• Title/Summary/Keyword: Cr carbide

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The Effects of Nb, V on the High Temperature Wear and Corrosion of the Overlaying Materials for Continuous Casting Rolls (연주롤용 육성용접 재료의 고온마모 및 부식특성에 미치는 Nb, V의 영향)

  • Kim, C.G.;Whang, D.S.;Yoon, J.H.;Kang, C.Y.;Kwak, H.H.
    • Journal of Power System Engineering
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    • v.8 no.3
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    • pp.30-35
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    • 2004
  • In the steel making industries, the continuous casting process has been applied to the number of company because of its economical benefit. Casting rolls are utilized for frictional drive and transport of solidifying slap. Dimensional tolerances, mechanical stability and surface condition of the cast roll can affect both the surface and internal quality of the product being cast. To overcome these problems, the industry is accelerating on the rate of technology improvements. Samples were overlaid on the S45C steel by submerged arc welding process. And the hardness, wear, electrochemical corrosion and oxidation tests were carried out. Test results were that all these materials were satisfying basic requirements of caster rolls. By these results, the addition of 0.1%Nb and 0.15%V increase mechanical properties and tempering resistance by its superior carbide forming characteristics in low carbon $12{\sim}13%Cr$ martensitic stainless steels.

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Sliding Wear Behavior of Plasma Sprayed Zirconia Coatingagainst Silicon Carbide Ceramic Ball

  • Le Thuong Hien;Chae Young-Hun;Kim Seock Sam;Kim Bupmin;Yoon Sang-bo
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2004.11a
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    • pp.66-74
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    • 2004
  • The sliding wear behavior of $ZrO_2-22wt\%MgO\;(MZ)\;and\;ZrO_2-8wt\%Y_2O_3\;(YZ)$ deposited on a casting aluminum alloy with bond layer (NiCrCoAlY) by plasma spray against an SiC ball was investigated under dry test conditions at room temperature. At all load conditions, the wear mechanisms of the MZ and the YZ coatings were almost the same. The wear mechanisms involved the forming of a smooth film by material transferred on the sliding surface and pullout. The wear rate of the MZ coating was less than that of the YZ coating. With an increase normal load the wear rate of the studied coatings increased. The SEM was used to examine the sliding surfaces and elucidate likely wear mechanisms. The EDX analysis of the worn surface indicated that material transfer was occurred from the SiC ball to the disk. It was suggested that the material transfer played an important role in the wear performance.

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A Study on the High Temperature Strength of Ferritic Stainless Cast Steels (페라이트계 스테인레스 주강의 고온강도에 관한 연구)

  • Ann, Soo-Jung;Kang, Mi-Ri;Seo, Do-Soo;Kim, Yong-Hyun;Lee, Kwang-Hak;Kim, Heung-Shik
    • Journal of Korea Foundry Society
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    • v.18 no.6
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    • pp.563-569
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    • 1998
  • A Study on microstructure and elevated temperature strength of 18Cr-2Mo ferritic stainless steel castings strengthened by alloying small amounts of titanium and carbon, has been conducted. The morphology of titanium carbides showed spherical in shape and their distribution depended on the amount of alloying elements. Maximum density ($7{\times}10^5/cm^2$) of titanium carbides has been formed in the alloy containing 2.0 wt.% titanium and 0.5 wt.% carbon as alloying elements and the size of carbide particles is in the range of 0.5 to $3.0\;{\mu}m$. High temperature tensile and fatigue strength of this alloy were the highest among the alloys tested in this research. The fracture mode of the alloys containing alloying elements less that 2.0 wt.% titanium and 0.5 wt.% carbon showed intercrystalline fracture at room temperature, while the alloys containing higher amounts of alloying elements showed transcrystalline fracture. All of the alloys showed creep or ductile rupture mode at elevated temperature.

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A study on the KLA behaviors in HAZ and the mechanical properties of austenitic stainless steel weld (스테인레스강용접 열영향부의 KLA거동 및 기계적 특성에 관한 연구)

  • 조종춘;김영석;김학민
    • Journal of Welding and Joining
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    • v.8 no.4
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    • pp.27-34
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    • 1990
  • Integranular corrosion behaviors of KAL (Knife Line Attack) and mechanical properties such as tensile and creep rupture were investigated for the tube material used for nearly 20 years under the condition of 463.deg. C and 28 $kg/cm^2$. Based and weld metal were austenitic stainless steel AISI 321 containing Ti, AISI 347 containing Nb, respectively. KLA is a kind of the intergranular corrosion which often occurs just near the HAZ (heat affected zone) of AISI 321 and AISI 347 stainless steel due to the grain boundary sensitization. In KLA zone, intergranular corrosion crack has propagated outwards from the inner surface and carbides of white and narrow band type assuming as (Cr, Fe) carbide were confirmed. All the delta-ferrite formed in the weld metal during weld solidification has been transformed into sigma-phase since delta-ferrte was exposed for 20 years at 463.deg. C. Elongation was very low at the range from room temperature to 600.deg. C and it was confirmed that creep-rupture properties were not consideralbly affected.

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Effect of Coating Materials on Surface Layer Structures of Austenitic Stainless Steel Castings in Evaporative Pattern Process (소실모형 주조법에서 도형제가 오스테나이트 스테인레스강 주물의 표면층조직에 미치는 영향)

  • Kim, Ji-Youn;Cho, Nam-Don
    • Journal of Korea Foundry Society
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    • v.15 no.6
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    • pp.604-615
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    • 1995
  • Austenitic stainless steel castings using expandable polystylene(referred to hereafter as EPS) patterns are often affected by distinctive defects associated with incomplete decomposition of the EPS as the molds are filled with metal. The quality of the castings, with particular reference to carbon pick-up in austenitic stainless steel is further influenced to a significant extent by such factors as reduced pressure, the additive by adding $Na_2CO_3$ in coating. The steel composition and microstructure were examined at the surface layer of castings, at depths of 1mm, by taking successive layers of swarf and analysis. In experiments, the carburizing atmosphere was neutralized, showing that the coating performed efficiently by decomposing almost instantly on heating and liberating $CO_2$. The upper parts of castings obtained using EPS patterns were slightly higher in carbon pick-up than other parts. Comparing the 316L and 304 stainless steel castings, qualitative and quantative differences could be found between the carbon pick-up behaviours as influence of the carbon content and alloying elements. Carbide former such as Cr makes carbon more soluble in the steel. This must make carbon pick-up in the surface layer but at the same time richer in carbon especially in the 304 stainless steel castings.

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Effect on Anti-impact and Anti-thermal Fatigue Properties of STD61 Material Affected by Gas Quenching Pressure of Quenching Process (STD61 공구강의 내충격 및 내열피로 특성에 미치는 가스 퀜칭 압력의 영향)

  • Park, Hyun-Jun;Choi, Kwang-Jin;Kim, Jong-Yeob;Shin, Seung-Yong;Moon, Kyoung-Il
    • Journal of the Korean Society for Heat Treatment
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    • v.29 no.6
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    • pp.277-283
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    • 2016
  • The influences of cooling pressure of quenching process on the mechanical properties such as hardness, impact endurance and anti-thermal fatigue behaviour of STD61 steel were investigated. The specimens were heat-treated using a vacuum furnace in which they were austenitized at $1,030^{\circ}C$ for 1hour under the pressure of $10^{-3}$ torr and cooled with quenching gas of various pressure, i.e. 1, 2 and 6 bar. According to the observation on the specimens prepared with quenching from austenizing temperature, the mechanical properties of the samples with higher quenching pressure were better than those of prepared at lower quenching pressure. The samples prepared with high quenching pressure showed the more homogeneous microstructure with finer carbides. The size of carbides such as VC and (Fe, Cr)C in quenched specimens decreased with increasing gas quenching pressure. It is considered that the rapid cooling with pressure may restrict the formation and growth of carbide.

A Study on Hot Ductility Behavior of Ni-based Superalloys (니켈기 초내열합금의 고온연성거동에 관한 연구)

  • Lee, Choung-Rae;Um, Sang-Ho;Kim, Sung-Wook;Choi, Cheol;Lee, Chang-Hee
    • Journal of Welding and Joining
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    • v.22 no.2
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    • pp.59-68
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    • 2004
  • Plasma transferred arc welding (PTAW) has been taken into consideration for repairing Ni-based superalloy components used gas turbine blades. Various cracks has been generally reported to be found in the base metal heat affected zone(HAZ) along grain boundary. Thus, hot cracking susceptibility of Ni-based superalloys was evaluated according to heat treatments. Hot ductility test was conducted on specimens with solution treated at 112$0^{\circ}C$ for 2 hours and aging treated at 845$^{\circ}C$ for 24hours after solution treatment. The results of the hot ductility test appeared that solution treated specimens were the highest ductility recovery rate among three conditions. The loss of ductility at high temperature in Ni-based superalloy was mainly controlled by the degree of pain boundary wetting due to constitutional liquation of MC carbide precipitates. Meanwhile, the highest ductility recovery rate in solution-treated alloys seems to be lack of M23C6, which can be dissolved during heating and then result in the local enrichment of Cr in the vicinity of the grain boundary.

Effect of Primarily Solidified Structure on the Microstructure and the Mechanical Properties of High Cr White Iron (고크롬 백주철의 미세조직과 기계적 특성에 미치는 초기응고 조직의 영향)

  • Jo, Hyun-Wook;Do, Jeong-Hyeon;Jo, Won-Je;Chung, Hyun-Deuk;Lee, Je-Hyun;Jo, Chang-Yong
    • Journal of Korea Foundry Society
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    • v.35 no.6
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    • pp.178-184
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    • 2015
  • Due to excellent abrasion resistance the high-chrome white irons are widely used in mining and mineral industries. Minor variation of carbon content in 28% chrome white iron resulted in difference in primarily solidified microstructure. Sub-eutectic (hypoeutectic) composition led to formation of primarily solidified dendrites. Formation of primarily solidified dendrites which were supersaturated with carbon and chrome also caused precipitation of fine secondary carbides that are different from relatively large plate type $M_7C_3$ carbides in the eutectic structure. Small portion of primarily solidified dendrite expected to contribute significantly to the improvement of abrasion resistance of the white iron because the dendrites provided mechanical support to carbides. The relative fraction of primary dendrite increased with reduction of carbon content from the eutectic composition. The increased fraction of primary dendrite increased hardness value of the white irons.

Cavitation-Erosion Characteristics of the Stainless Steel with Adding Ti Stabilizer Element in Sea Water (안정화 원소 Ti 첨가에 따른 스테인리스강의 해수 내 캐비테이션-침식 특성)

  • Choi, Yong-Won;Yang, Ye-Jin;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.49 no.4
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    • pp.344-348
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    • 2016
  • Stainless steel is widely applied in many industrial fields due to its excellent anti-corrosion and durability characteristics. However, stainless steel is very vulnerable to cavitation attack caused by high speed flow of fluid in the chloride environments such as marine environment. These conditions promote intergranular corrosion and cavitation-erosion, leading to degradation of the structural integrity and service life. In order to prevent these problems, the stabilized stainless steel is applied to the offshore and shipbuilding industries. In this study, Ti was added to 19%Cr-9%Ni as the stabilizer element with different concentrations (0.26%, 0.71%), and their durabilities were evaluated with cavitation-erosion experiment by a modified ASTM G32 method. The microstructural change was observed with the stabilizer element contents. The result of the observation indicated that the amount of carbide precipitation was decreased and its size became finer with increasing Ti content. In the cavitation-erosion experiment, both weight loss and surface damage depth represented an inverse proportional relationship with the amount of Ti element. Consequently, the stainless steel containing 0.71% of Ti had excellent durability characteristics.

Machinability of CBN Tools in Interrupted Milling Process of Die & Mold Steels with High Hardness (고경도 금형강 단속 밀링절삭에 대한 CBN 공구의 가공 성능)

  • Song, Jun-Hee;Mun, Sang-Don
    • Korean Journal of Metals and Materials
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    • v.48 no.7
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    • pp.651-659
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    • 2010
  • When high-speed interrupted cutting is carried out for die and mold steels with high hardness, CBN tools manifested a significantly longer wear life than carbide, ceramic, or cermet tools in an experiment of face milling characteristics. In addition, it was also found that they secured a stable surface roughness within a range of 1.6 S~6.3 S, an acceptable range for precision machining for polished machining parts. And it makes them acceptable in the precision machining field, except in industries where very high machining accuracy is required. In the high hardness interrupted cutting, it was advantageous to perform a negaland treatment and a honning treatment on the tools' cutting edge to extend tool life and surface roughness. Also, severe crater development was found on the sloped face in CBN tools following high-speed machining. This caused the cutting edge to be weakened and damaged, and ultimately resulted in a shorter tool life. Finally, as a result of EDX mapping inspection, Cr component was detected evenly on the entire crater wear area, which can be included only in STD 11.