• Title/Summary/Keyword: Cr equivalent

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Adsorption Characteristics of Co(II), Ni(II), Cr(III) and Fe(III) Ions onto Cation Exchange Resin - Application to the Demineralizing Process in a Primary Coolant System of PWR (양이온교환수지에 대한 Co(II), Ni(II), Cr(III), Fe(III) 이온의 흡착 특성 - 원자로 일차 냉각재 계통내 탈염 공정에의 적용)

  • Kang, So-Young;Lee, Byung-Tae;Lee, Jong-Un;Moon, Seung-Hyeon;Kim, Kyoung-Woong
    • Journal of Radiation Protection and Research
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    • v.27 no.1
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    • pp.27-35
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    • 2002
  • Characteristics of Amberlite IRN 77, a cation exchange resin, and the mechanisms of its adsorption equilibria with Co(II), Ni(II), Cr(III) and Fe(III) ions were investigated for the application of the demineralizing process in the primary coolant system of a pressurized water reactor (PWR). The optimum dosage of the resin for removal of the dissolved metal ions at $200mgL^{-1}$ was 0.6 g for 100 mL solution. Most of each metal ion was adsorbed onto the resin in an hour from the start of the reaction. Each metal adsorption onto the resin could be well represented by Langmuir isotherms. However, in the case of Fe(III) adsorption, continuous formation of Fe-oxide or -hydroxide and its subsequent precipitation inhibited the completion of the equilibrium between the metal and the adsorbent Cobalt(II) and Ni(II), which have an equivalent electrovalence, were adsorbed to the resin with a similar adsorption amount when they coexisted in the solution. However, Cr(III) added to the solution competitively replaced Co(II) and Ni(II) which were already adsorbed onto the resin, resulting in desorption of these metals into the solution. The result was likely due to a higher adsorption affinity of Cr(III) than Co(II) and Ni(II). This implies that the interactively competitive adsorption of multi-cations onto the resin should be fully considered for an efficient operation of the demineralizing ion exchange process in the primary coolant system.

Study on the Correlation between Refractive error and Components of Eye's Optical system in Children and Teenagers in an Optometric Practice (안과 병원을 내원한 소아 청소년의 굴절이상과 안광학 성분간의 상관관계 연구)

  • Ha, Na-Ri;Kim, Hyun Jung
    • Journal of Korean Ophthalmic Optics Society
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    • v.17 no.1
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    • pp.67-74
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    • 2012
  • Purpose: The purpose of this study to evaluate visual acuity and refractive state and measure and analyze the components of eye's optical system in children and teenagers. Methods: With subjects of 124 (230 eyes) children and teenagers who had no eye diseases, correlation between the correlation between refractive errors and component's of eye's optical system was investigated. The spherical equivalent power of cycloplegic clinical refraction or manifest clinical refraction(SE), corneal power(CP), corneal radius(CR), axial length(AL), anterior chamber depth(ACD) and axial length to corneal radius (AL/CR) ratio were measured and analysed. Results: the SE was negatively correlated with the AL(r = -0.80, p = 0.00), the ACD(r = -0.35, p = 0.00) and the CR(r = -0.11, p=0.00) and positively correlated with the CP(r = +0.11, p=0.00). The AL was positively correlated with the AL/CR ratio (r = +0.84, p = 0.00), the ACD(r = +0.47, p=0.00) and the CR(r = +0.38, p = 0.00) and negatively correlated with the CP(r = -0.38, p=0.00). The CR was negatively correlated with CP(r = -1.00, p = 0.00), the AL/CR ratio(r = -0.19, p = 0.00) and the ACD(r = -0.06, p = 0.39). The CP was positively correlated with the AL/CR ratio(r = +0.19, p = 0.00) and the ACD(r = +0.06, p = 0.39). The ACD was positively correlated with the AL/CR ratio(r = 0.53, p = 0.00). Conclusions: the highest change of refractive errors was shown that the AL/CR ratio was a very important indicator for diagnosing the refractive errors of the children and teenagers.

Evaluation of Aging Degradation in 2.25Cr-1Mo Steel by Coercivity and Remanence Measurements - Microstructural Approach (보자력 및 잔류자화를 이용한 2.25Cr-1Mo강의 경년열화도 평가 - 미세조직적 접근)

  • Byeon, Jai-Won;Kwun, Sook-In
    • Journal of the Korean Society for Nondestructive Testing
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    • v.22 no.1
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    • pp.65-73
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    • 2002
  • Artificial aging was performed to simulate the microstructural degradation in 2.25Cr-1Mo steel arising from long time exposure at $540^{\circ}C$. Microstructural analysis (mean equivalent size, number of carbides per unit area) and measurement of mechanical properties(UTS, Vickers hardness) and magnetic properties(coercivity, remanence) were performed. By comparing these results, the relationship between magnetic properties and microstructural changes with artificial aging was clarified. The carbides were classified as rod, globular and acicular type in terms of morphology. The fine acicular carbides were found to diminish drastically in the initial stage of aging. The magnetic coercivity and remanence were observed to decrease rapidly in the initial about 920 hours of aging time and then decrease slowly afterwards. Linear correlations between the mechanical properties and magnetic properties such as correlations remanence were found.

Evaluations of Microstructure and Electrochemical Anodic Polarization of AISI 304L and AISI 316L Stainless Steel Weld Metals with Creq/Nieq Ratio (Creq/Nieq비에 따른 AISI 304L 및 AISI 316L 스테인리스강 용접부의 미세조직 및 전기화학적 양극분극 평가)

  • Kim, Yeon Hee;Jang, Ah Young;Kang, Dong Hoon;Ko, Dae Eun;Shin, Yong Taek;Lee, Hae Woo
    • Korean Journal of Metals and Materials
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    • v.48 no.12
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    • pp.1090-1096
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    • 2010
  • This pitting corrosion study of welded joints of austenitic stainless steels (AISI 304L and 316L) has addressed the differentiating solidification mode using three newly introduced filler wires with a flux-cored arc welding process (FCAW). The delta ferrite (${\delta}$-ferrite) content in the welded metals increased with an increasing equivalent weight ratio of chromium/nickel ($Cr_{eq}/Ni_{eq}$). Ductility dip cracking (DDC) was observed in the welded metal containing ferrite with none of AISI 304L and 0.1% of AISI 316L. The potentiodynamic anodic polarization results revealed that the $Cr_{eq}/Ni_{eq}$ ratio in a 3.5% NaCl solution didn't much affect the pitting potential ($E_{pit}$). The AISI 316L welded metals with ${\ddot{a}}$-ferrite content of over 10% had a superior $E_{pit}$ value. Though the AISI 316L welded metal with 0.1% ferrite had larger molybdenum contents than AISI 304L specimens, it showed a similar $E_{pit}$ value because the concentration of chloride ions and the corrosion product induced severe damage near the DDC.

A Study on Stress Analysis of Small Punch-Creep Test and Its Experimental Correlations with Uniaxial-Creep Test (소형펀치-크리프 시험에 대한 응력해석과 일축 크리프 시험과의 상관성에 관한 연구)

  • Lee, Song-In;Baek, Seoung-Se;Kwon, Il-Hyun;Yu, Hyo-Sun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.12
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    • pp.2565-2573
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    • 2002
  • A basic research was performed to ensure the usefulness of Small Punch-creep(SP-creep) test for residual life evaluation of heat resistant components effectively. This paper presents analytical results of initial stress and strain distributions in SP specimen caused by constant loading for SP-creep test and its experimental correlations with uniaxial creep(Ten-creep) test on 9Cr1MoVNb steel. It was shown that the initial maximum equivalent stress, ${\sigma}_{eq{\cdot}max}$ from FE analysis was correlated with steady-state equivalent creep strain rate, ${\epsilon}_{qf-ss'}$ rupture time, $t_r$, activation energy, Q and Larson-Miller Parameter, LMP during SP-creep deformation. The simple correlation laws, ${\sigma}_{sp}-{\sigma}_{TEN}$, $P_{sp}-{\sigma}_{TEN}\; and\; Q_{sp}-Q_{TEN}$ adopted to established a quantitative correlation between SP-creep and Ten-creep test data. Especially, the activation energy obtained from SP-creep test is linearly related to that from Ten-creep test at $650^{\circ}C$ as follows : $Q_{SP-P}\;{\risingdotseq}\;1.37 \;Q_{TEN},\; Q_{SP-{\sigma}}{\risingdotseq}1.53\; Q_{TEN}$.

Refractory Textile Wastewater Treatment Using Cell-Immobilized Polyethylene glycol Media (PEG 포괄고정화담체를 이용한 난분해성 염색폐수 처리)

  • Han, Duk-Gyu;Cho, Young-Jin;Bae, Woo-Keun;Hwang, Byung-Ho;Lee, Yong-Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.3
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    • pp.345-350
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    • 2006
  • This study investigated the removal of recalcitrant organics in dyeing wastewater using a fluidized bed reactor(FBR) that contained cell-immobilized pellets. The pellets were manufactured and condensing the gel phase by mixing PEG-polymer and cells to form micro-porous PEG-polymer pellets whose size were ${\Phi}\;4mm{\times}H\;4mm$ on average. An industrial activated sludge without any pre-adaptation was used for the cell immobilization because it gave an equivalent removal efficiency to a pre-adapted sludges. The feed was obtained from an effluent of a biological treatment plant, which contained $SCOD_{Cr}$ of 330 mg/L and $SBOD_5$ of 20 mg/L. The $SCOD_{Cr}$ removal efficiency was over 45% and the effluent $COD_{Mn}$ concentration was less than 100 mg/L at HRTs from 6 to 24 hrs. The optimum HRT in the FBR was determined as 12 hrs considering the removal efficiency and cost. When a raw wastewater containing 768 mg/L of $COD_{Cr}$ was fed to the FBR, the effluent $COD_{Cr}$ concentration increased only slightly, giving a 70% of $COD_{Cr}$ removal or a 97% of $BCOD_5$ removal. This indicated that the FBR had an excellent capability of biodegradable organics removal also. In conclusion, the FBR could be applied to textile wastewater treatment in place of an activated sludge process.

Oral Bioavailability for Sub-micron Particle Curcumin (TheracurminCR-033P) and Absorption Rate by Product Composition in Healthy Human Volunteers (서브마이크론 입자 형태 커큐민의 생체 흡수율 및 제품 조성에 따른 흡수율 동등성 연구)

  • Park, Hee Jung;Takahashi, Tsukasa;Ozawa, Hitomi
    • Food Engineering Progress
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    • v.21 no.3
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    • pp.273-279
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    • 2017
  • Curcumin have various health-beneficial properties in numerous studies. However, its bioavailability is low due to its limited intestinal uptake and rapid metabolism. This study aimed to evaluate the pharmacokinetics of newly developed sub-micron particle curcumin with increased water dispersibility (Theracurmin(R) CR-033P). Plasma curcumin levels were measured at 0, 1, 2, 4, 8 h after Theracurmin(R) CR-033P intake using high-performance liquid chromatography. For analyzing pharmacokinetics of Theracurmin(R) CR-033P, eighteen healthy subjects were recruited and received Theracurmin(R) CR-033P at a single oral dose containing curcumin 30 mg. $C_{max}$ was 28.14 ng/ml, and the area under the curve for 8 h was estimated to be 104.36 ng/ml. Based on the area under the plasma concentration (AUC), the bioavailability of sub-micron particle curcumin was higher 22-, 35-, 28-fold than native curcumin in men, women, and all subjects, respectively. For comparing by formulation, seven healthy subjects were recruited and received two type of treatment: (1) existing dosage form 300 mg (contained curcumin 30 mg) ${\times}$ 3 capsule, (2) high dosage form 300 mg (contained curcumin 90 mg) ${\times}$ 1 capsule + placebo 300 mg ${\times}$ 2 capsule. In the cross-over study, there was no significant differences in $C_{max}$ and AUC of plasma curcumin. In conclusion, submicron particle curcumin with increased water dispersibility significantly improved its oral bioavailability and women absorbed curcumin more effectively than men. Different formulation of Theracurmin(R) CR-033P has shown equivalent to the reference in terms of pharmacokinetics.

MMSE Transmit Optimization for Multiuser Multiple-Input Single-Output Broadcasting Channels in Cognitive Radio Networks

  • Cao, Huijin;Lu, Yanhui;Cai, Jun
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.7 no.9
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    • pp.2120-2133
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    • 2013
  • In this paper, we address the problem of linear minimum mean-squared error (MMSE) transmitter design for the cognitive radio (CR) multi-user multiple-input single-output (MU-MISO) broadcasting channel (BC), where the cognitive users are subject to not only a sum power constraint, but also a interference power constraint. Evidently, this multi-constraint problem renders it difficult to solve. To overcome this difficulty, we firstly transform it into its equivalent formulation with a single constraint. Then by utilizing BC-MAC duality, the problem of BC transmitter design can be solved by focusing on a dual MAC problem, which is easier to deal with due to its convexity property. Finally we propose an efficient two-level iterative algorithm to search the optimal solution. Our simulation results are provided to corroborate the effectiveness of the proposed algorithm and show that this proposed CR MMSE-based scheme achieves a suboptimal sum-rate performance compared to the optimal DPC-based algorithm with less computational complexity.

Effect of Working Capital Management on the Profitability of Steel Companies on Vietnam Stock Exchanges

  • PHAM, Kien Xuan;NGUYEN, Quang Ngoc;NGUYEN, Cong Van
    • The Journal of Asian Finance, Economics and Business
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    • v.7 no.10
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    • pp.741-750
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    • 2020
  • This study examines the influence of working capital management (WCM) factors on the profitability of steel companies listed on the Stock Exchange of Vietnam. Data was collected from audited financial statements of companies for a period of 10 years, from 2010 to 2019. The number of samples eligible for research is 20 out of 26 companies, which is equivalent to 76.9%. With the help of dedicated software Stata version 14, the impact determination of WCM (through 8 independent variables: DIO, DPO, DSO, CCC, SIZ, CR, LEV, GRO) to the firm's profitability (through the dependent variable) is performed through multivariate regression models. Research results from companies in the steel industry in Vietnam during this period indicate that WCM has a strong impact on the profitability of businesses. Among 8 factors affecting the profitability of steel enterprises, factors DPO, DIO, DSO, CR, SIZ, GRO have a positive impact, boosting profitability; 2 factors CCC and LEV have a negative impact on profitability; in which, the effect of CCC is negligible. This conclusion is almost in contrast to many previously published studies due to the specifics of the industry as well as the different stages of economic development associated with the economic management policies of the State.

Fabrication and evaluation of hydrophobic metal stent using electron beam equipment (전자빔 처리를 통한 발수성 금속 스텐트 제작 및 평가)

  • Kim, Jisoo;Park, Jongsung
    • Journal of Sensor Science and Technology
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    • v.30 no.3
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    • pp.165-169
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    • 2021
  • The objective of this study was to fabricate a novel hydrophobic stent for reducing restenosis by employing electron beam equipment. The stent was fabricated from a CoCr alloy tube by using a femtosecond laser and was treated with argon plasma. Subsequently, the stent's surface specification changed from hydrophilic to hydrophobic. Application of the electron beam offers several advantages such as a short processing time, whole surface reforming, and enhancement of material properties. As the surface of the stent was rendered hydrophobic, it can provide equivalent or enhanced mechanical properties and greater functionality with a higher radial force at the extended stent in a blood vessel. The obtained results corresponding to the mechanical properties indicate that the contact angle increased to approximately 130°, and the radial force increased to approximately 3 N. Furthermore, cell culture experiments were conducted for verifying whether cells were cultured on the surface-modified CoCr surface. Based on the obtained results, it is believed that an effective reduction in the restenosis of inserted vascular stents is possible.