatography revealed the triglyceride and free fatty acid contents to be markedly increased in Cr-4013. The major fatty acids identified were palmitic acid, oleic acid, linoleic acid, and linolenic acid. Random amplified polymeric DNA analysis showed partial genetic modifications in Cr-4013. To ascertain the changes of protein expression in the mutant strain, two-dimensional electrophoresis was conducted. These results showed that gamma radiation could be used for the development of efficient microalgal strains for lipid production.

Characteristics of Zr-base Passivation Layers of Tinplate (전기주석도금강판의 Zr계 화학처리 피막 특성)

  • Bae D.C.;Kim T.Y.;Cho K.
    • Journal of the Korean institute of surface engineering
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    • v.36 no.3
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    • pp.251-255
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    • 2003
  • With increasing environmental demands in surface treatment of steel sheets, the passivation layers containing hexavalent chromium $(Cr^{+6})$ are being replaced by non-chromium or trivalent chromium compounds. After review on the various types of inorganic compounds, the zirconates was chosen as the candidate for alternative to sodium dichromate in the aspect of its barrier properties with excellent adhesion to organics. The ammonium zirconium carbonate (AZC) and sodium hexafluorozirconate (SFZ) could be reach $70-80\%$ level of CDC (cathodic dichromate) treatment by their single applications. But high porosity in the AZC layer and poor electrical conductivity of SFZ solution limit the single application of zirconate. Mixed composition of zirconates to compensate their inferiorities or incorporation of organic compounds to seal the porosity seems to be inevitable to match up the target level of Cr-free passivation of tinplate.

Effect of the Droplets on the Wear Characteristics of Steel for the Cold Working Roller (Droplet가 냉연 롤러용 강의 마모 특성에 미치는 영향)

  • 문봉호
    • Tribology and Lubricants
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    • v.20 no.3
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    • pp.145-151
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    • 2004
  • A modified surface layer by ion implantation is very thin (under 1 $\mu\textrm{m}$) but has superior mechanical characteristics. therefore ion implantation has been used successfully as a surface treatment technology to improve the wear, fatigue, and corrosion resistances of materials. MEVVA which is a kind of ion beam apparatus has merits of low cost and is usable to various metals, but occurs a droplet ranging from micron to tens of micron on the implanted surface at ion implantations. wear is a dynamic phenomenon on interacting surfaces with rotative motion. Since wear changes in condition of the surface, we should control to surface. In order to improve a wear resistance of Ti ion implanted 1C-3Cr steel(material for roller in the cold working process), it is essential to investigate the effect of the droplets on the wear characteristics. In this study, we investigate the effect of the droplets on the wear characteristics of 1C-3Cr steel using SEM Tribosystem as in-situ system. Results show that the droplet occurred at ion implantation becomes the cause of severe wear. Therefore, the ion-implanted surface should be removed the droplet to improve wear resistance.

A Study on the High Temperature Gas Nitriding Heat Treatment of STS 347 and STS 310S Austenitic Stainless Steel (STS 347 및 STS 310S 오스테나이트계 스테인리스강의 고온 가스질화 열처리 특성 연구)

  • Yoo, Dae Kyoung;Kong, Jung Hyun;Lee, Hea Joeng;Sung, Jang Hyun;Lee, Hae Woo
    • Korean Journal of Metals and Materials
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    • v.46 no.11
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    • pp.708-712
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    • 2008
  • The influence of high temperature gas nitriding (HTGN) in STS347 and STS310S steels was experimentally investigated. The HTGN was carried out at $1,050^{\circ}C{\sim}1,150^{\circ}C$ for 10 hrs in a gaseous atmosphere containing $1kg/mm^2$ of nitrogen. After HTGN, fine precipitates of $Cr_2N$ and NbN appeared in austenite on the surface of STS 347, while nitrogen pearlite, which was layeredof $Cr_2N$ and austenite alternatively, appeared in austenite on the surface of STS 310S. The surface hardness of HTGN-treated, STS 347 and STS 310S specimens was 250~360 Hv and 270~400 Hv, respectively, depending on the temperature of HTGN. The nitrogen content was analyzed 1.4 wt% and 1.6 wt% at the surface layer of STS 347 and STS 310S steels, respectively. In addition, an improvement in the corrosion resistance of HTGN treated specimens was observed.

Fate and Transport of Cr(VI) Contaminated Groundwater from the Industrial Area in Daejeon (대전 산업단지 지하수의 6가 크롬 오염 및 확산 평가)

  • Chon, Chul-Min;Moon, Sang-Ho;Ahn, Joo-Sung;Kim, Yung-Sik;Won, Jong-Ho;Ahn, Kyoung-Hwan
    • Economic and Environmental Geology
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    • v.40 no.4
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    • pp.403-418
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    • 2007
  • The objective of this research was to characterize the fate and transport of Cr(VI) contaminated groundwater in the Daejeon industrial area. Five subsidiary monitoring wells were newly installed and two existing wells were utilized for the investigation and the reduction process of Cr(VI) contaminated groundwater of the Daejeon(Mun-pyeong) national groundwater monitoring station. The Cr(VI) concentrations at the shallow aquifer well of the station were in the range of 3.2-4.5 mg/L indicating continuous contamination. However, Cr was not detected at the deep bedrock well and the other monitoring wells except MPH-1 and 3. The Cr(VI) concentrations of MPH-1 and MPH-3 were below the drinking water guideline value (0.05 mg/L). Therefore, the plume of the Cr(VI) contaminated groundwater was predicted to be confined within the narrow boundary around the station. The soluble/exchangeable Cr(VI) concentrations were below the detection limit in all core and slime samples taken from the five newly installed wells. Although the exact source of contamination was not directly detected in the study area, the spatial Cr(VI) distribution in groundwater and characteristics of the core samples indicated that the source and the dispersion range were confined within the 100 m area from the monitoring station. The contamination might be induced from the unlined landfill of industrial wastes which was observed during the installation of an subsidiary monitoring well. For the evaluation of the natural attenuation of Cr(VI), available reduction capacities of Cr(VI) with an initial concentration of 5 mg/L were measured in soil and aquifer materials. Dark-gray clay layer samples have high capacities of Cr(VI) reduction ranging from 58 to 64%, which is obviously related to organic carbon contents of the samples. The analysis of reduction capacities implied that the soil and aquifer materials controlled the dispersion of Cr(VI) contamination in this area. However, some possibilities of dispersion by the preferential flow cannot be excluded due to the limited numbers of monitoring wells. We suggest the removal of Cr(VI) contaminated groundwater by periodical pumping, and the continuous groundwater quality monitoring for evaluation of the Cr(VI) dispersion should be followed in the study area.