• Title/Summary/Keyword: Cr 층

검색결과 456건 처리시간 0.029초

Laser Engraving of Plasma Sprayed Ceramic Coatings (플라즈마 용사된 세라믹 코팅층의 레이저 홈가공)

  • Bang, Se Yoon
    • Journal of the Korean Society for Precision Engineering
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    • 제14권1호
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    • pp.142-149
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    • 1997
  • Ceramic-coated anilox roll for printing is resistant to corrosion and wear, and hence has enhanced life and quality. Laser engraving is used typically for machining holes to store ink in this roll. Since engraved hole size and shape are directly related to laser processing parameters, it is necessary to know the rela- tionships among these parameters. In this study, the parameters for engraving of ;oasma sprayed ceramic coatings with Nd:YAG laser were studied. Relationships between hole shape and processing parameters were analyzed. Cr$_{2}$O$_{3}$ceramic was found to be most suitable for Nd:YAG laser engraving. It was found that hole depth can be increased by using higher energy pulses. Effect of using different assistant gases was small to the final results. For better results, it was suggested to use a very stable laser with shorter pulses and higher pulse energy.

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Geoacoustic characteristics of Quaternary stratigraphic sequences in the mid-eastern Yellow Sea (황해 중동부 제4기 퇴적층의 지음향 특성)

  • Jin, Jae-Hwa;Jang, Seong-Hyeong;Kim, Seong-Pil;Kim, Hyeon-Tae;Lee, Chi-Won;Chang, Jeong-Hae;Choi, Jin-Hyeok;Ryang, Woo-Heon
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • 제6권2호
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    • pp.81-92
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    • 2001
  • According to analyses of high-resolution seismic profiles (air gun, sparker, and SBP) and a deep-drill core(YSDP 105) in the mid-eastern Yellow Sea, stratigraphic and geoacoustic models have been established and seismo-acoustic modeling has been fulfilled using ray tracing of finite element method. Stratigraphic model reflects seismo-, litho-, and chrono-stratigraphic sequences formed under a significant influence of Quaternary glacio-eustatic sea-level fluctuations. Each sequence consists of terrestrial to very-shallow-marine coarse-grained lowstand systems tract and tidal fine-grained transgressive to highstand systems tract. Based on mean grain-size data (121 samples) of the drill core, bulk density and P-wave velocity of depositional units have been inferred and extrapolated down to a depth of the recovery using the Hamilton's regression equations. As goo-acoustic parameters, the 121 pairs of bulk density and P-wave velocity have been averaged on each unit of the stratigraphic model. As a result of computer ray-tracing simulation of the subsurface strata, we have found that there are complex ray paths and many acoustic-shadow zones owing to the presence of irregular layer boundaries and low-velocity layers.

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Sewage Treatment Using a Double Media Reed Constructed Wetland (복층여재 갈대 인공습지에 의한 생활하수 처리)

  • Seo, Jeoung-Yoon
    • Journal of Wetlands Research
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    • 제16권4호
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    • pp.379-388
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    • 2014
  • A sewage was treated using a serially combined vertical(VFCW) and horizontal flow double media (sand and zeolite for VFCW and sand and waste oyster-shell for HFCW) reed constructed wetland(HFCW) with intermittent feeding (see Fig. 1). The sewage was fed into the reed constructed wetland for 10 minutes every 6 hours at the hydraulic load of $314L/m^2{\cdot}day$. The summarized results were as follows: pH values in the effluent depended very heavily on oyster-shell height filled in the HFCW. They were maintained at less than pH 6.24 when the height of the oyster-shell layer was 200 mm. Influent DO(oxygen demand) values(average 0.19 mg/L) were increased in the VFCW(average 7.65 mg/L) and decreased again in the HFCW(average 6.49 mg/L). They were higher in the winter than in the summer. The OTR(oxygen transfer rate) was $57.15g\;O_2/m^2{\cdot}day$ in the VFCW and $5.65g\;O_2/m^2{\cdot}day$ in the HFCW. The removal efficiency of $NH_4{^+}$-N was 80.17%(6.01 $NH_4{^+}$-N mg/L in the effluent). It was lower than that in the case where only zeolite was filled in the reed constructed wetland. But it was expected that treated sewage effluent using a double media reed constructed wetland with 300 mm zeolite layer could stably meet the Korean treated sewage effluent standard(20 mg T-N/L). Average removal efficiencies were SS 88.09%, BOD 88.12%, $COD_{Cr}$ 83.11%, $COD_{Mn}$ 85.58%, T-N 57.21%, $NH_4{^+}$-N 80.17%, T-P 86.73%. Nearly, The concentration of $NO_3{^-}$-N in the effluent of the VFCW was decreased in that of the HFCW. More than half of T-N in the effluent was $NO_3{^-}$-N(7.92 mg/L) but the concentration of $NO_2{^-}$-N in the effluent was average 0.90 mg/L. The removal efficiencies of T-P were 93.24%, 86.30% and 55.44% at the height of the oyster-shell-filled constructed wetland of 800 mm, 500 mm and 200 mm, respectively and therefore, they were proportional to oyster-shell height filled in the HFCW.

Geology and Soils of Chojeong-Miwon Area (초정-미원지역의 지질과 토양에 관한 연구)

  • 나기창
    • The Journal of the Petrological Society of Korea
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    • 제9권1호
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    • pp.13-28
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    • 2000
  • Chojeong area is mainly composed of the Ogcheon Group which consists of regionally metamorphosed, age-unknown sedimentary rocks. In the northwestern parts, the Group is intruded by the Jurassic Daebo granite and Cretaceous felsic and mafic dykes. The lowermost, Midongsan Formation which consists of milky white impure quartzite, crops out along the anticline axes with N40E trend. Ungyori quartzite Formation is intercalated with quartzite and slate. Miwon Formation is most widely exposed in the area and consists mainly of phyllitic sandy rocks with a thin crystalline limestone bed. Hwajeonri Formation is divided into two parts, pelitic lower and calcareous upper parts, composed with phyllite and slate. Changri and Hwanggangri Formations are typical members of Ogcheon Group, the former bearing coally graphite seams consists mainly of black slate and phyllite with intercalated greenish grey phyllite, the latter is pebble bearing phyllite formation of which matrix and pebbles are variable in compositions and size. Biotite granite, porphyritic granite and two mica granite belong to Jurassic so-called Dabo granite. They intruded the Ogcheon Group forming vast contact metarnophic zone. Quartz porphyry, mafic dyke and felsite intruded along the marginal zone of porphyritic granite batholith and fracture of NS trend. Main structural lineaments in Ogcheon Group shows N25-45E, NS and N30-45W trends. The N25-45E trends are mainly from general ductile deformation during regional metamorphism, showing isoclinal folding, Fl foliations and lithological erosional characters. Some of these trends are due to normal faults. The NS and N30-45W trends represent brittle deformation including faults and joints. In the area of granitic batholith, NS to N30- 45 trends are from the direction of dykes. In the soils of the area, average contents of heavy metal elements such as Cd, Cr, Cu, Pb, and Zn are 0.2, 50.6, 35.5, 27.9, and 93.4 ppm respectively, which are not higher than the average values of natural soils, under the tolerable level. Enrichment Index does not show any heavy metal pollution in the area. Average depths of weathering(5m vs. 2m), porosities(43.94 vs. 51.80), densities(l.29 vs. 1.15), and permeabilities(2.52 vs. 8.07) are comparable in granite areas and in the phyllite areas of Ogcheon Group.

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A Study on the Wetting Properties of UBM-coated Si-wafer (UBM(Under Bump Metallurgy)이 단면 증착된 Si-wafer의 젖음성에 관한 연구)

  • 홍순민;박재용;박창배;정재필;강춘식
    • Journal of the Microelectronics and Packaging Society
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    • 제7권2호
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    • pp.55-62
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    • 2000
  • The wetting balance test was performed in an attempt to estimate the wetting properties of the UBM-coated Si-wafer on one side to the Sn-Pb solder. The wetting curves of the one and both side-coated UBM layers had the similar shape and the parameters characterizing the curve shape showed the similar transition tendency to the temperature. The wetting property estimation was possible with the new wettability indices from the wetting curves of one side-coated specimen; $F_{min}$, $F_{s}t_{s}$ and $t_s$. For UBM of Si-chip, Au/Cu/Cr UBM was better than Au/Ni/Ti in the point of wetting time. The contact angle of the one side coated Si-plate to the Sn-Pb solder could be calculated from the force balance equation by measuring the static state force and the tilt angle.

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Kinetics of Catalytic Oxidation of Vinyl Chloride over CrOx/γ-alumina (CrOx/γ-alumina 촉매상에서 Vinyl Chloride의 산화반응 속도해석)

  • Lee, Hae-Wan;Kim, Young Chai;Moon, Sei-Ki
    • Applied Chemistry for Engineering
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    • 제10권1호
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    • pp.85-92
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    • 1999
  • The complete catalytic oxidation of vinyl chloride was investigated over chromium oxide supported ${\gamma}$-alumina using a fixed bed micro-reactor at temperature between 240 and $300^{\circ}C$ and concentration between 600 and 3500 ppm. The oxidation of vinyl chloride was nonlinear in the concentration of vinyl chloride and zeroth order in the concentration of oxygen. The addition of HCl and $H_2O$ as products to the feed stream didn't influence the conversion of vinyl chloride. Several kinetic rate model were tested to describe the data over the range of condition investigated, and developed a model which provide the best correlation of experimental data. The resulting model of kinetic rate was derived by assuming that the reacting occurred via adsorption and subsequent decomposition of the vinyl chloride onto the oxygen covered chromium oxide surface, with the reaction being inhibited by the adsorption of vinyl chloride. The percent standard deviation between the predicted and experimental was about 5.2%, and the activation energy was 18.9 kcal/mol.

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Effect of HAZ Softening Zone on Creep Rupture Properties of 1.0Cr-1.0Mo-0.25V Turbine Steels -Part II : Carbide Morphology- (1.0Cr-1.0Mo-0.25V 터어빈 로터강의 열영향부 연화층이 크립 파단 특성에 미치는 영향 - Part II : 탄화물 형태 -)

  • ;Indacochea, J. E.
    • Journal of Welding and Joining
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    • 제15권1호
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    • pp.101-108
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    • 1997
  • In repaired weldment of ASTM A-470 class 8 high pressure stream turbine rotor steel, creep rupture life was studied in relation with carbide morphology. Carbides were identified using carbide extraction replica method. A retired rotor has molybdenum rich carbide $M_2C$, lndacochea vanadium rich carbide $M_4C_3$, and chromium rich carbides $M_{23}C_6$and $M_7C_3$. Weldments ruptured at ICHAZ showed that some of carbides have been transformed into spherical types of coarsened carbides at ruptured area. Those carbides were revealed as molybdenum rich $M_6C$ carbide and they provided cavitation sites due to molybdenum depletion around $(M_6C)$ carbide. However coarsened $M_6C$ and $M_{23}C_6$ carbides were observed at ruptured area in case of ruptured at CGHAZ.

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The Quality Characteristic of Pearls Produced at Pearl oyster, Pinctada fucata cultured in Tongyeong (통영해역의 진주조개, Pinctada fucata에서 생산된 진주의 품질특성)

  • Seo, Jin-Hyung;Lee, Sang-Jun;Jeong, Woo-Geon;Cho, Sang-Man
    • The Korean Journal of Malacology
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    • 제28권3호
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    • pp.245-254
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    • 2012
  • This project analyzes distinct qualities of pearl cultured in Tongyeong by physical, chemical and optical test. The result is to provide scientific data for the value of pearl from Korean seawater. It divides one year pearl, which is used as a sample in the project, into white, natural blue and yellow gold colors, and then it has been divided into A, B and C based on the quality of the last results. A chemical experiment demonstrates that the higher quality has lower protein content of less than 10%. In another test called heavy metal content test, there is no big difference among classes. In the characterization of spectroscopy, it shows 280 nm peak indicated the conchiolin. It is clear that 407 nm, 430 nm and 460 nm peak are White group that are not in processed condition.

Removal, Recovery, and Process Development of Heavy Metal by Immobilized Biomass Methods (미생물 고정화법에 의한 중금속 제거, 회수 및 공정개발)

  • Ahn, Kab-Hwan;Shin, Yong-Kook;Suh, Kuen-Hack
    • Journal of Environmental Science International
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    • 제6권1호
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    • pp.61-67
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    • 1997
  • Heavy metal adsorption by microbial cells is an alternative to conventional methods of heavy metal removal and recovery from metal-bearing wastewater The waste Sac-chuomyces cerevisiae is an inexpensive, relatively available source of biomass for heavy metal biosorption. Biosorption was investigated by free and immobilized-S. cerevisiae. The order of biosorption capacity was Pb>Cu>Cd with batch system. The biosorption parameters had been determined for Pb with free , cells according to the Freundlich and Langmuir model. It was found that the data fitted reasonably well to the Freundlich model. The selective uptake of immobilized-S. cerevisiae was observed when all the metal ions were dissolved in a mixed metals solution(Pb, Cu, Cr and Cd). The biosorption of mixed metals solution by immobilized-cell was studied in packed bed reactor. The Pb uptake was Investigated in particular, as it represents one of the most widely distributed heavy metals in water. We also tested the desorption of Pb from immobilized-cell by us- ing HCI, $H_2SO_4$ and EDTA.

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Surface Modification of Reverse Osmosis Membrane Skin Layer by Silane Compound (Silane 화합물을 이용한 역삼투막 활성층의 표면개질)

  • Lee Yong-Taek;Shin Dong-Ho;Kim No-Won
    • Membrane Journal
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    • 제16권2호
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    • pp.106-114
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    • 2006
  • This study is concerned with preparation of chlorine resistant (CR) thin layer composite (TFC) membranes. The novel method for making CR membranes from commercially available RO membranes is based on sol-gel condensation of trialkoxyalkylsilane derivatives. The silane coupling agents used in this study have different number of alkyl carbon chain group (methyltriethoxysilane; METES and octyltriethoxysilane; OCTES). The OCTES composite membranes have a significant tolerance to chlorine compared to commercial polyamide RO membrane or METES composite membranes. The surface properties of membranes were examined to explain a significant difference of chlorine tolerance between OCTES composite membrane and the other two membranes. In this study, we tried several surface analyses to explain difference of chlorine tolerance. The element composition results of surface analysis by EDX confirmed that both silane fixed on polyamide firmly, The surface roughness and contact angle results showed long chain alkyl group of OCTES enhancing hydrophobicity considerably than METES. The hydrophobicity plays an important role in chlorine resistance of membrane.