• Title/Summary/Keyword: Cr$Cr^{6+}$

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Characteristics of Stabilization and Adsorption of Heavy Metal (As3+, Cr6+) by Modified Activated Carbon (표면 개질 활성탄에 의한 중금속(As3+, Cr6+) 흡착 및 안정화 특성)

  • Shin, Woo-Seok;Na, Kyu-Ri;Kim, Young-Kee
    • Journal of Navigation and Port Research
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    • v.39 no.3
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    • pp.185-192
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    • 2015
  • In this study, the adsorption efficiency of mixed heavy metals in aqueous solution was investigated using modified activated carbon. Moreover, the heavy-metal stabilization treatment of contaminated marine sediment was achieved using modified activated carbon as stabilizing agents. From the experimental results, it was shown that the adsorption equilibrium was attained after 120 mins. Heavy metal adsorption was characterized using Freundlich and Langmuir equations. The equilibrium adsorption data were fitted well to the Langmuir model in modified activated carbon. The adsorption uptake of $As^{3+}$ (28.47 mg/g) was higher than $Cr^{6+}$ (13.28 mg/g). In case of the $Cr^{6+}$, the results showed that adsorption uptake decreased with increasing pH from 6 to 10. However, adsorption of $As^{3+}$ slightly increased in the increasing change of pH. The modified activated carbon was applied for a wet-curing duration of 120 days. From the sequential extraction results, the exchangeable, carbonate, and oxides fractions of Cr and As in sediment decreased by 5.8% and 7.6%, respectively.

Micro Structure and Surface Characteristics of NiCr Thin films Prepared by DC Magnetron Sputter according to Annealing Conditions (DC 마그네트론 스퍼터링 NiCr 박막의 열처리 조건에 따른 미세구조 및 표면특성)

  • Kwon, Yong;Kim, Nam-Hoon;Choi, Dong-You;Lee, Woo-Sun;Seo, Yong-Jin;Park, Jin-Seong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.6
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    • pp.554-559
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    • 2005
  • Ni/Cr thin film is very interesting material as thin film resistors, filaments, and humidity sensors because their relatively large resistivity, more resistant to oxidation and a low temperature coefficient of resistance (TCR). These interesting properties of Ni/Cr thin films are dependent upon the preparation conditions including the deposition environment and subsequent annealing treatments. Ni/Cr thin films of 250 nm were deposited by DC magnetron sputtering on $Al_2O_3/Si$ substrate with 2-inch Ni/Cr (80/20) alloy target at room temperature for 45 minutes. Annealing treatments were performed at $400^{\circ}C,\;500^{\circ}C,\;and\;600^{\circ}C$ for 6 hours in air or $H_2$ ambient, respectively. The clear crystal boundaries without crystal growth and the densification were accomplished when the pores were disappeared in air ambient. Most of surface was oxidic including NiO, $Ni_2O_3$ and $Cr_xO_y$(x=1,2, y=2,3) after annealing in air ambient. The crystal growth in $H_2$ ambient was formed and stabilized by combination with each other due to the suppression of oxidized substance on film surface. Most oxidic Ni was restored when the oxidic Cr was present due to its stability in high-temperature $H_2$ ambient.

Reduction Efficiency of Cr(VI) in Aqueous Solution by Different Sources of Zero-Valent Irons (수용액 중 영가 철(Zero-Valent Iron)의 특성에 따른 Cr(VI)의 환원 효율 비교)

  • Yang, Jae-E.;Kim, Jong-Sung;Ok, Yong-Sik;Yoo, Kyung-Yoal
    • Korean Journal of Environmental Agriculture
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    • v.24 no.3
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    • pp.203-209
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    • 2005
  • Objective of this research was to assess the effectiveness of the different sources of the zero-valent irons (ZVIs) on the reduction of the toxic Cr(VI) to the nonhazardous Cr(III) in an aqueous solution. The physical and chemical properties of the six ZVIs were determined. Particle size and specific surface area of the ZVIs were in the ranges of $85.55{\sim}196.46{\mu}m\;and\;0.055{\sim}0.091m^2/g$, respectively. Most of the ZVIs contained Fe greater than 98% except for J (93%) and PU (88%). Reduction efficiencies of the ZVI for Cr(VI) reduction were varied with kinds of ZVIs. The J and PU ZVIs reduced 100% and 98% of Cr(VI) in the aqueous solution, respectively, within 3 hrs of reaction. However, PA, F, Sand J1 reduced 74, 65, 29 and 11% of Cr(VI), respectively, after 48 hrs. The pH of the reacting solution was rapidly increased from 3 to $4.34{\sim}9.04$ within 3 hrs. The oxidation-reduction potential (Eh) of the reacting solution was dropped from 600 to 319 mV within 3 hrs following addition of ZVIs to the Cr(VI) contaminated water. The capability of ZVIs for Cr(VI) reduction was the orders of PU > J > PA > F > S > J1, which coincided with the capacities to increase the pH and decrease the redox potentials. Results suggested that the reduction of Cr(VI) to Cr(III) was derived from the oxidation of the ZVI in the aqueous solution.

Magnetic Properties in Alternating Magnetic Field for the Sintered Ee-l7Cr-2M(M=Si, Nb, Mo) Alloys (Fe-l7Cr-2M(M=Si, Nb, Mo)합금 분말 소결체의 교류 자기 특성)

  • 김정곤;김택기;오용수
    • Journal of the Korean Magnetics Society
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    • v.10 no.6
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    • pp.269-273
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    • 2000
  • Fe-l7Cr-2M(M=Si, Nb, Mo) alloy powder was prepared by plasma electrode rotating atomizer and than the alloy powder was formed and sintered. The particle shape of the Fe-l7Cr-2M(M=Si, Nb, Mo) alloy power is spherical. The saturation magnetization of the sintered Fe-17Cr-2Mo and Fe-l7Cr-2Nb alloy are 155 emu/g. The saturation magnetization of the sintered Fe-l7Cr-2Si alloy is less than that of the sintered Fe-l7Cr-2Mo and Fe-l7Cr-2Nb alloy. The amplitude relative permeability of the sintered Fe-l7Cr-2M(M=Si, Nb, Mo) alloy has the maximum value in the range of 3∼5 Oe applied field at forming pressure 12 ton/cm$^2$, sintering temperature 1200$^{\circ}C$, and frequency 1 kHz. Power loss of the sintered Fe-l7Cr-2Nb alloy is 40 mW/cc at applied field, H$\sub$a/=5 Oe, and frequency, f=1 kHz. The power loss of the sintered Fe-l7Cr-2Nb alloy is a half of that of the sintered Fe-l7Cr-2Si and Fe-l7Cr-2Mo alloy.

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Energy Efficient Spectrum Sensing for Ad-hoc Cognitive Radio (애드혹 인지무선시스템을 위한 효과적 에너지 검출 방식)

  • Lee, So-Young;Kim, Eun-Cheol;Kim, Jin-Young
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.9 no.6
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    • pp.113-119
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    • 2010
  • Wireless ad hoc network composed of low power devices has been operated in ISM bands. However, with the growing proliferation of wireless services, these bands are increasingly getting congested. In order to relieve the spectrum scarcity and inefficient spectrum utilization, ad ho cognitive radio was proposed. In this paper we propose the efficient spectrum sensing method to reduce power consumption and detect white space in ad hoc cognitive radio system. The wireless channel between a licensed user and CR systems is modeled as Gaussian channel, the distance between a licensed user and CR systems is assumed differently. Also, the wireless channel among CR systems is assumed as the perfect channel and the distance among CR systems is assumed close distance. CR systems sense the spectrum of the licensed user by using a energy detection method. From the simulation results, spectrum sensing performance of combining sensing result of CR systems with high received energy shows higher than combining sensing result of all CR systems and we can refer to the proposed sensing method in order to perform effective spectrum sensing with low power consumption.

Magnetic Properties of Cr/CoPtCr/$SiO_2$Thin Films for High Density Magnetic Recording Media (고밀도 자기기록매체용 Cr/CoPtCr/$SiO_2$ 다층박막의 자기적 성질)

  • Choi, H.;Hong, Y.G.;Kim, C.O.
    • Korean Journal of Materials Research
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    • v.8 no.6
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    • pp.560-564
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    • 1998
  • CoPtCr magnetic layer was fabricated on the Cr underlayer by RF magnetron sputtering and the protective $SiO_2$ layer was deposited at room temperature. As the thickness of Cr underlayer increased, the coercive force of magnetic layer increased, then saturated slightly further increasing Cr underlayer thickness. Maximum coercive force was 860 Oe. It is thought that in-plane arrangement of magnetic phase and magnetic decoupling between the magnetic crystallites could lead to the increase of the coercive force. Post-annealing raised the coercive force exceedingly. and maximum coercive force value was 1650 Oe which was acquired from the sample annealed at 55$0^{\circ}C$ for 1hr.

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The Characteristics of Adsorption Treatment of Cr(VI)-containing Wastewater using Kudzu as the Adsorbent (칡을 이용(利用)한 크롬페수(廢水) 흡착(吸着) 처리(處理) 특성(特性))

  • Seo, Myung-Soon;Kim, Dong-Su
    • Resources Recycling
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    • v.17 no.3
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    • pp.56-61
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    • 2008
  • The kudzu has been investigated as an adsorbent for treatment of Cr(VI)-containing wastewater. The specific surface of kudzu was analyzed to be $189.91m^2/g$ and its major composition were found to be nitrogen and oxygen. It was observed that adsorption reaction for Cr(VI) on kudzu meets 1st order in kinetics and Langmuir Model in equilibrium. As the pH of wastewater was increased, the adsorbed amount of Cr(VI) onto kudzu was increased due to the pre-combination of $OH^-$ with adsorbent and the efficiency of adsorption was found to be 60% when real electroplating Cr(VI)-containing wastewater was applied.

A Study on Corrosion Resistance Characteristics of PVD Cr-N Coated Steels by Electrochemical Method

  • Ahn, SeungHo;Yoo, JiHong;Choi, YoonSeok;Kim, JungGu;Han, JeonGun
    • Corrosion Science and Technology
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    • v.2 no.6
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    • pp.289-295
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    • 2003
  • The corrosion behavior of Cr-N coated steels with different phases (${\alpha}-Cr$, CrN and $Cr_2N$) deposited by cathodic arc deposition on Hl3 steel was investigated in 3.5% NaCl solution at ambient temperature. Potentiodynamic polarization test, electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM) were the techniques applied to characterize the corrosion behavior. It was found that the CrN coating had a lower current density from potentiodynamic polarization test than others. The porosity, corresponding to the ratio of the polarization resistance of the uncoated and the coated substrate, was higher in the $Cr_2N$ coating than in the other Cr-N coated steels. EIS measurements showed, for the most of Cr-N coated steels, that the Bode plot presented two time constants. Also, the $Cr_2N$ coating represents the characteristic of Warburg behavior after 72hr of immersion. The coating morphologies were examined in planar view and cross-section by SEM analyses and the results were compared with those of the electrochemical measurement. The CrN coating had a dense, columnar grain-sized microstructure with minor intergranular porosity. From the above results, the CrN coating provided a better corrosion protection than the other Cr-N coated steels.

Prevalence of Plasmid-Mediated Quinolone Resistance Genes in Escherichia coli Isolated from Diseased Animals in Korea (환축에서 분리된 Escherichia coli의 plasmid-mediated quinolone resistance genes 분포도 조사)

  • Shin, Dong-Ho;Kim, Ha-Young;Byun, Jae-Won;Kim, Dae-Keun;Lim, Suk-Kyung;Jung, Byeong-Yeal
    • Journal of Life Science
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    • v.20 no.6
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    • pp.964-967
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    • 2010
  • Plasmid-mediated quinolone resistance (PMQR) determinants have been contributed to quinolone resistance of gram-negative bacteria worldwide. However, little data on the prevalence of these determinants in bacteria from animals are available in Korea. In this study, the prevalence of PMQR genes was investigated with E. coli originating from diseased animals. Among 55 E. coli tested, 11 showed PMQR genes by PCR. The most prevalent genotype was qepA (14.5%), followed by aac(6')-Ib-cr (7.3%) and qnrS (1.8%). Interestingly, two isolates with PMQR genes did not show quinolone resistance in this study. The isolates exhibited higher fluoroquinolone resistance in aac(6')-Ib-cr in combination with qnrS or qepA compared with aac(6')-Ib-cr only. In a conjugal transfer test, PMQR genes were transferred from donor to recipient.

Effect of tempering treatment on the mechanical properties in 12Cr heat resistant steel with ferrite phase (페라이트상을 갖는 12Cr 내열강의 기계적성질에 미치는 템퍼링 처리의 영향)

  • Kang, C.Y.;Lee, S.M.;Cho, Y.K.;Byun, S.S.;Jung, B.H.
    • Journal of Power System Engineering
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    • v.15 no.2
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    • pp.49-54
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    • 2011
  • Effect of tempering treatment on the mechanical properties of 12Cr heat resistant steel with ferrite phase was investigate in this study. As time and temperature of tempering treatment were increase, C and Cr contents in matrix structure were decreased. Due to increase of the amount of Cr26C6 type carbides. It was confirmed in mechanical properties experimental that tensile strength and hardness were decreased, while elongation and impact value were, increased with increasing the time and temperature.